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Volumn 129, Issue 19, 2007, Pages 6104-6116

Properties of prussian blue materials manifested in molecular complexes: Observation of cyanide linkage isomerism and spin-crossover behavior in pentanuclear cyanide clusters

Author keywords

[No Author keywords available]

Indexed keywords

CLUSTER FORMATION; CYANIDE LINKAGE ISOMERISMS; MOLECULAR COMPLEXES; PRUSSIAN BLUE;

EID: 34249084598     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja066273x     Document Type: Article
Times cited : (201)

References (68)
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    • See, for example
    • See, for example, http://www.fda.gov/cder/drug/infopage/prussian_blue/.
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    • Berlinguette, C. P.; Vaughn, D.; Cañada-Vilalta, C.; Galán-Mascarós, J. R.; Dunbar, K. R. Angew. Chem., Int. Ed. 2003, 42, 1523-1526.
    • Berlinguette, C. P.; Vaughn, D.; Cañada-Vilalta, C.; Galán-Mascarós, J. R.; Dunbar, K. R. Angew. Chem., Int. Ed. 2003, 42, 1523-1526.
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    • Vos, G.; De Graaff, R. A. G.; Haasnoot, J. G.; van der Kraan, A. M.; De, Vaal, P.; Reedijk, J. Inorg. Chem. 1984, 23, 2905-2910.
    • Vos, G.; De Graaff, R. A. G.; Haasnoot, J. G.; van der Kraan, A. M.; De, Vaal, P.; Reedijk, J. Inorg. Chem. 1984, 23, 2905-2910.
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    • (1986) Magnetochemistry
    • Carlin, R.L.1
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    • University of Gottingen: Gottingen, Germany
    • Sheldrick, G. M. SADABS; University of Gottingen: Gottingen, Germany, 1996.
    • (1996) SADABS
    • Sheldrick, G.M.1
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  • 68
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    • III centers. The Zeeman interaction lowers the energy of the electronic β spins relative to α spins, such that the β electrons are the majority spin carriers in the lowest Zeeman level. This level has the highest Boltzmann population and determines the sign of the internal field.
    • III centers. The Zeeman interaction lowers the energy of the electronic β spins relative to α spins, such that the β electrons are the majority spin carriers in the lowest Zeeman level. This level has the highest Boltzmann population and determines the sign of the internal field.


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