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Examples of intrinsically stable germylenes coordinated, by carbenes have reported by others
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An. N-heterocyclic gallium anion can also stabilize a reactive germylene
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Digermamum(0) can also be stabilized by NHCs
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The mesityl-substituted 12 can also be synthesized from the reaction of two equivalents of NHC 6 to tetramesityldigermene
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The mesityl-substituted 12 can also be synthesized from the reaction of two equivalents of NHC 6 to tetramesityldigermene. See ref 7 and Hurni, K. L.; Rupar, P. A.; Payne, N. C.; Baines, K. M. Organometallics 2007, 26, 5569.
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60649120416
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DFT has been endorsed as an excellent method for predicting bond lengths and bond dissociation energies of NHC complexes of metals
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The PBElPBE function had. been shown to be reasonable at predicting bond lengths
-
The PBElPBE function had. been shown to be reasonable at predicting bond lengths. See: Staroverov, V. N.; Scuseria, G. E.; Tao, J. M.; Perdew, J. P. J. Chem. Phys. 2003, 779, 12129 and
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77949467710
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crnplx of the systems under study; see Supporting Information for details
-
crnplx of the systems under study; see Supporting Information for details.
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41
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77949471966
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2, BSSE = 5.9kJ/mol;R = OH, BSSE = 8.2kJ/mol;R = FBSSE = 6.3 kJ/mol; R = Cl, BSSE = 6.7 k.J/mol; R = Br, BSSE = 29.4 kJ/mol; R = Ph, BSSE = 5.6 kJ/mol
-
2, BSSE = 5.9kJ/mol;R = OH, BSSE = 8.2kJ/mol;R = FBSSE = 6.3 kJ/mol; R = Cl, BSSE = 6.7 k.J/mol; R = Br, BSSE = 29.4 kJ/mol; R = Ph, BSSE = 5.6 kJ/mol.
-
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42
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77949447402
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3 is 1.9.6 kJ/mol and for the C-C bond in ethane is 31.3 kJ/mol using PBElPBE/6-311+G(d,p) model chemistry. See the Supporting Information for further details
-
3 is 1.9.6 kJ/mol and for the C-C bond in ethane is 31.3 kJ/mol using PBElPBE/6-311+G(d,p) model chemistry. See the Supporting Information for further details.
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2-dioxane. The addition, of this Grignard reagent to 8 resulted in. a higher yield for the formation of 12 in comparison to the addition, of MesMgBr. See: Cannon, K. C.; Krow, G R. In Handbook of Grignard Reagents; Silverman, G. S., Rakita, P. E., Eds.; Marcel Dekker: New York, 1996.
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Nakajima, T.25
Honda, Y.26
Kitao, O.27
Nakai, H.28
Vreven, T.29
Montgomery Jr., J.A.30
Peralta, J.E.31
Ogliaro, F.32
Bearpark, M.33
Heyd, J.J.34
Brothers, E.35
Kudin, K.N.36
Staroverov, V.N.37
Kobayashi, R.38
Normand, J.39
Raghavachari, K.40
Rendell, A.41
Burant, J.C.42
Iyengar, S.S.43
Tomasi, J.44
Cossi, M.45
Rega, N.46
Millam, J.M.47
Kiene, M.48
Knox, J.E.49
Cross, J.B.50
Bakken, V.51
Adamo, C.52
Jaramillo, J.53
Gomperts, R.54
Stratmann, R.E.55
Yazyev, O.56
Austin, A.J.57
Cammi, R.58
Pomelli, C.59
Ochterski, J.W.60
Martin, R.L.61
Morokuma, K.62
Zakrzewski, V.G.63
Voth, G.A.64
Salvador, P.65
Dannenberg, J.J.66
Dapprich, S.67
Daniels, A.D.68
Farkas, O.69
Foresman, J.B.70
Ortiz, J.V.71
Cioslowski, J.72
Fox, D.J.73
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