-
1
-
-
84857653254
-
-
Wiley-VCH, Weinheim
-
H.-J. Arpe, S. Hawkins, Industrial Organic Chemistry, 5thed., Wiley-VCH, Weinheim, 2010.
-
(2010)
Industrial Organic Chemistry, 5thed.
-
-
Arpe, H.-J.1
Hawkins, S.2
-
2
-
-
80053579659
-
-
For example the Shell higher olefin, Takasago menthole, BASF vitaminA, DuPont hydrocyanation processes. For reviews of academic and technical olefin isomerization processes, see:
-
For example the Shell higher olefin, Takasago menthole, BASF vitaminA, DuPont hydrocyanation processes. For reviews of academic and technical olefin isomerization processes, see:
-
-
-
-
3
-
-
0001239075
-
23
-
in (Eds.: E.N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, New York, Ch.
-
S. Akutagawa in Comprehensive Asymmetric Catalysis (Eds.: E.N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, New York, 1999, Ch.23, p.813;
-
(1999)
Comprehensive Asymmetric Catalysis
, pp. 813
-
-
Akutagawa, S.1
-
4
-
-
34547775368
-
2.9
-
in (Eds.: M. Beller, C. Bolm), Wiley-VCH, Weinheim, Ch.
-
S. Otsuka, K. Tani in Transition Metals for Organic Synthesis (Eds.: M. Beller, C. Bolm), Wiley-VCH, Weinheim, 2004, Ch.2.9, p.199.
-
(2004)
Transition Metals for Organic Synthesis
, pp. 199
-
-
Otsuka, S.1
Tani, K.2
-
7
-
-
80053587204
-
-
Selected examples: Friedel-Crafts-type reactions:
-
Selected examples: Friedel-Crafts-type reactions:
-
-
-
-
10
-
-
0347504883
-
-
Metal-catalyzed allylic substitutions:
-
A. Hasegawa, K. Ishihara, H. Yamamoto, Angew. Chem. 2003, 115, 5909-5911; Angew. Chem. Int. Ed. 2003, 42, 5731-5733; Metal-catalyzed allylic substitutions:
-
(2003)
Angew. Chem. 2003, 115, 5909-5911; Angew. Chem. Int. Ed.
, vol.42
, pp. 5731-5733
-
-
Hasegawa, A.1
Ishihara, K.2
Yamamoto, H.3
-
12
-
-
38049017956
-
-
Z. Lu, S. Ma, Angew. Chem. 2008, 120, 264-303; Angew. Chem. Int. Ed. 2008, 47, 258-297;
-
(2008)
Angew. Chem. 2008, 120, 264-303; Angew. Chem. Int. Ed.
, vol.47
, pp. 258-297
-
-
Lu, Z.1
Ma, S.2
-
15
-
-
74949133334
-
-
H. Ohmiya, Y. Makida, D. Li, M. Tanabe, M. Sawamura, J. Am. Chem. Soc. 2010, 132, 879-889;
-
(2010)
J. Am. Chem. Soc.
, vol.132
, pp. 879-889
-
-
Ohmiya, H.1
Makida, Y.2
Li, D.3
Tanabe, M.4
Sawamura, M.5
-
16
-
-
22744436808
-
-
Allylation of carbonyl compounds:
-
H. Yorimitsu, K. Oshima, Angew. Chem. 2005, 117, 4509-4513; Angew. Chem. Int. Ed. 2005, 44, 4435-4439; Allylation of carbonyl compounds:
-
(2005)
Angew. Chem. 2005, 117, 4509-4513; Angew. Chem. Int. Ed.
, vol.44
, pp. 4435-4439
-
-
Yorimitsu, H.1
Oshima, K.2
-
18
-
-
0002446724
-
-
in (Eds.: B.M. Trost, I. Fleming, C.H. Heathcock), Pergamon, Oxford
-
W. R. Roush in Comprehensive Organic Synthesis (Eds.: B.M. Trost, I. Fleming, C.H. Heathcock), Pergamon, Oxford, 1991, Vol.2, p.1;
-
(1991)
Comprehensive Organic Synthesis
, vol.2
, pp. 1
-
-
Roush, W.R.1
-
20
-
-
80053581816
-
-
Selected recent examples:
-
Selected recent examples:
-
-
-
-
21
-
-
77953313694
-
-
D. Gauthier, A. T. Lindhardt, E. P. K. Olsen, J. Overgaard, T. Skrydstrup, J. Am. Chem. Soc. 2010, 132, 7998-8009;
-
(2010)
