Silanones and silanethiones from the reactions of transient silylenes with oxiranes and thiiranes in solution. The direct detection of diphenylsilanethione

Journal of the American Chemical Society

Volumn 133, Issue 12, 2011, Pages 4377-4388

  Kostina, Svetlana S ^a   Leigh, William J ^a  

^a MCMASTER UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AB INITIO STUDY; C-O CLEAVAGE; COMPLEX DECAY; CONCERTED MECHANISM; CYCLOHEXENE OXIDE; DECAY KINETICS; DIFFUSION LIMITS; DIRECT DETECTION; EXCITATION LASERS; HYDROCARBON SOLVENTS; LASER FLASH PHOTOLYSIS; MULTI-STEP; N-BUTYL AMINE; OXIRANES; PROPYLENE OXIDE; RATE DETERMINING STEP; SECOND ORDERS; SILYL SUBSTITUENTS; SILYLENES; TERT BUTANOL; TETRA-HYDROFURAN; TETRAHYDROTHIOPHENE; THIIRANES; UV ABSORPTION SPECTRUM;

ACETIC ACID; CALCULATIONS; HYDROCARBONS; LASER EXCITATION; LIGHT ABSORPTION; METHANOL; PHOTOLYSIS; PROPYLENE; REACTION KINETICS; SULFUR COMPOUNDS;

RATE CONSTANTS;

ACETIC ACID; ALKANE DERIVATIVE; ALKENE DERIVATIVE; BUTYLAMINE; CARBON; CYCLOHEXANE OXIDE; DIMETHYLSILANONE; DIPHENYLSILANETHIONE; EPOXIDE; ETHYLENE OXIDE; ETHYLENE OXIDE DERIVATIVE; METHANOL; ORGANOSILICON DERIVATIVE; OXYGEN; PROPYLENE OXIDE; PROPYLENE SULFIDE; SILANE DERIVATIVE; SILANETHIONE; SILYLENE; SULFUR; TERT BUTYL ALCOHOL; TETRAHYDROFURAN; TETRAHYDROTHIOPHENE DERIVATIVE; THIIRANE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; COMPLEX FORMATION; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; EQUILIBRIUM CONSTANT; EXCITATION; EXCITATION LASER PULSE; KINETICS; LASER; PHOTOLYSIS; SUBSTITUTION REACTION; ULTRAVIOLET SPECTROSCOPY;

ETHYLENE OXIDE; MOLECULAR STRUCTURE; QUANTUM THEORY; SILANES; SILICON COMPOUNDS; SOLUTIONS; STEREOISOMERISM; SULFIDES; THIONES;

EID: 79953041964     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja107881p     Document Type: Article

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