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Volumn 14, Issue 35, 2008, Pages 10932-10936

Ligand oxidation of a deprotonated bis(picolyl)amine IrI(cod) complex

Author keywords

Iridium; Non innocent ligands; Picolylamtne; Potassium; Radicals

Indexed keywords

AMINES; CHEMICAL OXYGEN DEMAND; CHEMICAL REACTIVITY; COORDINATION REACTIONS; IRIDIUM; ORGANIC COMPOUNDS; ORGANOMETALLICS; OXIDATION; POTASSIUM; REDOX REACTIONS; SILVER;

EID: 57149127252     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200801162     Document Type: Article
Times cited : (46)

References (42)
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    • n) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam. ac.uk/data-request/cif
    • n) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam. ac.uk/data-request/cif
  • 36
    • 57149141330 scopus 로고    scopus 로고
    • 2 ligand can be regarded as a pyridine-2-imine ligand reduced by two electrons. Only two such Mg species have been structurally characterized: M. Westerhausen, T. Bollwein. N. Makro-poulos, S. Schneiderbauer, M. Suter, H. Nöth, P. Mayer, H. Piotrowski, K. Polborn, A. Pfitzner, Eur. J. Inorg. Chem. 2002, 389-404.
    • 2 ligand can be regarded as a pyridine-2-imine ligand reduced by two electrons. Only two such Mg species have been structurally characterized: M. Westerhausen, T. Bollwein. N. Makro-poulos, S. Schneiderbauer, M. Suter, H. Nöth, P. Mayer, H. Piotrowski, K. Polborn, A. Pfitzner, Eur. J. Inorg. Chem. 2002, 389-404.
  • 37
    • 57149137118 scopus 로고    scopus 로고
    • + are 2.794 and 2.788 Å, with a ring-slippage of 0.132 and 0.161 Å, respectively. The angles formed by the K-Ct line with the best plane of the metallacycles were found to be 87.2 and 86.7°. respectively.
    • + are 2.794 and 2.788 Å, with a ring-slippage of 0.132 and 0.161 Å, respectively. The angles formed by the K-Ct line with the best plane of the metallacycles were found to be 87.2 and 86.7°. respectively.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.