Electronic and steric effects on the Lewis acidities of transient silylenes and germylenes: Equilibrium constants for complexation with chalcogen and pnictogen donors

Organometallics

Volumn 31, Issue 9, 2012, Pages 3755-3767

  Kostina, Svetlana S ^a   Singh, Tishaan ^a   Leigh, William J ^a  

^a MCMASTER UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BINDING CONSTANT; BINDING FREE ENERGY; CHALCOGENS; DIETHYL ETHERS; EXPERIMENTAL DATA; GERMYLENES; HYDROCARBON SOLVENTS; LASER FLASH PHOTOLYSIS; LEWIS ACID; LEWIS ACID-BASE COMPLEXATION; LEWIS ACIDITY; LOWER LIMITS; P DONORS; SILYLENES; STERIC EFFECT; SYSTEMATIC ASSESSMENT; TETRAHYDROFURANS; TETRAHYDROTHIOPHENE (THT); THERMOCHEMICAL PARAMETERS; TRIETHYLAMINES; TRIETHYLPHOSPHINE;

BINDING ENERGY; COMPLEXATION; ETHERS; GERMANIUM; METHANOL; ORGANIC COMPOUNDS; ORGANIC SOLVENTS; THERMODYNAMICS;

EQUILIBRIUM CONSTANTS;

EID: 84861125812     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om3002558     Document Type: Article

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