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23
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0001559505
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3) and norbornene or acetone was observed.
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3) and norbornene or acetone was observed.
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24
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18844462731
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(b) Yamada, J.; Fujiki, M.; Nomura, K. Organometallics 2005, 24, 2248.
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descriptions concerning application as the catalysts
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Kilgore, U.J.1
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Examples for related complexes containing vanadium(V)-carbon double bonds: (a) Hessen, B.; Meetsma, A.; van Bolhuis, F.; Teuben, J. H. Organometallics 1990, 9, 1925.
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Examples for related complexes containing vanadium(V)-carbon double bonds: (a) Hessen, B.; Meetsma, A.; van Bolhuis, F.; Teuben, J. H. Organometallics 1990, 9, 1925.
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33847691467
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37
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61849174303
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Experimental details including syntheses, identification, and structural analysis reports are shown in the Supporting Information
-
Experimental details including syntheses, identification, and structural analysis reports are shown in the Supporting Information.
-
-
-
-
40
-
-
61849163392
-
-
The reaction of 1 with 1 equiv of 2,6-Me2C6H 3SH in n-hexane did not take place, as seen in the attempted reaction of 2.6d The reaction of 1 with 1 equiv of (CF3) 2CHOH in n-hexane at 25 °C recovered 1 in high yield even if the mixture was stirred overnight (> 12 h),10 and the results would be an interesting contrast to the fact that the reaction of 2 with (CF 3)2C(Me)OH cleanly afforded the corresponding alkoxide.6d Detailed results are shown in the Supporting Information
-
6d Detailed results are shown in the Supporting Information.
-
-
-
-
41
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61849175379
-
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We attempted the crystallographic analysis several times, and the structure could be solved, but the R value may not be satisfactory; these results are shown in the Supporting Information
-
We attempted the crystallographic analysis several times, and the structure could be solved, but the R value may not be satisfactory; these results are shown in the Supporting Information.
-
-
-
-
42
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0001284632
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2. Solan, G. A.; Cozzi, P. G.; Floriani, C; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1994, 13, 2572.
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2. Solan, G. A.; Cozzi, P. G.; Floriani, C; Chiesi-Villa, A.; Rizzoli, C. Organometallics 1994, 13, 2572.
-
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43
-
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36849065859
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For example: (a) N-Heterocyclic Carbenes in Synthesis; Nolan, S. P., Ed.; Wiley-VCH: Weinheim, Germany, 2006.
-
For example: (a) N-Heterocyclic Carbenes in Synthesis; Nolan, S. P., Ed.; Wiley-VCH: Weinheim, Germany, 2006.
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49
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61849104123
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-
10 but attempted isolation of any complexes from the mixture
-
10 but attempted isolation of any complexes from the mixture
-
-
-
-
50
-
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61849159350
-
-
n = 2.0. TON after 1 h was 390 if the reaction with 7 was conducted under the same conditions.
-
n = 2.0. TON after 1 h was 390 if the reaction with 7 was conducted under the same conditions.
-
-
-
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