Snapshots of a reversible metal-ligand two-electron transfer step involving compounds related by multiple types of isomerism

European Journal of Inorganic Chemistry

Volumn , Issue 3, 2012, Pages 512-519

  Tejel, Cristina ^a   Asensio, Laura ^a   Pilar Del Rio M ^a   De Bruin, Bas ^b   Lõpez, José A ^a   Ciriano, Miguel A ^a  

^a UNIVERSITY OF ZARAGOZA   (Spain)

^b UNIVERSITY OF AMSTERDAM   (Netherlands)

Author keywords

Electron transfer; Imines; Iridium; Mixed valent compounds; Redox noninnocent ligands; Rhodium

Indexed keywords

DEHYDROGENATION; ELECTRON TRANSITIONS; IRIDIUM; IRIDIUM COMPOUNDS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RHODIUM COMPOUNDS; STEREOCHEMISTRY; X RAY DIFFRACTION;

ELECTROMERISM; ELECTRON TRANSFER; ELECTRON-TRANSFER STEP; IMINE; METAL LIGANDS; MIXED-VALENT COMPOUNDS; NMR-SPECTROSCOPY; NON-INNOCENT LIGANDS; REDOX NONINNOCENT LIGAND; TWO-ELECTRON TRANSFER;

ISOMERS;

EID: 84856054190     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201100868     Document Type: Article

References (75)

