Enantioselective prophenol-catalyzed addition of 1,3-diynes to aldehydes to generate synthetically versatile building blocks and diyne natural products

Journal of the American Chemical Society

Volumn 132, Issue 14, 2010, Pages 5186-5192

  Trost, Barry M ^a   Chan, Vincent S ^a   Yamamoto, Daisuke ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNYLS; BUILDING BLOCKES; CATALYTIC ADDITION; CATALYTIC TRANSFORMATION; CHIRAL RECOGNITION; DINUCLEAR; ENANTIOSELECTIVE; HYDROSILYLATIONS; NATURAL PRODUCTS; TOTAL SYNTHESIS; TRIPHENYLPHOSPHINE OXIDE;

KETONES; SYNTHESIS (CHEMICAL); ZINC;

ALDEHYDES;

8 HYDROXYHEPTADECA 1 EN 4,6 DIYN 3 YL ETHANOATE; ALDEHYDE; LEWIS BASE; NATURAL PRODUCT; NUCLEOPHILE; OPIOPANDIOL ACETATE; PANAXYNOL; PANAXYTRIOL; PENTA 2,4 DIYNYL ETHANOATE; PHENOL DERIVATIVE; PHOSPHINE OXIDE DERIVATIVE; POLYACETYLENE; SIPHONODIOL; STRONGYLODIOL A; STRONGYLODIOL B; UNCLASSIFIED DRUG; ZINC COMPLEX;

ANTIFUNGAL ACTIVITY; ANTINEOPLASTIC ACTIVITY; ANTIPROTOZOAL ACTIVITY; ARTICLE; CANCER CELL; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRAL CHROMATOGRAPHY; DRUG CYTOTOXICITY; DRUG ISOLATION; ENANTIOSELECTIVITY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MARINE ENVIRONMENT; NONHUMAN; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SPONGE (PORIFERA); STOICHIOMETRY; SYNTHESIS;

ALDEHYDES; BIOLOGICAL FACTORS; CATALYSIS; DIYNES; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PHENOLS; STEREOISOMERISM; ZINC;

EID: 77950833106     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja910656b     Document Type: Article

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