J. Am. Chem. Soc.
, vol.132
, pp. 7998-8009
-
-
Gauthier, D.1
Lindhardt, A.T.2
Olsen, E.P.K.3
Overgaard, J.4
Skrydstrup, T.5
-
23
-
-
70350707662
-
-
N. Catozzi, M. G. Edwards, S. A. Raw, P. Wasnaire, R. J. K. Taylor, J. Org. Chem. 2009, 74, 8343-8354;
-
(2009)
J. Org. Chem.
, vol.74
, pp. 8343-8354
-
-
Catozzi, N.1
Edwards, M.G.2
Raw, S.A.3
Wasnaire, P.4
Taylor, R.J.K.5
-
24
-
-
70349542887
-
-
T. J. Donohoe, T. J. C. O'Riordan, C. P. Rosa, Angew. Chem. 2009, 121, 1032-1035; Angew. Chem. Int. Ed. 2009, 48, 1014-1017;
-
(2009)
Angew. Chem. 2009, 121, 1032-1035; Angew. Chem. Int. Ed.
, vol.48
, pp. 1014-1017
-
-
Donohoe, T.J.1
O'Riordan, T.J.C.2
Rosa, C.P.3
-
25
-
-
0037239704
-
-
R. Uma, C. Crevisy, R. Gree, Chem. Rev. 2003, 103, 27-51;
-
(2003)
Chem. Rev.
, vol.103
, pp. 27-51
-
-
Uma, R.1
Crevisy, C.2
Gree, R.3
-
26
-
-
0038102808
-
-
M. Mirza-Aghayan, R. Boukherroub, M. Bolourtchian, M. Hoseini, K. Tabar-Hydar, J. Organomet. Chem. 2003, 678, 1-4;
-
(2003)
J. Organomet. Chem.
, vol.678
, pp. 1-4
-
-
Mirza-Aghayan, M.1
Boukherroub, R.2
Bolourtchian, M.3
Hoseini, M.4
Tabar-Hydar, K.5
-
27
-
-
0036186748
-
-
I. R. Baxendale, A.-L. Lee, S. V. Ley, Synlett 2002, 3, 0516-0518;
-
(2002)
Synlett
, vol.3
, pp. 0516-0518
-
-
Baxendale, I.R.1
Lee, A.-L.2
Ley, S.V.3
-
29
-
-
44349129755
-
-
A. Correa, O. G. Mancheno, C. Bolm, Chem. Soc. Rev. 2008, 37, 1108-1117;
-
(2008)
Chem. Soc. Rev.
, vol.37
, pp. 1108-1117
-
-
Correa, A.1
Mancheno, O.G.2
Bolm, C.3
-
31
-
-
67649099463
-
-
W. M. Czaplik, M. Mayer, J. Cvengroš, A. JacobivonWangelin, ChemSusChem 2009, 2, 396-407.
-
(2009)
ChemSusChem
, vol.2
, pp. 396-407
-
-
Czaplik, W.M.1
Mayer, M.2
Cvengroš, J.3
JacobivonWangelin, A.4
-
34
-
-
0010884268
-
-
P. A. Tooley, L. W. Arndt, M. Y. Darensbourg, J. Am. Chem. Soc. 1985, 107, 2422-2427;
-
(1985)
J. Am. Chem. Soc.
, vol.107
, pp. 2422-2427
-
-
Tooley, P.A.1
Arndt, L.W.2
Darensbourg, M.Y.3
-
35
-
-
3342941111
-
-
E. N. Frankel, E. A. Emken, V. L. Davison, J. Am. Oil Chem. Soc. 1966, 43, 307-311.
-
(1966)
J. Am. Oil Chem. Soc.
, vol.43
, pp. 307-311
-
-
Frankel, E.N.1
Emken, E.A.2
Davison, V.L.3
-
36
-
-
77956912460
-
-
M. Mayer, W. M. Czaplik, A. JacobivonWangelin, Adv. Synth. Catal. 2010, 352, 2147-2152.
-
(2010)
Adv. Synth. Catal.
