Ruthenium acetate complexes as versatile probes of metal-ligand interactions: Insight into the ligand effects of vinylidene, carbene, carbonyl, nitrosyl and isocyanide

European Journal of Inorganic Chemistry

Volumn , Issue 9, 2012, Pages 1493-1506

  Welby, Christine E ^a   Eschemann, Thomas O ^a   Unsworth, Christopher A ^a   Smith, Elizabeth J ^a   Thatcher, Robert J ^a   Whitwood, Adrian C ^a   Lynam, Jason M ^a  

^a UNIVERSITY OF YORK   (United Kingdom)

Author keywords

Carbene ligands; Carbonyl ligands; Isocyanide ligands; Ligand effects; Nitrosyl ligands; Ruthenium; Vinylidene ligands

Indexed keywords

CYANIDES; ORGANIC COMPOUNDS; RUTHENIUM COMPOUNDS; SPECTROSCOPIC ANALYSIS; X RAY CRYSTALLOGRAPHY;

ACETATE COMPLEXES; CARBENE LIGANDS; CARBONYL LIGAND; ELECTRON DONORS; ISOCYANIDE LIGANDS; LIGANDS EFFECT; NITROSYL LIGAND; RUTHENIUM ACETATES; SPECTROSCOPIC DATA; VINYLIDENE LIGANDS;

LIGANDS;

EID: 84858676963     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201100931     Document Type: Article

References (58)

