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74549115431
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The fac/mer ratio did not change even after prolonged heating of a solution of 2 in toluene at 110°C
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The fac/mer ratio did not change even after prolonged heating of a solution of 2 in toluene at 110°C.
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50
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74549225760
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2"
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2".
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74549116046
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This MVP process is supposed to generate also acetone, but the latter compound could not be identified, probably because of the low amounts generated, its volatility, and possibly its reactivity in the reaction mixture as well
-
This MVP process is supposed to generate also acetone, but the latter compound could not be identified, probably because of the low amounts generated, its volatility, and possibly its reactivity in the reaction mixture as well.
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57
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74549173125
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3 led to complex mixtures of compounds, out of which 6 could not be isolated in pure form
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3 led to complex mixtures of compounds, out of which 6 could not be isolated in pure form.
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74549116625
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Several crystals of 3 and 7 obtained from different batches were examined and all found to be identical
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Several crystals of 3 and 7 obtained from different batches were examined and all found to be identical.
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74549210892
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2-bridged isopropoxide groups
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2-bridged isopropoxide groups.
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A control reaction performed with enantiomerically pure S,S-lactide (L-LA) established that pure isotactic PLLA is produced with these systems. This observation confirms that no epimerization occurs under the conditions used
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A control reaction performed with enantiomerically pure S,S-lactide (L-LA) established that pure isotactic PLLA is produced with these systems. This observation confirms that no epimerization occurs under the conditions used.
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