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77249113835
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X-Y is the rate constant for the addition of monomer Y to the chain end of the monomer X moiety.
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X-Y is the rate constant for the addition of monomer Y to the chain end of the monomer X moiety.
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34
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77249110388
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Florcza and Duda recently reported another sophisticated approach using a chiral Al complex to adjust the reactivity of CL and L-lactide, but their chiral system is not applicable to the copolymerization using LA. See: Florcza, M, Duda, A. Angew. Chem, Int. Ed. 2008, 47, 9088. Comprehensive references for the copolymerization of CL with LA are listed therein
-
(a) Florcza and Duda recently reported another sophisticated approach using a chiral Al complex to adjust the reactivity of CL and L-lactide, but their chiral system is not applicable to the copolymerization using LA. See: Florcza, M.; Duda, A. Angew. Chem., Int. Ed. 2008, 47, 9088. Comprehensive references for the copolymerization of CL with LA are listed therein.
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35
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0031599166
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Also see ref 4, b Duda, A, Biela, T, Libiszowski, J, Penczek, S, Dubois, P, Mecerreyes, D, Jérôme, R. Polym. Degrad. Stab. 1998, 59, 215
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Also see ref 4. (b) Duda, A.; Biela, T.; Libiszowski, J.; Penczek, S.; Dubois, P.; Mecerreyes, D.; Jérôme, R. Polym. Degrad. Stab. 1998, 59, 215.
-
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36
-
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84890137702
-
-
LA = 2 for the copolymer does not indicate the randomness, as shown in Table 1 for complex 1.
-
LA = 2 for the copolymer does not indicate the randomness, as shown in Table 1 for complex 1.
-
-
-
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37
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77249131811
-
-
See the Supporting Information
-
See the Supporting Information.
-
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38
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77249117755
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LA = 2.8 by the NLLS method.
-
LA = 2.8 by the NLLS method.
-
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39
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67649196800
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For references on the NLLS method, see: a
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For references on the NLLS method, see: (a) Chen, Y.; Sen, A. Macromolecules 2009, 42, 3951.
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77249084203
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g value of - 13 °C for the random copolymer expected on the basis of the empirical relations of the Fox equation (see Chapter 11.2 of ref 10)
-
The DSC measurement on the obtained random copolymer showed a distinct
-
g value of - 13 °C for the random copolymer expected on the basis of the empirical relations of the Fox equation (see Chapter 11.2 of ref 10). No melting temperature was observed.
-
No melting temperature was observed
-
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There are reports that the ring sizes of lactones influence the Lewis basicity of their carboxyl groups: δ-valerolactone, which is a six-membered lactone, is more basic than CL. See: (a) Okamoto, Y. Makromol. Chem, Macromol. Symp. 1991, 42/43, 117
-
There are reports that the ring sizes of lactones influence the Lewis basicity of their carboxyl groups: δ-valerolactone, which is a six-membered lactone, is more basic than CL. See: (a) Okamoto, Y. Makromol. Chem., Macromol. Symp. 1991, 42/43, 117.
-
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34447578411
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Even if the Lewis basicity of each carboxyl group of CL and LA is the same, LA has the double potential for coordination with the catalyst because each LA molecule has two carboxyl groups
-
Even if the Lewis basicity of each carboxyl group of CL and LA is the same, LA has the double potential for coordination with the catalyst because each LA molecule has two carboxyl groups.
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