From highly enantioselective catalytic reaction of 1,3-diynes with aldehydes to facile asymmetric synthesis of polycyclic compounds

Journal of the American Chemical Society

Volumn 133, Issue 30, 2011, Pages 11780-11794

  Turlington, Mark ^a   Du, Yuhao ^a   Ostrum, Samuel G ^a   Santosh, Vishaka ^a   Wren, Kathryne ^a   Lin, Tony ^a   Sabat, Michal ^a   Pu, Lin ^a  

^a UNIVERSITY OF VIRGINIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC SYNTHESIS; BULKY SUBSTITUENTS; CATALYTIC REACTIONS; CHEMOSELECTIVE; CHIRAL CENTERS; CYCLOADDITION PRODUCTS; DIASTEREO-SELECTIVITY; DIASTEREOSELECTIVE; DIELS-ALDER REACTION; ENANTIOSELECTIVE; ENYNE METATHESIS; OPTICALLY ACTIVE; PAUSON-KHAND; POLYCYCLIC COMPOUNDS; RING CLOSINGS; STRUCTURAL FRAMEWORKS; SYNTHETIC ROUTES; TRICYCLIC COMPOUNDS;

ALDEHYDES; CATALYSIS; CATALYSTS; CYCLOADDITION; MALEIC ANHYDRIDE; RHODIUM; STEREOSELECTIVITY;

SYNTHESIS (CHEMICAL);

2,2' DIHYDROXY 1,1' BINAPHTHYL; 6 PHENYLHEXA 1,3 DIYNE; ALDEHYDE DERIVATIVE; ALKYNE DERIVATIVE; BENZALDEHYDE; CARBON DIOXIDE; CYCLOHEXYLAMINE DERIVATIVE; DIENEDIYNE DERIVATIVE; ETHYLENE; MALEIC ANHYDRIDE; PENTANAL; POLYCYCLIC HYDROCARBON; RHODIUM; TIGLIANE DERIVATIVE; TITANIUM DERIVATIVE; UNCLASSIFIED DRUG; ZINC DERIVATIVE;

ADDITION REACTION; ARTICLE; ASYMMETRIC SYNTHESIS; CATALYSIS; CHEMICAL STRUCTURE; CHIRALITY; CYCLOADDITION; DIELS ALDER REACTION; ENANTIOSELECTIVITY; PAUSON KHAND REACTION; REACTION ANALYSIS; REACTION OPTIMIZATION; RING CLOSING METATHESIS; STEREOCHEMISTRY;

ALDEHYDES; CATALYSIS; CYCLIZATION; DIYNES; MOLECULAR STRUCTURE; POLYCYCLIC COMPOUNDS; STEREOISOMERISM;

EID: 79960878138     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja204289q     Document Type: Article

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