Total synthesis of absinthin

Journal of the American Chemical Society

Volumn 127, Issue 1, 2005, Pages 18-19

  Zhang, Weihe ^a,b   Luo, Shengjun ^a   Fang, Fang ^a   Chen, Qingshou ^a   Hu, Hanwei ^a   Jia, Xueshun ^b   Zhai, Hongbin ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b SHANGHAI UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ABSINTHIN; GUAIANOLIDE DERIVATIVE; SANTONIN; TRITERPENE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; CONFORMATION; DIELS ALDER REACTION; DIMERIZATION; MITSUNOBU REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; STEREOSPECIFICITY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ARTEMISIA ABSINTHIUM; SESQUITERPENES, GUAIANE; STEREOISOMERISM;

EID: 11844306006     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0439219     Document Type: Article

References (20)

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15. α-Santonin is commercially available from Aldrich Company ($17.40/5 g; $28.60/10 g) according to a 2003-2004 product catalog. For total synthesis of α-santonin, see: (a) Abe, Y.; Harukawa, T.; Ishikawa, H.; Miki, T.; Sumi, M.; Toga, T. J. Am. Chem. Soc. 1956, 78, 1422. (b) Marshall, J. A.; Wuts, P. G. M. J. Org. Chem. 1978, 43, 1086.
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20. 25D -170 ∼ -175 (c 2.0, alc)}.