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73649105249
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Crystal structure data for 1
-
2 using SHELXTL. CCDC 734042 for 1 and CCDC 734043 for 2 contains the supplementary crystallographic data for this paper. The data can be obtained free of charge from The Cambridge Crystallographic Data Centre at www.ccdc.cam.ac.uk/data-request/cif.
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21
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73649112183
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Bond valence sum of 1: Co1 for +2, 1.836; Co2 for +2, 1.880; Co3 for +2, 1.713; Co4 for +2, 1.774; Co5 for +2, 1.899; Co6 for +2, 1.791; Co7 for +2, 1.897; Co8 for +2, 1.967
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Bond valence sum of 1: Co1 for +2, 1.836; Co2 for +2, 1.880; Co3 for +2, 1.713; Co4 for +2, 1.774; Co5 for +2, 1.899; Co6 for +2, 1.791; Co7 for +2, 1.897; Co8 for +2, 1.967.
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22
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33847246427
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tau;4=(360- (α+β))/141, where α and β are the two largest q angles in a four-coordinate species, with t4=1 a perfect tetrahedron, and t4= 0 perfect square planar geometry
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tau;4=(360- (α+β))/141, where α and β are the two largest q angles in a four-coordinate species, with t4=1 a perfect tetrahedron, and t4= 0 perfect square planar geometry. L. Yang, D. R. Powell, R. P. Houser, Dalton Trans. 2007, 955.
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73649099988
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Bond valence sum of 2: Co1 for +3, 3.75; Co2 for +2, 2.25; Co3 for +2, 1.65; Co4 for +2, 2.25; Co5 for +2, 1.54
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Bond valence sum of 2: Co1 for +3, 3.75; Co2 for +2, 2.25; Co3 for +2, 1.65; Co4 for +2, 2.25; Co5 for +2, 1.54.
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