Regioselective synthesis of trialkylpyrazines via nickel-catalyzed Negishi cross-coupling of pyrazine triflate

Synthesis (Germany)

Volumn 44, Issue 11, 2012, Pages 1631-1636

  Pitchaiah, Arigala ^a   Hwang, Intaek ^a   Hwang, Jin Soo ^a   Kim, Hyungrok ^a   Lee, Kee In ^a  

^a Korea Research Institute of Chemical Technology   (South Korea)

Author keywords

Negishi cross coupling; organozinc halide; pheromone; pyrazine triflate; trialkylpyrazine

Indexed keywords

NEGISHI CROSS-COUPLING; ORGANOZINC HALIDE; PHEROMONE; TRIALKYLPYRAZINE; TRIFLATES;

NICKEL; ORGANOMETALLICS; REGIOSELECTIVITY;

CATALYSIS;

2,3 DIMETHYL 5 (2 THIENYL)PYRAZINE; 2,3 DIMETHYL 5 PHENYLPYRAZINE; 2,3 DIMETHYL 5 PROPYLPYRAZINE; 2,3 DIMETHYL 5 TRIFLUOROMETHANESULFONYLOXYPYRAZINE; 2,3,5 TRIMETHYLPYRAZINE; 5 (3 FLUOROPHENYL) 2,3 DIMETHYLPYRAZINE; 5 (4 METHOXYPHENYL) 2,3 DIMETHYLPYRAZINE; 5 (4 TERT BUTYLPHENYL) 2,3 DIMETHYLPYRAZINE; 5 (SEC BUTYL) 2,3 DIMETHYLPYRAZINE; 5 BENZYL 2,3 DIMETHYLPYRAZINE; 5 BUTYL 2,3 DIMETHYLPYRAZINE; 5 CYCLOHEXYL 2,3 DIMETHYLPYRAZINE; 5 ETHYL 2,3 DIMETHYLPYRAZINE; 5 HYDROXY 2,3 DIMETHYLPYRAZINE; 5 ISOBUTYL 2,3 DIMETHYLPYRAZINE; 5 ISOPENTYL 2,3 DIMETHYLPYRAZINE; 5 ISOPROPYL 2,3 DIMETHYLPYRAZINE; NICKEL; PALLADIUM; PHEROMONE DERIVATIVE; PYRAZINE DERIVATIVE; TRIALKYLPYRAZINE DERIVATIVE; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG;

ANT; ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CONTROLLED STUDY; CROSS COUPLING REACTION; EUTETRAMORIUM MOCQUERYSI; NEGISHI CROSS COUPLING REACTION; NONHUMAN; NUCLEOPHILICITY; STEREOCHEMISTRY; SYNTHESIS;

EID: 84861341940     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0031-1290972     Document Type: Article

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