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Volumn 49, Issue 2, 2010, Pages 385-389

Electromeric rhodium radical complexes

Author keywords

EPR spectroscopy; Radicals; Redox chemistry; Rhodium; Valence isomerization

Indexed keywords

CHEMICAL EQUATIONS; EPR SPECTROSCOPY; LOW-VALENT; PARAMAGNETIC COMPLEXES; RADICAL COMPLEXES; RADICALS; REDOX CHEMISTRY; RH COMPLEXES; SPIN DENSITIES; VALENCE ISOMERIZATION;

EID: 73349127037     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200903201     Document Type: Article
Times cited : (33)

References (36)
  • 1
    • 33947442693 scopus 로고
    • We refer to the definition given by G. N. Lewis and G. T. Seaborg who in 1939 defined the term "electromer" as two forms of a molecule with the atoms in the same, or nearly the same, relative position but with a difference in electronic distribution.
    • a) We refer to the definition given by G. N. Lewis and G. T. Seaborg who in 1939 defined the term "electromer" as two forms of a molecule with the atoms in the same, or nearly the same, relative position but with a difference in electronic distribution. G. N. Lewis, G. T. Seaborg, J. Am. Chem. Soc. 1939, 61, 1886;
    • (1939) J. Am. Chem. Soc. , vol.61 , pp. 1886
    • Lewis, G.N.1    Seaborg, G.T.2
  • 8
    • 0037179984 scopus 로고    scopus 로고
    • 2-) "redox isomers" (Q = quinone type ligand), see: and references therein
    • 2-) "redox isomers" (Q = quinone type ligand), see: W. Kaim, M. Wanner, A. Knödler, S. Záliš, Inorg. Chim. Acta 2002,337,163, and references therein;
    • (2002) Inorg. Chim. Acta , vol.337 , pp. 163
    • Kaim, W.1    Wanner, M.2    Knödler, A.3    Záliš, S.4
  • 21
    • 73349138377 scopus 로고    scopus 로고
    • note
    • -3. AU nonhydrogen atoms were refined anisotropically. The contribution of the hydrogen atoms, in their calculated positions, was included in the refinement using a riding model;
  • 22
    • 73349120693 scopus 로고    scopus 로고
    • note
    • -3. AU non-hydrogen atoms were refined anisotropically. The contribution of the hydrogen atoms, in their calculated positions, was included in the refinement using a riding model. CCDC 706734 (2) and 706733 (5 a) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif.
  • 33
    • 73349108909 scopus 로고    scopus 로고
    • These products and the mechanism leading to their formation is currently under investigation and will be published elsewhere
    • These products and the mechanism leading to their formation is currently under investigation and will be published elsewhere.
  • 34
    • 73349113614 scopus 로고    scopus 로고
    • For the real (nonsimplified) molecules, this barrier could be somewhat higher because of steric reasons
    • For the real (nonsimplified) molecules, this barrier could be somewhat higher because of steric reasons.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.