메뉴 건너뛰기




Volumn 29, Issue 6, 2010, Pages 1362-1367

On the bonding in N-heterocyclic carbene complexes of germanium(II)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTATIONAL ANALYSIS; GERMANIUM CENTERS; MODEL COMPOUND; N-HETEROCYCLIC CARBENE COMPLEX; N-HETEROCYCLIC CARBENES; STRUCTURAL METRICS; SUBSTITUENT EFFECT;

EID: 77949448012     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om900977g     Document Type: Article
Times cited : (56)

References (50)
  • 1
    • 1542763767 scopus 로고
    • Reviews on germanium(II) chemistry
    • Reviews on germanium(II) chemistry: (a) Neumann. W. P. Chem. Rev. 1991, 91, 311.
    • (1991) Chem. Rev. , vol.91 , pp. 311
    • Neumann, W.P.1
  • 11
    • 84906481373 scopus 로고    scopus 로고
    • Mingos, D. M. P., Crabtree, R. H., Housecraft, C. E., Eds.; Elsevier: Oxford
    • (k) Weinert. C. S. In Comprehensive Organometallic Chemistry III, Vol 3; Mingos, D. M. P., Crabtree, R. H., Housecraft, C. E., Eds.; Elsevier: Oxford, 2007; pp 699-808.
    • (2007) Comprehensive Organometallic Chemistry III , vol.3 , pp. 699-808
    • Weinert, C.S.1
  • 26
    • 33751385425 scopus 로고
    • Examples of intrinsically stable germylenes coordinated, by carbenes have reported by others
    • Examples of intrinsically stable germylenes coordinated, by carbenes have reported by others. See: (a) Arduengo, A. J., III; Dias, H. V. R.; Calabrese, J. C.; Davidson, F. Inorg. Chem. 1993, 32, 1541.
    • (1993) Inorg. Chem. , vol.32 , pp. 1541
    • Arduengo III, A.J.1    Dias, H.V.R.2    Calabrese, J.C.3    Davidson, F.4
  • 28
    • 34248137111 scopus 로고    scopus 로고
    • An. N-heterocyclic gallium anion can also stabilize a reactive germylene
    • An. N-heterocyclic gallium anion can also stabilize a reactive germylene. See: Rupar, P. A.; Jennings, M. C.; Baines, K. M. Can. J. Chem. 2007, 85, 141.
    • (2007) Can. J. Chem. , vol.85 , pp. 141
    • Rupar, P.A.1    Jennings, M.C.2    Baines, K.M.3
  • 36
    • 36248963242 scopus 로고    scopus 로고
    • The mesityl-substituted 12 can also be synthesized from the reaction of two equivalents of NHC 6 to tetramesityldigermene
    • The mesityl-substituted 12 can also be synthesized from the reaction of two equivalents of NHC 6 to tetramesityldigermene. See ref 7 and Hurni, K. L.; Rupar, P. A.; Payne, N. C.; Baines, K. M. Organometallics 2007, 26, 5569.
    • (2007) Organometallics , vol.26 , pp. 5569
    • Hurni, K.L.1    Rupar, P.A.2    Payne, N.C.3    Baines, K.M.4
  • 37
    • 60649120416 scopus 로고    scopus 로고
    • DFT has been endorsed as an excellent method for predicting bond lengths and bond dissociation energies of NHC complexes of metals
    • DFT has been endorsed as an excellent method for predicting bond lengths and bond dissociation energies of NHC complexes of metals. See: Jacobsen, H.; Correa, A.; Poater, A.; Costabile, C.; Cavallo, L. Coord. Chem. Rev. 2009, 253, 687.
    • (2009) Coord. Chem. Rev. , vol.253 , pp. 687
    • Jacobsen, H.1    Correa, A.2    Poater, A.3    Costabile, C.4    Cavallo, L.5
  • 38
    • 0347319419 scopus 로고    scopus 로고
    • The PBElPBE function had. been shown to be reasonable at predicting bond lengths
    • The PBElPBE function had. been shown to be reasonable at predicting bond lengths. See: Staroverov, V. N.; Scuseria, G. E.; Tao, J. M.; Perdew, J. P. J. Chem. Phys. 2003, 779, 12129 and
    • (2003) J. Chem. Phys. , vol.779 , pp. 12129
    • Staroverov, V.N.1    Scuseria, G.E.2    Tao, J.M.3    Perdew, J.P.4
  • 40
    • 77949467710 scopus 로고    scopus 로고
    • crnplx of the systems under study; see Supporting Information for details
    • crnplx of the systems under study; see Supporting Information for details.
  • 41
    • 77949471966 scopus 로고    scopus 로고
    • 2, BSSE = 5.9kJ/mol;R = OH, BSSE = 8.2kJ/mol;R = FBSSE = 6.3 kJ/mol; R = Cl, BSSE = 6.7 k.J/mol; R = Br, BSSE = 29.4 kJ/mol; R = Ph, BSSE = 5.6 kJ/mol
    • 2, BSSE = 5.9kJ/mol;R = OH, BSSE = 8.2kJ/mol;R = FBSSE = 6.3 kJ/mol; R = Cl, BSSE = 6.7 k.J/mol; R = Br, BSSE = 29.4 kJ/mol; R = Ph, BSSE = 5.6 kJ/mol.
  • 42
    • 77949447402 scopus 로고    scopus 로고
    • 3 is 1.9.6 kJ/mol and for the C-C bond in ethane is 31.3 kJ/mol using PBElPBE/6-311+G(d,p) model chemistry. See the Supporting Information for further details
    • 3 is 1.9.6 kJ/mol and for the C-C bond in ethane is 31.3 kJ/mol using PBElPBE/6-311+G(d,p) model chemistry. See the Supporting Information for further details.
  • 44
    • 77949469047 scopus 로고    scopus 로고
    • Tiekink, E. R. T., Vittal, J. J., Eds.; John Wiley & Sons, Ltd: Chichester, England
    • (b) Steed, J. W. In Frontiers in Crystal Engineering; Tiekink, E. R. T., Vittal, J. J., Eds.; John Wiley & Sons, Ltd: Chichester, England, 2006; pp 68-90.
    • (2006) Frontiers in Crystal Engineering , pp. 68-90
    • Steed, J.W.1
  • 46
    • 77949426048 scopus 로고    scopus 로고
    • 2-dioxane. The addition, of this Grignard reagent to 8 resulted in. a higher yield for the formation of 12 in comparison to the addition, of MesMgBr. See: Cannon, K. C.; Krow, G R. In Handbook of Grignard Reagents; Silverman, G. S., Rakita, P. E., Eds.; Marcel Dekker: New York
    • 2-dioxane. The addition, of this Grignard reagent to 8 resulted in. a higher yield for the formation of 12 in comparison to the addition, of MesMgBr. See: Cannon, K. C.; Krow, G R. In Handbook of Grignard Reagents; Silverman, G. S., Rakita, P. E., Eds.; Marcel Dekker: New York, 1996.
    • (1996)


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.