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-
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52649180414
-
-
The average values for the two time constants were calculated by averaging each time constant for the two D peaks (1969 and 1977 cm -1) and the two C peaks 1990 and 2058 cm-1
-
-1).
-
-
-
-
51
-
-
52649121715
-
-
The dynamics of the shoulder at 2045 cm-1 are masked by the dynamics of the neighboring peak at 2058 cm-1
-
-1.
-
-
-
-
52
-
-
52649171799
-
-
Unpublished data
-
Unpublished data.
-
-
-
-
53
-
-
52649125548
-
-
-1 peak, which is expected to be the largest peak in E, we expect the population of E to be small. Therefore, the contribution to the catalytic cycle will be small and not detectable.
-
-1 peak, which is expected to be the largest peak in E, we expect the population of E to be small. Therefore, the contribution to the catalytic cycle will be small and not detectable.
-
-
-
-
54
-
-
0000101660
-
-
Desrosiers, M.; Wink, D.; Trautman, R.; Friedman, A.; Ford, P. J. Am. Chem. Soc. 1986, 108, 1917.
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-
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Desrosiers, M.1
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-
58
-
-
0032494426
-
-
Yang, H.; Asplund, M. C.; Kotz, K. T.; Wilken, M. J.; Frei, H.; Harris, C. B. J. Am. Chem. Soc. 1998, 120, 10154-10165.
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-
Yang, H.1
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Wilken, M.J.4
Frei, H.5
Harris, C.B.6
-
60
-
-
52649088715
-
-
mer, respectively, correspond to a time constant of ca. 200 ns.
-
mer, respectively, correspond to a time constant of ca. 200 ns.
-
-
-
-
61
-
-
52649164493
-
-
2 and indicated that this isomer is isoenergetic with the trans-isomer.
-
2 and indicated that this isomer is isoenergetic with the trans-isomer.
-
-
-
-
62
-
-
52649101360
-
-
-1 according to the DFT results summarized in Table 2.
-
-1 according to the DFT results summarized in Table 2.
-
-
-
-
65
-
-
52649135424
-
-
Previous studies have been performed with complexes with a pentene ligand, but the experiments presented herein have been performed with a hexene ligand
-
Previous studies have been performed with complexes with a pentene ligand, but the experiments presented herein have been performed with a hexene ligand.
-
-
-
-
66
-
-
52649166662
-
-
The time constants reported in the main text are average values, while the time constants in the figure are for the specific C and D peaks displayed.
-
The time constants reported in the main text are average values, while the time constants in the figure are for the specific C and D peaks displayed.
-
-
-
|