A new ruthenium-catalyzed cleavage of a carbon-carbon triple bond: Efficient transformation of ethynyl alcohol into alkene and carbon monoxide

Journal of the American Chemical Society

Volumn 125, Issue 31, 2003, Pages 9294-9295

  Datta, Swarup ^a   Chang, Chia Lung ^a   Yeh, Kuo Liang ^a   Liu, Rai Shung ^a  

^a NATIONAL TSING HUA UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; ALKENE; ALKYNE; CARBON; CARBON MONOXIDE; DEUTERIUM; ETHYNYL ALCOHOL; FUNCTIONAL GROUP; LEWIS ACID; ORGANIC COMPOUND; RHODIUM; RUTHENIUM; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; COVALENT BOND; COVALENT BOND CLEAVAGE; DEGRADATION; IONIZATION; ISOTOPE LABELING; PROTON TRANSPORT; REACTION ANALYSIS; STEREOCHEMISTRY; TRIPLE BOND;

EID: 0043210660     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036246w     Document Type: Article

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36. Related to this process is the water-assisted splitting of alkyne into alkane (or alkyl) and coordinated CO, which requires a stoichiometric amount of metal complexes. The latter reaction has not been effected catalytically despite its popularity and long history.