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Volumn 29, Issue 2, 2010, Pages 491-500

Aluminum complexes of fluorinated β-diketonate ligands: Syntheses, structures, intramolecular reduction, and use in ring-opening polymerization of lactide

Author keywords

[No Author keywords available]

Indexed keywords

AL COMPLEX; ALUMINUM COMPLEXES; ATACTIC; CARBONYL GROUPS; CONTROLLED MOLECULAR WEIGHT; DIANIONIC LIGANDS; DINUCLEAR; HETEROLEPTIC; HETEROLEPTIC COMPLEXES; HOMOLEPTIC COMPLEX; HYDROLYSIS PRODUCTS; HYDROXIDE GROUPS; ISO-PROPOXIDE; ISOPROPOXIDE GROUPS; LACTIDES; MER-ISOMERS; OH GROUP; ROOM TEMPERATURE; SINGLE CRYSTAL X-RAY DIFFRACTION; TOLUENE SOLUTION; TRINUCLEAR STRUCTURE;

EID: 74549220334     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9009312     Document Type: Article
Times cited : (72)

References (76)
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    • The fac/mer ratio did not change even after prolonged heating of a solution of 2 in toluene at 110°C.
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    • 2"
    • 2".
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    • This MVP process is supposed to generate also acetone, but the latter compound could not be identified, probably because of the low amounts generated, its volatility, and possibly its reactivity in the reaction mixture as well
    • This MVP process is supposed to generate also acetone, but the latter compound could not be identified, probably because of the low amounts generated, its volatility, and possibly its reactivity in the reaction mixture as well.
  • 57
    • 74549173125 scopus 로고    scopus 로고
    • 3 led to complex mixtures of compounds, out of which 6 could not be isolated in pure form
    • 3 led to complex mixtures of compounds, out of which 6 could not be isolated in pure form.
  • 58
    • 74549221891 scopus 로고
    • Certain metal-hexafluoroacetylacetonate compounds may be attacked at carbon by nucleophiles, such as hydroxyl anions; see for instance: van Eldik, R. Inorg. Chem. 1985, 24, 423.
    • (1985) Inorg. Chem. , vol.24 , pp. 423
    • Van Eldik, R.1
  • 61
    • 74549116625 scopus 로고    scopus 로고
    • Several crystals of 3 and 7 obtained from different batches were examined and all found to be identical
    • Several crystals of 3 and 7 obtained from different batches were examined and all found to be identical.
  • 63
    • 74549210892 scopus 로고    scopus 로고
    • 2-bridged isopropoxide groups
    • 2-bridged isopropoxide groups.
  • 69
    • 74549225280 scopus 로고    scopus 로고
    • A control reaction performed with enantiomerically pure S,S-lactide (L-LA) established that pure isotactic PLLA is produced with these systems. This observation confirms that no epimerization occurs under the conditions used
    • A control reaction performed with enantiomerically pure S,S-lactide (L-LA) established that pure isotactic PLLA is produced with these systems. This observation confirms that no epimerization occurs under the conditions used.
  • 74
    • 0004150157 scopus 로고    scopus 로고
    • Universität Göttingen: Germany
    • SHELXL97; Universität Göttingen: Germany, 1998
    • (1998) SHELXL97


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.