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Volumn 27, Issue 17, 2008, Pages 4370-4379

Mechanism for iron-catalyzed alkene isomerization in solution

Author keywords

[No Author keywords available]

Indexed keywords

MODEL SYSTEMS; ROOM TEMPERATURES; TIME-RESOLVED;

EID: 52649130255     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800481r     Document Type: Article
Times cited : (42)

References (66)
  • 43
    • 52649163290 scopus 로고    scopus 로고
    • Harvey, J. N. Spin-Forbidden Reactions in Transition Metal Chemistry. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker Inc.: New York, NY, 2001; pp 291-321.
    • Harvey, J. N. Spin-Forbidden Reactions in Transition Metal Chemistry. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker Inc.: New York, NY, 2001; pp 291-321.
  • 50
    • 52649180414 scopus 로고    scopus 로고
    • The average values for the two time constants were calculated by averaging each time constant for the two D peaks (1969 and 1977 cm -1) and the two C peaks 1990 and 2058 cm-1
    • -1).
  • 51
    • 52649121715 scopus 로고    scopus 로고
    • The dynamics of the shoulder at 2045 cm-1 are masked by the dynamics of the neighboring peak at 2058 cm-1
    • -1.
  • 52
    • 52649171799 scopus 로고    scopus 로고
    • Unpublished data
    • Unpublished data.
  • 53
    • 52649125548 scopus 로고    scopus 로고
    • -1 peak, which is expected to be the largest peak in E, we expect the population of E to be small. Therefore, the contribution to the catalytic cycle will be small and not detectable.
    • -1 peak, which is expected to be the largest peak in E, we expect the population of E to be small. Therefore, the contribution to the catalytic cycle will be small and not detectable.
  • 60
    • 52649088715 scopus 로고    scopus 로고
    • mer, respectively, correspond to a time constant of ca. 200 ns.
    • mer, respectively, correspond to a time constant of ca. 200 ns.
  • 61
    • 52649164493 scopus 로고    scopus 로고
    • 2 and indicated that this isomer is isoenergetic with the trans-isomer.
    • 2 and indicated that this isomer is isoenergetic with the trans-isomer.
  • 62
    • 52649101360 scopus 로고    scopus 로고
    • -1 according to the DFT results summarized in Table 2.
    • -1 according to the DFT results summarized in Table 2.
  • 65
    • 52649135424 scopus 로고    scopus 로고
    • Previous studies have been performed with complexes with a pentene ligand, but the experiments presented herein have been performed with a hexene ligand
    • Previous studies have been performed with complexes with a pentene ligand, but the experiments presented herein have been performed with a hexene ligand.
  • 66
    • 52649166662 scopus 로고    scopus 로고
    • The time constants reported in the main text are average values, while the time constants in the figure are for the specific C and D peaks displayed.
    • The time constants reported in the main text are average values, while the time constants in the figure are for the specific C and D peaks displayed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.