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Volumn 29, Issue 21, 2010, Pages 4871-4881

Reactivity studies of N-heterocyclic carbene complexes of germanium(II)

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EID: 78149341708     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100059z     Document Type: Article
Times cited : (41)

References (86)
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    • For a recent comparison of different neutral donors and their Lewis basicity see
    • For a recent comparison of different neutral donors and their Lewis basicity see: Gusev, D. G. Organometallics 2009, 28, 763
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    • tBu with 6
    • tBu with 6.
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    • Calculations using standard density functionals such as B3LYP, BP86, B98, and PW91 have been endorsed as an excellent method for predicting bond lengths and bond dissociation energies of NHC complexes of metals. See
    • Calculations using standard density functionals such as B3LYP, BP86, B98, and PW91 have been endorsed as an excellent method for predicting bond lengths and bond dissociation energies of NHC complexes of metals. See: Jacobsen, H.; Correa, A.; Poater, A.; Costabile, C.; Cavallo, L. Coord. Chem. Rev. 2009, 253, 687
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    • 2 complexes. Both MP2/6-311+G(d,p) and PBE1PBE/6-311+G(d,p) model chemistries were used and found to give very similar results. Therefore, only PBE1PBE/6-311+G(d,p) was used in the present study; see
    • 2 complexes. Both MP2/6-311+G(d,p) and PBE1PBE/6-311+G(d,p) model chemistries were used and found to give very similar results. Therefore, only PBE1PBE/6-311+G(d,p) was used in the present study; see: Ruddy, A. J.; Rupar, P. A.; Bladek, K. J.; Allan, C. J.; Avery, J. C.; Baines, K. M. Organometallics 2010, 29, 1362.
    • (2010) Organometallics , vol.29 , pp. 1362
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    • Compound 19 has been reported previously. (20a)
    • Compound 19 has been reported previously. (20a)
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    • Radical cations derived from 5 were formed by one-electron oxidation of the NHC by tetracyanoethylene and ferrocenium. See
    • Radical cations derived from 5 were formed by one-electron oxidation of the NHC by tetracyanoethylene and ferrocenium. See: Ramnial, T.; McKenzie, I.; Gorodetsky, B.; Tsang, E. M. W.; Clyburne, J. A. C. Chem. Commun. 2004, 1054
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    • + has been reported before and was synthesized by the direct reaction of 5 with MeI. See
    • + has been reported before and was synthesized by the direct reaction of 5 with MeI. See: Kuhn, N.; Göhner, M.; Steimann, M. Z. Naturforsch., B 2002, 57, 631
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    • 2 hybridization of the ipso mesityl carbon substituents
    • 2 hybridization of the ipso mesityl carbon substituents.
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    • 2, as was observed previously in the reaction of 5 with hexachloroethane. See
    • 2, as was observed previously in the reaction of 5 with hexachloroethane. See: Kuhn, N.; Abu-Rayyan, A.; Göhner, M.; Steimann, M. Z. Anorg. Allg. Chem. 2002, 628, 1721
    • (2002) Z. Anorg. Allg. Chem. , vol.628 , pp. 1721
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    • Adduct 28 has been previously reported and was formed by the direct reaction of tetramesityldigermene with pivalic acid
    • Adduct 28 has been previously reported and was formed by the direct reaction of tetramesityldigermene with pivalic acid: Hurni, K. L.; Rupar, P. A.; Payne, N. C.; Baines, K. M. Organometallics 2007, 26, 5569
    • (2007) Organometallics , vol.26 , pp. 5569
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    • a of the conjugate acid of the NHC used in this study has been calculated as approximately 36 in acetonitrile. See
    • a of the conjugate acid of the NHC used in this study has been calculated as approximately 36 in acetonitrile. See: Magill, A. M.; Cavell, K. J.; Yates, B. F. J. Am. Chem. Soc. 2004, 126, 8717
    • (2004) J. Am. Chem. Soc. , vol.126 , pp. 8717
    • Magill, A.M.1    Cavell, K.J.2    Yates, B.F.3
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