1. J. Choi, A. H. R. MacArthur, M. Brookhart, A. S. Goldman, Chem. Rev. 2011, 111, 1761-1779.
2. G. E. Dobereiner, R. H. Crabtree, Chem. Rev. 2010, 110, 681-703.
3. B. Gnanaprakasam, J. Zhang, D. Milstein, Angew. Chem. 2010, 122, 1510-1513;
4. Angew. Chem. Int. Ed. 2010, 49, 1468-1471.
5. T. Zweifel, J.-V. Naubron, H. Grützmacher, Angew. Chem. 2009, 121, 567-571;
6. Angew. Chem. Int. Ed. 2009, 48, 559-563.
7. B. A. Steinhoff, S. S. Stahl, J. Am. Chem. Soc. 2006, 128, 4348-4355.
8. I. W. C. E. Arends, R. A. Sheldon, in Modern Oxidation methods (Ed.:, J.-E. Bäckvall), Wiley-VCH, Weinheim, Germany, 2004, pp. 83-118.
9. P. Gamez, I. A. Koval, J. Reedijk, Dalton Trans. 2004, 4079-4088.
10. Advances in Catalytic Activation of Dioxygen by Metal Complexes (Ed.:, L. I. Simándi), in: Catalysis by Metal Complexes, vol. 26, Kluwer Academic, Dordrecht, The Netherlands, 2003.
11. K. Yamaguchi, N. Mizuno, Chem. Eur. J. 2003, 9, 4353-4361.
12. J. Pang, N. S. Scrutton, S. P. de Visser, M. J. Sutcliffe, Chem. Commun. 2010, 46, 3104-3106.
13. D. E. Edmondson, C. Binda, A. Mattevi, Arch. Biochem. Biophys. 2007, 464, 269-276.
14. I. S. MacPherson, M. E. P. Murphy, Cell Mol. Life Sci. 2007, 64, 2887-2899.
15. A. Roujeinikova, N. S. Scrutton, D. Leys, J. Biol. Chem. 2006, 281, 40264-40272.
16. N. S. Scrutton, Natl. Prod. Rep. 2004, 21, 722-730.
17. C. Binda, A. Mattevi, D. E. Edmondson, J. Biol. Chem. 2002, 277, 23973-23976.
18. M. Mure, S. A. Mills, J. P. Klinman, Biochemistry 2002, 41, 9269-9278.
19. J. P. Klinman, Chem. Rev. 1996, 96, 2541-2562.
20. G. J. Christian, A. Llobet, F. Maseras, Inorg. Chem. 2010, 49, 5977-5985.
21. J. P. Saucedo-Vázquez, V. M. Ugalde-Saldívar, A. R. Toscano, P. M. H. Kroneck, M. E. Sosa-Torres, Inorg. Chem. 2009, 48, 1214-1222.
22. G. J. Christian, A. Arbuse, X. Fontrodona, M. A. Martinez, A. Llobet, F. Maseras, Dalton Trans. 2009, 6013-6020.
23. B. Zhu, M. Lazar, B. G. Trewyna, R. J. Angelici, J. Catal. 2008, 260, 1-6.
24. A. Machkour, D. Mandon, M. Lachkar, R. Welter, Eur. J. Inorg. Chem. 2005, 158-161.
25. V. Amendola, L. Fabbrizzi, E. Mundum, P. Pallavicini, Dalton Trans. 2003, 773-774.
26. X. Gu, W. Chen, D. Morales-Morales, C. M. Jensen, J. Mol. Catal. A 2002, 189, 119-124.
27. F. R. Keene, Coord. Chem. Rev. 1999, 187, 121-149.
28. C. Zhang, N. Jiao, Angew. Chem. 2010, 122, 6310-6313;
29. Angew. Chem. Int. Ed. 2010, 49, 6174-6177.
30. S. Aiki, A. Taketoshi, J. Kuwabara, T. Koizumi, T. Kanbara, J. Organomet. Chem. 2011, 696, 1301-1304.
31. A. Taketoshi, T. Koizumi, T. Kanbara, Tetrahedron Lett. 2010, 51, 6457-6459.
32. W. H. Bernskoetter, M. Brookhart, Organometallics 2008, 27, 2036-2045.
33. K. Yamaguchi, N. Mizuno, Angew. Chem. 2003, 115, 1518-1521;
34. Angew. Chem. Int. Ed. 2003, 42, 1480-1483.
35. J. S. M. Samec, A. H. Éll, J.-E. Bäckvall, Chem. Eur. J. 2005, 11, 2327-2334.
36. C. Tejel, M. A. Ciriano, M. P. del Río, F. J. van den Bruele, D. G. H. Hetterscheid, N. Tsichlis i Spithas, B. de Bruin, J. Am. Chem. Soc. 2008, 130, 5844-5845.
37. C. Tejel, M. P. del Río, L. Asensio, F. J. van den Bruele, M. A. Ciriano, N. Tsichlis i Spithas, D. G. H. Hetterscheid, B. de Bruin, Inorg. Chem. 2011, 50, 7524-7534.
38. C. Tejel, M. A. Ciriano, M. P. del Río, D. G. H. Hetterscheid, N. Tsichlis i Spithas, J. M. M. Smits, B. de Bruin, Chem. Eur. J. 2008, 14, 10932-10936.
