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Volumn 15, Issue 6, 2009, Pages 1499-1507

Pincer thioamide and pincer thioimide palladium complexes catalyze highly efficient negishi coupling of primary and secondary alkyl zinc reagents at room temperature

Author keywords

C C coupling; Cross coupling; Palladium; Tridentate ligands; Zinc

Indexed keywords

ARYL IODIDES; C-C COUPLING; CATALYST LOADINGS; CATALYTIC SYSTEMS; CONCENTRATION OF; CROSS-COUPLING; EFFICIENT CATALYSTS; HYDROGEN ATOMS; KINETIC PROFILES; NEGISHI COUPLINGS; PALLADIUM COMPLEXES; POTENTIAL APPLICATIONS; ROOM TEMPERATURES; SYNTHETIC UTILITIES; THIOAMIDE; TRIDENTATE LIGANDS; TURN-OVER NUMBERS; X-RAY ANALYSIS; ZINC REAGENTS;

EID: 60849126713     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200801860     Document Type: Article
Times cited : (59)

References (74)
  • 1
    • 60849127151 scopus 로고    scopus 로고
    • Handb, Organopalladium Chem. for Org. Synth. (Ed.: E.-i. Negishi), Wiley, New York, 2002, Chapter 1, pp. 229.
    • Handb, Organopalladium Chem. for Org. Synth. (Ed.: E.-i. Negishi), Wiley, New York, 2002, Chapter 1, pp. 229.
  • 4
    • 22744442306 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 4442-4489.
    • (2005) Angew. Chem. Int. Ed , vol.44 , pp. 4442-4489
  • 7
    • 84868898360 scopus 로고    scopus 로고
    • D. J. Cárdenas, Angew. Chem. 2003, 115, 398-401: Angew. Chem. Int. Ed. 2003, 42, 384-387.
    • D. J. Cárdenas, Angew. Chem. 2003, 115, 398-401: Angew. Chem. Int. Ed. 2003, 42, 384-387.
  • 9
    • 0042969355 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2003, 42, 3690-3693.
    • (2003) Angew. Chem. Int. Ed , vol.42 , pp. 3690-3693
  • 16
    • 0033549832 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 1999, 38, 2411-2413.
    • (1999) Angew. Chem. Int. Ed , vol.38 , pp. 2411-2413
  • 21
    • 18844440955 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 3133-3135.
    • (2005) Angew. Chem. Int. Ed , vol.44 , pp. 3133-3135
  • 29
    • 0345404157 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 1998, 37, 2387-2390.
    • (1998) Angew. Chem. Int. Ed , vol.37 , pp. 2387-2390
  • 41
    • 0037020330 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 3662-3665.
    • (2002) Angew. Chem. Int. Ed , vol.41 , pp. 3662-3665
  • 46
    • 0035886138 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2001, 40, 3750-3781.
    • (2001) Angew. Chem. Int. Ed , vol.40 , pp. 3750-3781
  • 49
    • 0024294403 scopus 로고
    • J. H. Dawson. Science 1988, 240, 433-439.
    • (1988) Science , vol.240 , pp. 433-439
    • Dawson, J.H.1
  • 67
    • 60849128706 scopus 로고    scopus 로고
    • Syntheses of thioamide-type SCS and SNS pincer ligands and their and application in functional materials were reported,[52.53] However, little is known about their catalytic behavior. To the best of our knowledge, only one example was reported for a Heck reaction, in which moderate to good TONs were achieved, and a PdII/PdIV catalytic cycle was also proposed.[52.53
    • [52.53]
  • 72
    • 60849104300 scopus 로고    scopus 로고
    • Electron-rich ArI, such as 1-iodo-4-methoxylbenzene, showed lower activity. The yield of desired cross-coupling product at room temperature was 61%.
    • Electron-rich ArI, such as 1-iodo-4-methoxylbenzene, showed lower activity. The yield of desired cross-coupling product at room temperature was 61%.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.