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n) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam. ac.uk/data-request/cif
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2 ligand can be regarded as a pyridine-2-imine ligand reduced by two electrons. Only two such Mg species have been structurally characterized: M. Westerhausen, T. Bollwein. N. Makro-poulos, S. Schneiderbauer, M. Suter, H. Nöth, P. Mayer, H. Piotrowski, K. Polborn, A. Pfitzner, Eur. J. Inorg. Chem. 2002, 389-404.
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+ are 2.794 and 2.788 Å, with a ring-slippage of 0.132 and 0.161 Å, respectively. The angles formed by the K-Ct line with the best plane of the metallacycles were found to be 87.2 and 86.7°. respectively.
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