In situ generated bulky palladium hydride complexes as catalysts for the efficient isomerization of olefins. Selective transformation of terminal alkenes to 2-alkenes

Journal of the American Chemical Society

Volumn 132, Issue 23, 2010, Pages 7998-8009

  Gauthier, Delphine ^a   Lindhardt, Anders T ^a   Olsen, Esben P K ^a   Overgaard, Jacob ^a   Skrydstrup, Troels ^a  

^a AARHUS UNIVERSITY   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE CATALYST; ACYL COMPLEXES; ALLYL ETHERS; ALLYLATIONS; ALTERNATIVE CATALYSTS; CARBON MIGRATION; CATALYST LOADINGS; CATALYTIC SYSTEM; CHLORIDE LIGANDS; EPIMERIZATION; HOMOALLYLIC ALCOHOL; IN-SITU; PALLADIUM HYDRIDE; QUANTITATIVE YIELDS; SELECTIVE TRANSFORMATION; SINGLE CRYSTAL X-RAY STRUCTURES; STEREOGENIC CARBONS; TERMINAL ALKENES; TERMINAL OLEFINS;

AMINES; CHLORINE COMPOUNDS; CRYSTAL STRUCTURE; DYES; ELECTRON TRANSITIONS; ETHERS; FUNCTIONAL GROUPS; ISOMERIZATION; ISOMERS; LIGANDS; OLEFINS; PALLADIUM; PALLADIUM COMPOUNDS;

CATALYST SELECTIVITY;

ALKENE DERIVATIVE; PALLADIUM COMPLEX;

ALLYLATION; ARTICLE; CATALYSIS; EPIMERIZATION; ISOMERIZATION;

ALKENES; CARBON; CATALYSIS; PALLADIUM; STEREOISOMERISM; THERMODYNAMICS;

EID: 77953313694     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9108424     Document Type: Article

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