39. C. Tejel, M. P. del Río, M. A. Ciriano, E. J. Reijerse, F. Hartl, S. Zális, D. G. H. Hetterscheid, N. Tsichlis i Spithas, B. de Bruin, Chem. Eur. J. 2009, 15, 11878-11889.
40. S. Takemoto, S. Otsuki, Y. Hashimoto, K. Kamikawa, H. Matsuzaka, J. Am. Chem. Soc. 2008, 130, 8904-8905.
41. S.-Y. Liu, I. D. Hills, G. C. Fu, Organometallics 2002, 21, 4323-4325.
42. A. S. Batsanov, V. G. Andrianov, Y. T. Struchkov, V. S. Khandkarova, A. Z. Rubezhov, Organomet. Chem. (USSR) 1988, 1, 68.
43. J. Hao, H. Liu, H.-Y. Yuan, Acta Crystallogr., Sect. E 2011, 67, m469.
44. S. Yuan, S. Bai, D. Liu, W. H. Sun, Organometallics 2010, 29, 2132-2138.
45. A. G. Avent, P. B. Hitchcock, M. F. Lappert, R. Sablong, J. R. Severn, Organometallics 2004, 23, 2591-2600.
46. P. J. Daff, A. Monge, P. Palma, M. L. Poveda, C. Ruiz, P. Valerga, E. Carmona, Organometallics 1997, 16, 2263-2275.
47. W. I. Dzik, S. E. Calvo, J. N. H. Reek, M. Lutz, M. A. Ciriano, C. Tejel, D. G. H. Hetterscheid, B. de Bruin, Organometallics 2011, 30, 372-74.
48. C. Tejel, L. Asensio, M. P. del Río, B. de Bruin, J. A. Lõpez, M. A. Ciriano, Angew. Chem. 2011, 123, 9001-9005;
49. Angew. Chem. Int. Ed. 2011, 50, 8839-8843.
50. C. C. Lu, E. Bill, T. Weyhermüller, E. Bothe, K. Wieghardt, J. Am. Chem. Soc. 2008, 130, 3181-3197.
51. F. F. Puschmann, J. Harmer, D. Stein, H. Ruegger, B. de Bruin, B. H. Grützmacher, Angew. Chem. 2010, 122, 395-399;
52. Angew. Chem. Int. Ed. 2010, 49, 385-389.
53. F. F. Puschmann, H. Grützmacher, B. de Bruin, J. Am. Chem. Soc. 2010, 132, 73-75.
54. R. Usõn, L. A. Oro, J. A. Cabeza, Inorg. Synth. 1985, 23, 126-129.
55. C. Incarvito, M. Lam, B. Rhatigan, A. L. Rheingold, C. J. Qin, A. L. Gavrilova, B. Bosnich, J. Chem. Soc., Dalton Trans. 2001, 3478-3488.
56. G. M. Sheldrick, SADABS, Bruker AXS: Madison, WI, 1997.
57. G. M. Sheldrick, SHELXL-97, University of Göttingen, Germany, 1997.
58. L. J. Farrugia, J. Appl. Crystallogr. 1999, 32, 837-838.
59. R. Ahlrichs, Turbomole, v. 6.3, Theoretical Chemistry Group, University of Karlsruhe, Germany.
60. PQS, v. 2.4, 2001, Parallel Quantum Solutions, Fayettevile, Arkansas (USA); the Baker optimizer is available separately from PQS upon request:, I. Baker, J. Comput. Chem. 1986, 7, 385-395.
61. P. H. M. Budzelaar, J. Comput. Chem. 2007, 28, 2226-2236.
62. A. D. Becke, Phys. Rev. A 1988, 38, 3098-3100.
63. J. P. Perdew, Phys. Rev. B 1986, 33, 8822-8824.
64. F. Weigend, R. Ahlrichs, Phys. Chem. Chem. Phys. 2005, 7, 3297-3305.
65. F. Weigend, M. Häser, H. Patzelt, R. Ahlrichs, Chem. Phys. Lett. 1998, 294, 143-152.
66. D. Andrae, U. Haeussermann, M. Dolg, H. Stoll, H. Preuss, Theor. Chim. Acta 1990, 77, 123-141.
67. C. Lee, W. Yang, R. G. Parr, Phys. Rev. B 1988, 37, 785-789.
68. A. D. Becke, J. Chem. Phys. 1993, 98, 1372-1377.
69. A. D. Becke, J. Chem. Phys. 1993, 98, 5648-5652.
70. I. Mayer, Chem. Phys. Lett. 1983, 97, 270-274.
71. I. Mayer, Chem. Phys. Lett. 1984, 110, 440-444.
72. I. Mayer, Int. J. Quantum Chem. 1986, 29, 73-84.
73. I. Mayer, Int. J. Quantum Chem. 1986, 29, 477-483.
74. A. J. Bridgeman, G. Cavigliasso, L. R. Ireland, J. Rothery, J. Chem. Soc., Dalton Trans. 2001, 2095-2108.
75. S. I. Gorelsky, A. B. P. Lever, J. Organomet. Chem. 2001, 635, 187-196.