, vol.352
, pp. 2147-2152
-
-
Mayer, M.1
Czaplik, W.M.2
JacobivonWangelin, A.3
-
37
-
-
80053588339
-
-
2 flash chromatography (cyclohexane/ethyl acetate);
-
2 flash chromatography (cyclohexane/ethyl acetate);
-
-
-
-
38
-
-
80053601594
-
-
For more details, see Supporting Information;
-
For more details, see Supporting Information;
-
-
-
-
39
-
-
80053598957
-
-
p-Anisylpenta-2,4-diene was prepared from pentadienyl acetate according to Ref.[8].
-
p-Anisylpenta-2, 4-diene was prepared from pentadienyl acetate according to Ref.[8].
-
-
-
-
40
-
-
69949165772
-
-
The oxidative biaryl formation is hindered in cases where ortho-substituted aryl moieties are present. For the generation of iron(II) catalysts in the presence of bulky arylmagnesium halides, see
-
The oxidative biaryl formation is hindered in cases where ortho-substituted aryl moieties are present. For the generation of iron(II) catalysts in the presence of bulky arylmagnesium halides, see: D. Noda, Y. Sunada, T. Hatakeyama, M. Nakamura, H. Nagashima, J. Am. Chem. Soc. 2009, 131, 6078-6079.
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 6078-6079
-
-
Noda, D.1
Sunada, Y.2
Hatakeyama, T.3
Nakamura, M.4
Nagashima, H.5
-
41
-
-
37549040192
-
-
B. Plietker, A. Dieskau, K. Möws, A. Jatsch, Angew. Chem. 2008, 120, 204-207; Angew. Chem. Int. Ed. 2008, 47, 198-201;
-
(2008)
Angew. Chem. 2008, 120, 204-207; Angew. Chem. Int. Ed.
, vol.47
, pp. 198-201
-
-
Plietker, B.1
Dieskau, A.2
Möws, K.3
Jatsch, A.4
-
42
-
-
70349900182
-
-
M. Holzwarth, A. Dieskau, M. Tabassam, B. Plietker, Angew. Chem. 2009, 121, 7387-7391; Angew. Chem. Int. Ed. 2009, 48, 7251-7255.
-
(2009)
Angew. Chem. 2009, 121, 7387-7391; Angew. Chem. Int. Ed.
, vol.48
, pp. 7251-7255
-
-
Holzwarth, M.1
Dieskau, A.2
Tabassam, M.3
Plietker, B.4
-
43
-
-
0000275635
-
-
2]-allylbenzene from methyl phenylpropiolate, see
-
2]-allylbenzene from methyl phenylpropiolate, see: W. T. Hendrix, J. L. vonRosenberg, J. Am. Chem. Soc. 1976, 98, 4850-4852.
-
(1976)
J. Am. Chem. Soc.
, vol.98
, pp. 4850-4852
-
-
Hendrix, W.T.1
vonRosenberg, J.L.2
-
44
-
-
80053610290
-
-
Similar mechanistic scenarios have been reported;
-
Similar mechanistic scenarios have been reported;
-
-
-
-
45
-
-
52649130255
-
-
Iron carbonyl catalysts
-
Iron carbonyl catalysts: K. R. Sawyer, E. A. Glascoe, J. F. Cahoon, J. P. Schlegel, C. B. Harris, Organometallics 2008, 27, 4370-4379;
-
(2008)
Organometallics
, vol.27
, pp. 4370-4379
-
-
Sawyer, K.R.1
Glascoe, E.A.2
Cahoon, J.F.3
Schlegel, J.P.4
Harris, C.B.5
-
46
-
-
0346320741
-
-
Phosphine-ruthenium(0) catalysts, C-C.
-
Phosphine-ruthenium(0) catalysts: E. O. Sherman, Jr., M. Olson, J. Organomet. Chem. 1979, 172, C13-C19.
-
(1979)
J. Organomet. Chem.
, vol.172
, pp. 13-19
-
-
Sherman Jr, E.O.1
Olson, M.2
-
48
-
-
78651301850
-
-
For hydridoiron complexes in catalysis, see
-
For hydridoiron complexes in catalysis, see: H. Nakazawa, M. Itazaki, Top. Organomet. Chem. 2011, 33, 27-81;
-
(2011)
Top. Organomet. Chem.
