-
1
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33947442693
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-
We refer to the definition given by G. N. Lewis and G. T. Seaborg who in 1939 defined the term "electromer" as two forms of a molecule with the atoms in the same, or nearly the same, relative position but with a difference in electronic distribution.
-
a) We refer to the definition given by G. N. Lewis and G. T. Seaborg who in 1939 defined the term "electromer" as two forms of a molecule with the atoms in the same, or nearly the same, relative position but with a difference in electronic distribution. G. N. Lewis, G. T. Seaborg, J. Am. Chem. Soc. 1939, 61, 1886;
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(1939)
J. Am. Chem. Soc.
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Lewis, G.N.1
Seaborg, G.T.2
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2
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13644266344
-
-
for recent work, see: b
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for recent work, see: b) T. Bally, A. Maltsev, F. Gerson, D. Frank, A. de Meijere, J. Am. Chem. Soc. 2005, 127, 1983;
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(2005)
J. Am. Chem. Soc.
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Bally, T.1
Maltsev, A.2
Gerson, F.3
Frank, D.4
De Meijere, A.5
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3
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16744366259
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c) B. Müller, T. Bally, F. Gerson, A. de Meijere, M. von Seebach, J. Am. Chem. Soc. 2003, 125, 13776.
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J. Am. Chem. Soc.
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Müller, B.1
Bally, T.2
Gerson, F.3
De Meijere, A.4
Von Seebach, M.5
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7
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-
73349128225
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-
for an EPR study of paramagnetic Rh "redox isomers", see
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c) for an EPR study of paramagnetic Rh "redox isomers", see: B. V. Lebedev, N. N. Smirnova, G. A. Abakumov, V. K. Cherkasov, M. P. Bubnov, J. Organomet. Chem. 1989, 485, 341;
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(1989)
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Lebedev, B.V.1
Smirnova, N.N.2
Abakumov, G.A.3
Cherkasov, V.K.4
Bubnov, M.P.5
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8
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-
0037179984
-
-
2-) "redox isomers" (Q = quinone type ligand), see: and references therein
-
2-) "redox isomers" (Q = quinone type ligand), see: W. Kaim, M. Wanner, A. Knödler, S. Záliš, Inorg. Chim. Acta 2002,337,163, and references therein;
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(2002)
Inorg. Chim. Acta
, vol.337
, pp. 163
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-
Kaim, W.1
Wanner, M.2
Knödler, A.3
Záliš, S.4
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9
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31944445034
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I(R-N-O), see
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I(R-N-O), see: G. M. Larin, T. A. Stromnova, S. T. Orlova, Russ. Chem. Bull. Int. Ed. 2005, 54, 1798;
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(2005)
Russ. Chem. Bull. Int. Ed.
, vol.54
, pp. 1798
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Larin, G.M.1
Stromnova, T.A.2
Orlova, S.T.3
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10
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-
33846318406
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.-), see
-
.-), see: P. Chaudhuri, M. Hess, K. Hildenbrand, E. Bill, T. Weyhermüller, K. Wieghardt, Inorg. Chem. 1999, 38, 2781-2790;
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(1999)
Inorg. Chem.
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, pp. 2781-2790
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Chaudhuri, P.1
Hess, M.2
Hildenbrand, K.3
Bill, E.4
Weyhermüller, T.5
Wieghardt, K.6
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11
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-
37049073506
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-
.-) equilibrium (dbt = o-dibenzodithiolato), see
-
.-) equilibrium (dbt = o-dibenzodithiolato), see: C. A. Ghilardi, F. Laschi, S. Midollini, A. Orlandini, G Scapacci, P. Zanello, J. Chem. Soc. Dalton Trans. 1995, 531;
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(1995)
J. Chem. Soc. Dalton Trans.
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Ghilardi, C.A.1
Laschi, F.2
Midollini, S.3
Orlandini, A.4
Scapacci, G.5
Zanello, P.6
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12
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-
0034823190
-
-
IVO(por)] "electromers" (por = porphyrin ligand), see
-
IVO(por)] "electromers" (por = porphyrin ligand), see: S. P. de Visser, F. Ogliaro, N. Harris, S. Shaik, J. Am. Chem. Soc. 2001, 123, 3037.
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(2001)
J. Am. Chem. Soc.
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-
De Visser, S.P.1
Ogliaro, F.2
Harris, N.3
Shaik, S.4
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13
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73349139982
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For a Review covering Rh-, Ir-, Pd-, and Pt-based radicals, see: Chapter 5
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For a Review covering Rh-, Ir-, Pd-, and Pt-based radicals, see: B. de Bruin, D G H. Hetterscheid, A. J. J. Koekoek, H. Grützmacher, Prog. Inorg. Chem. 2007, 55, Chapter 5.
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(2007)
Prog. Inorg. Chem.
, vol.55
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De Bruin, B.1
Hetterscheid, D.G.H.2
Koekoek, A.J.J.3
Grützmacher, H.4
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14
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0001505668
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a) H. Schönberg, S. Boulmaâz, M. Wörle, L. Liesum, A. Schweiger, H. Grützmacher, Angew. Chem. 1998, 110, 1492;
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(1998)
Angew. Chem.
