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The literature of vinylidene complexes is extensive. Some comprehensive reviews are: [12a] M. I. Bruce, Chem. Rev. 1991, 91, 197. [12b] A. B. Antonova, A. A. loganson, Russ. Chem. Rev. 1989, 58, 593. [12c] M. I. Bruce, A. G. Swincer, Adv. Organomet. Chem 1983, 22, 59.
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Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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Ara, I.1
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Lalinde, E.4
Tomas, M.5
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19
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37049089091
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-
Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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(1995)
J. Chem. Soc. Dalton Trans.
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Beddoes, R.L.1
Bitcon, C.2
Grime, R.W.3
Ricalton, A.4
Whiteley, M.W.5
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20
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0000558264
-
-
Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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O'Connor, J.M.1
Hübner, K.2
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21
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0001165967
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Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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(1996)
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Bianchini, C.1
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Peruzzini, M.3
Romerosa, A.4
Zanobini, F.5
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22
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0000785012
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Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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Esteruelas, M.A.1
Lahoz, F.J.2
Oñate, E.3
Oro, L.A.4
Valero, C.5
Zeier, B.6
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23
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33748881808
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Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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Wolf, J.2
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24
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0002123197
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Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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(1993)
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Touchard, D.1
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26
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0001076032
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Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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27
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Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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28
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85153027503
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Recent leading references of transition metal vinylidene complexes: [13a] I. Ara, J. R. Berenguer, J. Forniés, E. Lalinde, M. Tomas, Organometallics 1996, 15, 1014. [13b] R. L. Beddoes, C. Bitcon, R. W. Grime, A. Ricalton, M. W. Whiteley, J. Chem. Soc. Dalton Trans. 1995, 2873. [13c] J. M. O'Connor, K. Hübner, R. Merwin, L. Pu, J. Am. Chem. Soc. 1995, 117, 8861. [13d] C. Bianchini, P. Innocenti, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1996, 15, 272. [13e] M. A. Esteruelas, F. J. Lahoz, E. Oñate, L. A. Oro, C. Valero, B. Zeier, J. Am. Chem. Soc. 1995, 117, 7935. [13f] R. Wiedemann, J. Wolf, H. Werner, Angew. Chem. Int. Ed Engl. 1995, 34, 1244. [13g] H. Werner, J. Organomet. Chem. 1994, 475, 45. [13h] D. Touchard, P. Haquette, N. Pirio, L. Toupet, P. H. Dixneuf, Organometallics 1993, 12, 3132. [13i] C. Bianchini, M. Peruzzini, A. Romerosa, F. Zanobini, Organometallics 1995, 14, 3152. [13j] C. Bianchini, L. Glendenning, M. Peruzzini, A. Romerosa, F. Zanobini, J. Chem. Soc. Chem. Commun. 1994, 2219. [13k] C. Bianchini, J. A. Casares, M. Peruzzini, A. Romerosa, F. Zanobini, J. Am. Chem. Soc. 1996, 118, 6415, 4585. [13l] I. de los Rios, M. Jimenez Tenorio, M. C. Puerta, P. Valerga, J. Am. Chem. Soc. 1997, 119, 6529.
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85152990940
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note
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A single-crystal X-ray diffraction study on 5 has fully confirmed the structural formulation determined in solution by multinuclear NMR spectroscopy. Details of this structure will be provided elsewhere.
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