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tBu with 6
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53
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60649120416
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77949448012
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2 complexes. Both MP2/6-311+G(d,p) and PBE1PBE/6-311+G(d,p) model chemistries were used and found to give very similar results. Therefore, only PBE1PBE/6-311+G(d,p) was used in the present study; see
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2 complexes. Both MP2/6-311+G(d,p) and PBE1PBE/6-311+G(d,p) model chemistries were used and found to give very similar results. Therefore, only PBE1PBE/6-311+G(d,p) was used in the present study; see: Ruddy, A. J.; Rupar, P. A.; Bladek, K. J.; Allan, C. J.; Avery, J. C.; Baines, K. M. Organometallics 2010, 29, 1362.
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78149299187
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Compound 19 has been reported previously. (20a)
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Compound 19 has been reported previously. (20a)
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59
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2442717475
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Radical cations derived from 5 were formed by one-electron oxidation of the NHC by tetracyanoethylene and ferrocenium. See
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Schmidt, H.; Keitemeyer, S.; Neumann, B.; Stammler, H.-G.; Schoeller, W. W.; Jutzi, P. Organometallics 1998, 17, 2149
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63
-
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85086684344
-
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+ has been reported before and was synthesized by the direct reaction of 5 with MeI. See
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+ has been reported before and was synthesized by the direct reaction of 5 with MeI. See: Kuhn, N.; Göhner, M.; Steimann, M. Z. Naturforsch., B 2002, 57, 631
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64
-
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78149354959
-
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2 hybridization of the ipso mesityl carbon substituents
-
2 hybridization of the ipso mesityl carbon substituents.
-
-
-
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65
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78149349708
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2. See
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2. See: Duverneuil, G.; Mazerolles, P.; Perrier, E. Appl. Organomet. Chem. 1995, 9, 37
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66
-
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0036060107
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2, as was observed previously in the reaction of 5 with hexachloroethane. See
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2, as was observed previously in the reaction of 5 with hexachloroethane. See: Kuhn, N.; Abu-Rayyan, A.; Göhner, M.; Steimann, M. Z. Anorg. Allg. Chem. 2002, 628, 1721
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Kuhn, N.1
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68
-
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36248963242
-
-
Adduct 28 has been previously reported and was formed by the direct reaction of tetramesityldigermene with pivalic acid
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Adduct 28 has been previously reported and was formed by the direct reaction of tetramesityldigermene with pivalic acid: Hurni, K. L.; Rupar, P. A.; Payne, N. C.; Baines, K. M. Organometallics 2007, 26, 5569
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0038678968
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Sweeder, R. D.; Edwards, F. A.; Miller, K. A.; Banaszak Holl, M. M.; Kampf, J. W. Organometallics 2002, 21, 457
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0344062713
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3242741731
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a of the conjugate acid of the NHC used in this study has been calculated as approximately 36 in acetonitrile. See
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