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Volumn 27, Issue 19, 2008, Pages 5043-5051

Synthesis and structure of N-heterocyclic carbene complexes of germanium(II)

Author keywords

[No Author keywords available]

Indexed keywords

BOND LENGTH; COMPLEXATION; GERMANIUM; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLIGOMERIZATION; SUBSTITUTION REACTIONS;

EID: 54249092331     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800368d     Document Type: Article
Times cited : (65)

References (75)
  • 10
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    • Mingos, D. M. P, Crabtree, R. H, Housecraft, C. E, Eds, Elsevier: Oxford
    • (i) Weinert, C. S. In Comprehensive Organometallic Chemistry III Vol. 3; Mingos, D. M. P., Crabtree, R. H., Housecraft, C. E., Eds.; Elsevier: Oxford, 2007; pp 699-808.
    • (2007) Comprehensive Organometallic Chemistry III , vol.3 , pp. 699-808
    • Weinert, C.S.1
  • 31
    • 14944363256 scopus 로고    scopus 로고
    • For a recent review on main group carbene complexes, see
    • For a recent review on main group carbene complexes, see: Kuhn, N.; Al-Sheikh, A. Coord. Chem. Rev. 2005, 249, 829.
    • (2005) Coord. Chem. Rev , vol.249 , pp. 829
    • Kuhn, N.1    Al-Sheikh, A.2
  • 40
    • 54249158925 scopus 로고    scopus 로고
    • N-heterocyclic germylene 9 has been reported previously. See: Hermann, W. A.; Denk, M.; Behm, J.; Scherer, W.; Klingan, F.; Bock, H.; Solouki, B.; Wagner, M. Angew. Chem., Int. Ed. Engl. 1992, 31, 1485.
    • N-heterocyclic germylene 9 has been reported previously. See: Hermann, W. A.; Denk, M.; Behm, J.; Scherer, W.; Klingan, F.; Bock, H.; Solouki, B.; Wagner, M. Angew. Chem., Int. Ed. Engl. 1992, 31, 1485.
  • 50
    • 33751310123 scopus 로고    scopus 로고
    • Using an intermolecular coordinating donor to stabilize a Ge(OR) 2 species has been previously reported. For example, Ge(OMes) 2 forms a monomer when coordinated by an amine. See: Bonnefille, E, Mazières, S, El Hawi, N, Gornitzka, H, Couret, C. J. Organomet. Chem. 2006, 691, 5619
    • 2 forms a monomer when coordinated by an amine. See: Bonnefille, E.; Mazières, S.; El Hawi, N.; Gornitzka, H.; Couret, C. J. Organomet. Chem. 2006, 691, 5619.
  • 53
    • 54249128503 scopus 로고    scopus 로고
    • Substitution reactions with all of the dihalo derivatives 3-6 were attempted and gave similar results.
    • Substitution reactions with all of the dihalo derivatives 3-6 were attempted and gave similar results.
  • 54
    • 37049088715 scopus 로고    scopus 로고
    • For examples of other R8Ge4 ring systems, see: Ando, W, Tsumuraya, T. J. Chem. Soc, Chem. Commun. 1987, 1514
    • 4 ring systems, see: Ando, W.; Tsumuraya, T. J. Chem. Soc., Chem. Commun. 1987, 1514.
  • 55
    • 54249165644 scopus 로고    scopus 로고
    • 2 · dioxane. The addition of this Grignard reagent to 3 resulted in a higher yield for the formation of 1 in comparison to the addition of MesMgBr. See: Cannon, K. C.; Krow, G. R. In Handbook of Grignard Reagents; Silverman, G. S., Rakita, P. E., Eds; Marcel Dekker: New York, 1996.
    • 2 · dioxane. The addition of this Grignard reagent to 3 resulted in a higher yield for the formation of 1 in comparison to the addition of MesMgBr. See: Cannon, K. C.; Krow, G. R. In Handbook of Grignard Reagents; Silverman, G. S., Rakita, P. E., Eds; Marcel Dekker: New York, 1996.
  • 57
    • 54249159798 scopus 로고    scopus 로고
    • Lattman, M, Kemp, R. A, Eds, American Chemical Society: Washington, DC
    • Power, P. P. In Modern Aspects of Main Group Chemistry; Lattman, M., Kemp, R. A., Eds.; American Chemical Society: Washington, DC, 2006; pp 179-191.
    • (2006) Modern Aspects of Main Group Chemistry , pp. 179-191
    • Power, P.P.1
  • 72
    • 0031059866 scopus 로고    scopus 로고
    • Otwinowski, Z.; Minor, W. In Methods in Enzymology. 276: Macromolecular Crystallography Part A; Carter, C. W., Jr., Sweet, R. M., Eds.; Academic Press: New York, 1997; p 307.
    • Otwinowski, Z.; Minor, W. In Methods in Enzymology. Vol. 276: Macromolecular Crystallography Part A; Carter, C. W., Jr., Sweet, R. M., Eds.; Academic Press: New York, 1997; p 307.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.