, vol.33
, pp. 27-81
-
-
Nakazawa, H.1
Itazaki, M.2
-
49
-
-
77955799803
-
-
Reactions with a formal iron hydride generated upon β-hydride elimination of alkyliron intermediates
-
Reactions with a formal iron hydride generated upon β-hydride elimination of alkyliron intermediates: W. M. Czaplik, S. Grupe, M. Mayer, A. JacobivonWangelin, Chem. Commun. 2010, 46, 6350-6352.
-
(2010)
Chem. Commun.
, vol.46
, pp. 6350-6352
-
-
Czaplik, W.M.1
Grupe, S.2
Mayer, M.3
JacobivonWangelin, A.4
-
50
-
-
34447275675
-
-
Average of five runs at large scales (5mmol reactions). After an induction period of 15min required for the (reductive)catalyst formation, no further biaryl formation was observed during the reaction under strictly anaerobic conditions. Similar observations pointing to an iron(0) catalyst in the presence of aryl Grignard species have been reported
-
Average of five runs at large scales (5mmol reactions). After an induction period of 15min required for the (reductive)catalyst formation, no further biaryl formation was observed during the reaction under strictly anaerobic conditions. Similar observations pointing to an iron(0) catalyst in the presence of aryl Grignard species have been reported: G. Cahiez, V. Habiak, C. Duplais, A. Moyeux, Angew. Chem. 2007, 119, 4442-4444; Angew. Chem. Int. Ed. 2007, 46, 4364-4366;
-
(2007)
Angew. Chem. 2007, 119, 4442-4444; Angew. Chem. Int. Ed.
, vol.46
, pp. 4364-4366
-
-
Cahiez, G.1
Habiak, V.2
Duplais, C.3
Moyeux, A.4
-
51
-
-
80053578362
-
-
EXAFS and XANES spectroscopy have been used for the detection of iron(0) species under such conditions: A. Welther, M. Bauer, A. JacobivonWangelin, unpublished results.
-
EXAFS and XANES spectroscopy have been used for the detection of iron(0) species under such conditions: A. Welther, M. Bauer, A. JacobivonWangelin, unpublished results.
-
-
-
-
52
-
-
46949098763
-
-
For alternative mechanistic postulates of iron-catalyzed cross-coupling reactions, see also:
-
A. Fürstner, R. Martin, H. Krause, G. Seidel, R. Goddard, C. W. Lehmann, J. Am. Chem. Soc. 2008, 130, 8773-8787. For alternative mechanistic postulates of iron-catalyzed cross-coupling reactions, see also:
-
(2008)
J. Am. Chem. Soc.
, vol.130
, pp. 8773-8787
-
-
Fürstner, A.1
Martin, R.2
Krause, H.3
Seidel, G.4
Goddard, R.5
Lehmann, C.W.6
-
53
-
-
80053591200
-
-
ref.[10];
-
ref.[10];
-
-
-
-
55
-
-
70350268917
-
-
J. Kleimark, A. Hedström, P.-F. Larsson, C. Johansson, P.-O. Norrby, ChemCatChem 2009, 1, 152-161;
-
(2009)
ChemCatChem
, vol.1
, pp. 152-161
-
-
Kleimark, J.1
Hedström, A.2
Larsson, P.-F.3
Johansson, C.4
Norrby, P.-O.5
-
57
-
-
34249705281
-
-
W. Arabczyk, D. Moszynski, U. Narkiewicz, R. Pelka, M. Podsiadły, Catal. Today 2007, 124, 43-48;
-
(2007)
Catal. Today
, vol.124
, pp. 43-48
-
-
Arabczyk, W.1
Moszynski, D.2
Narkiewicz, U.3
Pelka, R.4
Podsiadły, M.5
-
59
-
-
80051824396
-
-
For the direct synthesis of substituted styrenes via iron-catalyzed cross-coupling, see, and references therein.
-
For the direct synthesis of substituted styrenes via iron-catalyzed cross-coupling, see: W. M. Czaplik, M. Mayer, A. Jacobi von Wangelin, ChemCatChem 2011, 3, 135-138, and references therein.
-
(2011)
ChemCatChem
, vol.3
, pp. 135-138
-
-
Czaplik, W.M.1
Mayer, M.2
Wangelin, A.J.V.3
|