1. C. A. Tolman, Chem. Rev. 1977, 77, 313.
2. L. Perrin, E. Clot, O. Eisenstein, J. Loch, R. H. Crabtree, Inorg. Chem. 2001, 40, 5806.
3. C. Köcher, W. A. Herrmann, J. Organomet. Chem. 1997, 532, 261.
4. A. R. Chianese, X. Li, M. C. Janzen, J. W. Faller, R. H. Crabtree, Organometallics 2003, 22, 1663.
5. R. A. Kelly, H. Clavier, S. Giudice, N. M. Scott, E. D. Stevens, J. Bordner, I. Samardjiev, C. D. Hoff, L. Cavallo, S. P. Nolan, Organometallics 2008, 27, 202.
6. D. G. Gusev, Organometallics 2009, 28, 763.
7. D. G. Gusev, Organometallics 2009, 28, 6548.
8. J. M. Lynam, C. E. Welby, A. C. Whitwood, Organometallics 2009, 28, 1320.
9. D. G. Johnson, J. M. Lynam, J. M. Slattery, C. E. Welby, Dalton Trans. 2010, 39, 10432.
10. N. P. Hiett, J. M. Lynam, C. E. Welby, A. C. Whitwood, J. Organomet. Chem. 2011, 696, 378.
11. A. Spencer, G. Wilkinson, J. Chem. Soc., Dalton Trans. 1974, 786.
12. S. D. Robinson, M. F. Uttley, J. Chem. Soc., Dalton Trans. 1973, 1912.
13. G. B. Richter-Addo, P. Legzdins, Metal Nitrosyls, Oxford University Press, 1992.
14. D. A. Morgenstern, G. M. Ferrence, J. Washington, J. I. Henderson, L. Rosenhein, J. D. Heise, P. E. Fanwick, C. P. Kubiak, J. Am. Chem. Soc. 1996, 118, 2198.
15. I. S. Zavarine, C. P. Kubiak, T. Yamaguchi, K. Ota, T. Matsui, T. Ito, Inorg. Chem. 2000, 39, 2696.
16. M. I. Bruce, Chem. Rev. 1991, 91, 197.
17. H. Werner, J. Organomet. Chem. 1994, 475, 45.
18. M. C. Puerta, P. Valerga, Coord. Chem. Rev. 1999, 193-195, 977.
19. Y. Wakatsuki, J. Organomet. Chem. 2004, 689, 4092.
20. A. B. Antonova, Coord. Chem. Rev. 2007, 251, 1521.
21. C. Bruneau, P. H. Dixneuf, Metal Vinylidenes and Allenylidenes in Catalysis: From Reactivity to Applications in Synthesis, 2008, Wiley-VCH, Weinheim, Germany.
22. J. M. Lynam, Chem. Eur. J. 2010, 16, 8238.
23. J. P. Selegue, Organometallics 1982, 1, 217.
24. D. Touchard, P. H. Dixneuf, Coord. Chem. Rev. 1998, 178, 409.
25. M. I. Bruce, Chem. Rev. 1998, 98, 2797.
26. V. Cadierno, M. P. Gamasa, J. Gimeno, Eur. J. Inorg. Chem. 2001, 571.
27. S. Rigaut, D. Touchard, P. H. Dixneuf, Coord. Chem. Rev. 2004, 248, 1585.
28. J. P. Selegue, Coord. Chem. Rev. 2004, 248, 1543.
29. V. Cadierno, J. Gimeno, Chem. Rev. 2009, 109, 3512.
30. E. Bustelo, P. H. Dixneuf, Adv. Synth. Catal. 2005, 347, 393.
31. E. Bustelo, P. H. Dixneuf, Adv. Synth. Catal. 2007, 349, 933.
32. S. Datta, C. L. Chang, K.-L. Yeh, R. S. Liu, J. Am. Chem. Soc. 2003, 125, 9294.
33. V. Cadierno, J. Francos, J. Gimeno, Green Chem. 2010, 12, 135.
34. B. Weyershausen, K. H. Dötz, Eur. J. Inorg. Chem. 1999, 1057.
35. M. I. Bruce, A. G. Swincer, B. J. Thomson, R. C. Wallis, Aust. J. Chem. 1980, 33, 2605.
36. K. H. Dötz, W. Sturm, Organometallics 1987, 6, 1424.
37. R. W. Grime, M. Helliwell, Z. I. Hussain, H. N. Lancashire, C. R. Mason, J. J. W. McDouall, C. M. Mydlowski, M. W. Whiteley, Organometallics 2008, 27, 857.
38. S. Pavlik, K. Mereiter, M. Puchberger, K. Kirchner, J. Organomet. Chem. 2005, 690, 5497.
39. M. P. Gamasa, J. Gimeno, B. M. Martín-Vaca, R. Isea, A. Vegas, J. Organomet. Chem. 2002, 651, 22.
40. C. Bianchini, A. Marchi, N. Mantovani, L. Marvelli, D. Masi, M. Peruzzini, R. Rossi, Eur. J. Inorg. Chem. 1998, 211.
41. B. J. Coe, S. J. Glenwright, Coord. Chem. Rev. 2000, 203, 5.
42. See for example, M. Mitoraj, A. Michalak, Organometallics 2007, 26, 6576.
43. A. B. Antonova, N. E. Kolobova, P. V. Petrovsky, B. V. Lokshin, N. S. Obezyuk, J. Organomet. Chem. 1977, 137, 55.
44. D. Moigno, B. Callejas-Gasper, J. Gil-Rubio, H. Werner, W. Kiefer, J. Organomet. Chem. 2002, 661, 181.
45. [24]
46. For a relationship between the electrophilicity of Fischer carbene complexes and the chemical shift see, W.-Q. Zhang, A. C. Whitwood, I. J. S. Fairlamb, J. M. Lynam, Inorg. Chem. 2010, 49, 8941.
47. R. W. Mitchell, A. Spencer, G. Wilkinson, J. Chem. Soc., Dalton Trans. 1973, 846.
48. W. Wu, W. Wu, S. Ji, H. Guo, J. Zhao, Eur. J. Inorg. Chem. 2010, 4470.
49. S. K. Pondey, A. E. Greene, J.-F. Poisson, J. Org. Chem. 2007, 72, 7769.
50. B. P. Cho, Tetrahedron Lett. 1995, 36, 2403.
51. B. S. Macdonald, P. J. Sykes, P. M. Adhikary, R. A. Harkness, Steroids 1971, 18:6, 753.
52. J. F. Templeton, C. J. C. Jackson, Steroids 1983, 41, 485.
53. SMART, Control Software, Bruker SMART Apex X-ray Diffractometer. v5.625, Bruker-AXS GMBH, Karlsruhe, Germany.
54. SAINT+, Integrion Software, Bruker SMART detectors. v6.45, Bruker-AXS GMBH, Karlsruhe, Germany.
55. G. M. Sheldrick, SADABS, Program for Absorption Correction. v2.10, Bruker AXS Inc., Madison, Wisconsin, USA, 2007.
56. G. M. Sheldrick, Acta Crystallogr., Sect. A 2008, 64, 112.
57. CrysAlisPro Version 1.171.34.40, Oxford Diffraction Ltd.
58. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, H. Puschmann, J. Appl. Crystallogr. 2009, 42, 339.