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Volumn 255, Issue 19-20, 2011, Pages 2371-2377

Self-assembling properties of (arylimido)vanadium(V) compounds

Author keywords

(Arylimido)vanadium(V); Alkoxido bridging; CH interaction; Highly ordered molecular arrangement; Imido bridging; Self assembling

Indexed keywords


EID: 80051475014     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ccr.2011.01.055     Document Type: Review
Times cited : (17)

References (81)
  • 67
    • 80051469744 scopus 로고    scopus 로고
    • For reviews on this subject after see
    • For reviews on this subject after 2000, see:.
    • (2000)
  • 79
    • 37049096497 scopus 로고
    • The structural parameter proposed by Addison and Reedijik, τ=(β-α)/60, for the coordination geometry of the five-coordinated complex shows τ=0.96 and 0.002 for 2b and 16, respectively, where α and β represent two basal angles (β>thomampers
    • Addison A.W., Rao T.N., Reedijk J., van Rijn J., Verschoor G.C. J. Chem. Soc., Dalton Trans. 1984, 1349. The structural parameter proposed by Addison and Reedijik, τ=(β-α)/60, for the coordination geometry of the five-coordinated complex shows τ=0.96 and 0.002 for 2b and 16, respectively, where α and β represent two basal angles (β>α). The parameters for an ideal square pyramidal and trigonal bipyramidal geometries are τ=0 (α=β=180°) and τ=1 (α=120° and β=180°), respectively. The τ value of 2b indicates that the coordination geometry around the vanadium atom is a trigonal-bipyramid. The coordination geometry around the vanadium atom of 16 is suggested to be a square pyramidal geometry from the τ value.
    • (1984) J. Chem. Soc., Dalton Trans. , pp. 1349
    • Addison, A.W.1    Rao, T.N.2    Reedijk, J.3    van Rijn, J.4    Verschoor, G.C.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.