Unexpected cycloisomerizations of nonclassical carbocation intermediates in gold(I)-catalyzed homo-rautenstrauch cyclizations

Journal of Organic Chemistry

Volumn 76, Issue 14, 2011, Pages 5825-5831

  Wang, Guan ^a   Zou, Yue ^b   Li, Zhiming ^a   Wang, Quanrui ^a   Goeke, Andreas ^b  

^a FUDAN UNIVERSITY   (China)

^b Shanghai Givaudan Ltd   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOCATIONS; CHIRALITY TRANSFER; CYCLIZATIONS; CYCLOHEXENONES; CYCLOISOMERIZATIONS; GOLD CATALYSIS; MECHANISTIC STUDIES; OPTICALLY ACTIVE; PROPARGYL; PROPARGYLIC ESTER;

CATALYSIS; GOLD COMPOUNDS; KETONES; STEREOCHEMISTRY;

GOLD;

1 CYCLOPROPYL PROPARGYLIC ESTER; 2 CYCLOHEXENONE; ESTER DERIVATIVE; GOLD; UNCLASSIFIED DRUG;

ARTICLE; CARBOCATION; CATALYSIS; CHEMICAL PROCEDURES; CHIRALITY; CYCLIZATION; ISOMERIZATION;

EID: 79960188176     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo200416d     Document Type: Article

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