, vol.110
, pp. 1492
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Schönberg, H.1
Boulmaâz, S.2
Wörle, M.3
Liesum, L.4
Schweiger, A.5
Grützmacher, H.6
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16
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4243688777
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b) H. Grützmacher, H. Schönberg, S. Boulmaâz, M. Mlakar, S. Deblon, S. Loss, M. Wörle, Chem. Commun. 1998, 2623;
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(1998)
Chem. Commun.
, pp. 2623
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Grützmacher, H.1
Schönberg, H.2
Boulmaâz, S.3
Mlakar, M.4
Deblon, S.5
Loss, S.6
Wörle, M.7
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17
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0037006266
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c) S. Deblon, L. Liesum, J Harmer, H. Schönberg, A. Schweiger, H. Grützmacher, Chem. Eur. J 2002, 8, 601;
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(2002)
Chem. Eur. J.
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, pp. 601
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Deblon, S.1
Liesum, L.2
Harmer, J.3
Schönberg, H.4
Schweiger, A.5
Grützmacher, H.6
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18
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1242277754
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d) F. Breher, H. Rüegger, M. Mlakar, M. Rudolph, S. Deblon, S. Boulmaâz, H. Schönberg, I Thomaier, H. Grützmacher, Chem. Eur. J 2004, 10, 641-653;
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(2004)
Chem. Eur. J.
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, pp. 641-653
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Breher, F.1
Rüegger, H.2
Mlakar, M.3
Rudolph, M.4
Deblon, S.5
Boulmaâz, S.6
Schönberg, H.7
Thomaier, I.8
Grützmacher, H.9
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19
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34250155663
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e) B. de Bruin, J. C. Russcher, H. Grützmacher, J. Organomet. Chem. 2007, 692, 3167.
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J. Organomet. Chem.
, vol.692
, pp. 3167
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De Bruin, B.1
Russcher, J.C.2
Grützmacher, H.3
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21
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73349138377
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note
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-3. AU nonhydrogen atoms were refined anisotropically. The contribution of the hydrogen atoms, in their calculated positions, was included in the refinement using a riding model;
-
-
-
-
22
-
-
73349120693
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-
note
-
-3. AU non-hydrogen atoms were refined anisotropically. The contribution of the hydrogen atoms, in their calculated positions, was included in the refinement using a riding model. CCDC 706734 (2) and 706733 (5 a) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif.
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23
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27444444817
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a) P. Maire, T. Büttner, F. Breher, P. Le Floch, H. Grützmacher, Angew. Chem. 2005, 117, 6477;
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Angew. Chem.
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Maire, P.1
Büttner, T.2
Breher, F.3
Le Floch, P.4
Grützmacher, H.5
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25
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54149099457
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b) T. Zweifel, J.-V. Naubron, T. Büttner, T. Ott, H. Grützmacher, Angew. Chem. 2008,120,3289;
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Zweifel, T.1
Naubron, J.-V.2
Büttner, T.3
Ott, T.4
Grützmacher, H.5
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27
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37049126907
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4] (M = Fe, Ru, Os): a
-
4] (M = Fe, Ru, Os): a) M. Poliakoff, J. J. Turner, J. Chem. Soc. Dalton Trans. 1974, 2276;
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(1974)
J. Chem. Soc. Dalton Trans.
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Poliakoff, M.1
Turner, J.J.2
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29
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0004557178
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calculations
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c) calculations: J. Li, G Schreckenbach, T. Ziegler, J. Am. Chem. Soc. 1995, 117, 486;
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-
-
Li, J.1
Schreckenbach, G.2
Ziegler, T.3
-
30
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0030884475
-
-
4] complexes with SH structure, see : and references therein
-
4] complexes with SH structure, see : M. Ogasawara, D Huang, W E. Streib, J. C. Huffman, N. GallegoPlanas, F. Maseras, O. Eisenstein, K. G. Caulton, J. Am. Chem. Soc. 1997, 119, 8642, and references therein.
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-
Ogasawara, M.1
Huang, D.2
Streib, W.E.3
Huffman, J.C.4
Gallegoplanas, N.5
Maseras, F.6
Eisenstein, O.7
Caulton, K.G.8
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33
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73349108909
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These products and the mechanism leading to their formation is currently under investigation and will be published elsewhere
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These products and the mechanism leading to their formation is currently under investigation and will be published elsewhere.
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-
-
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34
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73349113614
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For the real (nonsimplified) molecules, this barrier could be somewhat higher because of steric reasons
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For the real (nonsimplified) molecules, this barrier could be somewhat higher because of steric reasons.
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-
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35
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34447566934
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D Ostendorf, C. Landis, H. Grützmacher, Angew. Chem. 2006, 118, 5293;
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Angew. Chem.
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Ostendorf, D.1
Landis, C.2
Grützmacher, H.3
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