Controlled rearrangement of lactam-tethered allenols with brominating reagents: A combined experimental and theoretical study on α-versus β-keto lactam formation

Chemistry - A European Journal

Volumn 17, Issue 41, 2011, Pages 11559-11566

  Alcaide, Benito ^a   Almendros, Pedro ^b   Luna, Amparo ^a   Cembellín, Sara ^a,b   Arnó, Manuel ^c   Domingo, Luis R ^c  

^a UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

^b INSTITUTO DE QUÍMICA ORGÁNICA GENERAL   (Spain)

^c UNIVERSITY OF VALENCIA   (Spain)

Author keywords

allenes; chemoselectivity; lactams; reaction mechanisms; rearrangement

Indexed keywords

ALLENES; CHEMO-SELECTIVITY; LACTAMS; REACTION MECHANISM; REARRANGEMENT;

AMIDES; HYDROCARBONS;

ORGANIC ACIDS;

ALKADIENE; ALLENE; BETA LACTAM; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; LACTAM; N BROMOSUCCINIMIDE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; THEORETICAL MODEL;

ALKADIENES; BETA-LACTAMS; BROMOSUCCINIMIDE; INDICATORS AND REAGENTS; LACTAMS; MODELS, THEORETICAL; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 80053211492     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201101160     Document Type: Article

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