Highly selective intramolecular carbene insertion into primary C-H bond of α-diazoacetamides mediated by a (p-cymene)ruthenium(II) carboxylate complex

Journal of the American Chemical Society

Volumn 134, Issue 18, 2012, Pages 7588-7591

  Lo, Vanessa Kar Yan ^a   Guo, Zhen ^a   Choi, Matthew Kwok Wai ^a   Yu, Wing Yiu ^a,b   Huang, Jie Sheng ^a   Che, Chi Ming ^a  

^a UNIVERSITY OF HONG KONG   (Hong Kong)

^b HONG KONG POLYTECHNIC UNIVERSITY   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

C-H BOND; CARBENE INSERTION; CARBOXYLATE COMPLEXES; DFT CALCULATION; P-CYMENE; REACTIVE SITE;

CARBOXYLATION; DENSITY FUNCTIONAL THEORY; ORGANIC COMPOUNDS; RUTHENIUM;

RUTHENIUM COMPOUNDS;

ACETAMIDE DERIVATIVE; CARBENE; CARBOXYLIC ACID DERIVATIVE; GAMMA LACTAM DERIVATIVE; RUTHENIUM DERIVATIVE;

ARTICLE; CALCULATION; CATALYST; CHEMICAL BOND; CRYSTAL STRUCTURE; HYDROGEN BOND; PROTON NUCLEAR MAGNETIC RESONANCE; X RAY CRYSTALLOGRAPHY;

ACETAMIDES; AZO COMPOUNDS; CARBOXYLIC ACIDS; COORDINATION COMPLEXES; METHANE; MODELS, MOLECULAR; MONOTERPENES; RUTHENIUM;

EID: 84860864333     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3006989     Document Type: Article

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