Synthetic and mechanistic aspects of the immortal ring-opening polymerization of lactide and trimethylene carbonate with new homo- and heteroleptic tin(II)-phenolate catalysts

Chemistry - A European Journal

Volumn 18, Issue 10, 2012, Pages 2998-3013

  Poirier, Valentin ^a   Roisnel, Thierry ^a   Sinbandhit, Sourisak ^b   Bochmann, Manfred ^c   Carpentier, Jean François ^a   Sarazin, Yann ^a  

^a INSTITUT DES SCIENCES CHIMIQUES DE RENNES   (France)

^b UNIVERSITÉ DE RENNES 1   (France)

^c UNIVERSITY OF EAST ANGLIA   (United Kingdom)

Author keywords

lactide; NMR spectroscopy; phenolate ligands; ring opening polymerization; tin

Indexed keywords

ACTIVE SPECIES; ALCOHOLYSIS; ALKOXIDES; ANCILLARY LIGANDS; CATIONIC COMPOUNDS; CONCENTRATION-DEPENDENT; DYNAMIC EQUILIBRIA; HETEROLEPTIC; HIGH ACTIVITY; HIGH YIELD; HIGHER TEMPERATURES; HOMOLEPTIC; HOMOLEPTIC COMPLEX; L-LACTIDE; LACTIDES; MECHANISTIC ASPECTS; MECHANISTIC STUDIES; MONODISPERSE; NEUTRAL SPECIES; NMR SPECTRUM; PHENOLATE LIGANDS; PRECATALYSTS; RING OPENING; SOLVENT FREE; SSBAUER SPECTROSCOPIES; TEMPERATURE DEPENDENT; TRIMETHYLENE CARBONATE; X RAY CRYSTAL STRUCTURES;

BIOGRAPHIES; CARBON DIOXIDE; CATALYSTS; DYNAMICS; ETHERS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHENOLS; POLYMERIZATION; TINNING;

TIN;

EID: 84857524527     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201102261     Document Type: Article

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