Swelling behaviour of PNIPAM-polyisoprene core-shell microgels at surface

Colloid and Polymer Science

Volumn 289, Issue 5-6, 2011, Pages 603-612

  Horecha, Marta ^a   Senkovskyy, Volodymyr ^a   Schneider, Konrad ^a   Kiriy, Anton ^a   Stamm, Manfred ^a  

^a LEIBNIZ INSTITUTE OF POLYMER RESEARCH DRESDEN   (Germany)

Author keywords

Core shell particles; Microgel; PNIPAM; Responsive surface; Switching effect

Indexed keywords

CORE-SHELL PARTICLE; MICROGEL; PNIPAM; RESPONSIVE SURFACES; SWITCHING EFFECT;

ACRYLIC MONOMERS; AMIDES; ANGLE MEASUREMENT; CONTACT ANGLE; HYDROPHILICITY; HYDROPHOBICITY; SHELLS (STRUCTURES); SWELLING;

GELS;

POLY(N ISOPROPYLACRYLAMIDE); POLYISOPRENE; POLYMER; UNCLASSIFIED DRUG; WATER;

ARTICLE; CONTACT ANGLE; CORE SHELL MICROGEL; HYDROGEL; HYDROPHILICITY; HYDROPHOBICITY; MATERIAL COATING; POLYMERIZATION; PRIORITY JOURNAL; SENSITIVITY ANALYSIS; SURFACE PROPERTY; WETTABILITY;

EID: 79959204792     PISSN: 0303402X     EISSN: 14351536     Source Type: Journal    
DOI: 10.1007/s00396-010-2312-9     Document Type: Article

References (74)

1. Schmaljohann D, Oswald J, Jørgensen B, Nitschke M, Beyerlein D, Werner C (2003) Thermo-responsive PNiAAm-g-PEG films for controlled cell detachment. Biomacromolecules 4:1733-1739 (Pubitemid 37455587)
2. Hoare T, Pelton R (2007) Engineering glucose swelling responses in poly(N-isopropylacrylamide)-based microgels. Macromolecules 40:670-678
3. Thies C (1996) In: Benita S (ed) Drugs and the pharmaceutical sciences, vol 73. Marcel Dekker, New York
4. Chen CW, Chen MQ, Serizawa T, Akashi M(1998) In situ synthesis and the catalytic properties of platinum colloids on polystyrene microspheres with surface-grafted poly(N-isopropylacrylamide). Chem Commun 7:831-832
5. Das M, Zhang H, Kumacheva E (2006) Microgels: old materials with new applications. Annu Rev Mater Res 36:117-142 (Pubitemid 44476827)
6. Suzuki D, McGrath JG, Kawaguchi H, Lyon LA (2007) Colloidal crystals of thermosensitive, core/shell hybrid microgels. J Phys Chem C 111:5667-5672 (Pubitemid 46686245)
7. Zhang G, Wang D, Gu ZZ, Hartmann J, Möhwald H (2005) Two-dimensional non-close-packing arrays derived from self-assembly of biomineralized hydrogel spheres and their patterning applications. Chem Mater 17:5268-5274 (Pubitemid 41527961)
8. Jiang P, McFariand MJ (2005) Wafer-scale periodic nanohole arrays templated from two-dimensional nonclose-packed colloidal crystals. J Am Chem Soc 127:3710-3711 (Pubitemid 40411407)
9. Retsos H, Gorodyska G, Kiriy A, Stamm M, Creton C (2005) Adhesion between chemically heterogeneous switchable polymeric brushes and an elastomeric adhesive. Langmuir 21:7722-7725 (Pubitemid 44323797)
10. Retsos H, Senkovskyy V, Kiriy A, Stamm M, Feldstein M, Creton C (2006) Controlling tack with bicomponent polymer brushes. Adv Mater 18:2624-2628 (Pubitemid 44563488)
11. Ruckenstein E, Lee SHJ (1987) Surface restructuring of polymers. Colloid Interface Sci 120:529-536
12. Lee SH, Ruckenstein EJ (1987) Stability of polymeric surfaces subjected to ultraviolet irradiation. Colloid Interface Sci 117:172-178
13. Hopken J, Moller M (1992) On the morphology of (perfluoroalkyl) alkanes. Macromolecules 25:2482-2489
14. Vaidya A, Chaudhury MK (2002) Synthesis and surface properties of environmentally responsive segmented polyurethanes. J Colloid Interface Sci 249:235-245 (Pubitemid 34953428)
15. Senshu K, Yamashita Sh, Mori H, ItoM, Hirao A, Nakahama S (1999) Time-resolved surface rearrangements of poly(2-hydroxyethyl methacrylate-block- isoprene) in response to environmental changes. Langmuir 15:1754-1762
16. Mori H, Hirao A, Nakahama S, Senshu K (1994) Synthesis and characterization of hydrophilic hydrophobic block-copolymers containing poly(2.3-dihydroxypropyl methacrylate). Macromolecules 27:4093-4100
17. Pientka Z, Oike H, Tezuka Y (1999) Atomic force microscopy study of environmental responses on poly(vinyl alcohol)-graft-polystyrene surfaces. Langmuir 15:3197-3201 (Pubitemid 32262865)
18. Minko S, Muller M, Motornov M, Nitschke M, Grundke K, Stamm M (2003) Two-level structured self-adaptive surfaces with reversibly tunable properties. J Am Chem Soc 125:3896-3900 (Pubitemid 36512381)
19. Senkovskyy V, Khanduyeva N, Komber H, Oertel U, Stamm M, Kuckling D, Kiriy A (2007) Conductive polymer brushes of regioregular head-to-tail poly(3-alkylthiophenes) via catalyst-transfer surface-initiated polycondensation. J Am Chem Soc 129:6626-6632 (Pubitemid 46799361)
20. Senkovskyy V, Tkachov R, Beryozkina T, Komber H, Oertel U, Horecha M, Bocharova V, Stamm M, Gevorgyan SA, Krebs FC, Kiriy A (2009) "Hairy" poly(3-hexylthiophene) particles prepared via surface-initiated kumada catalyst-transfer polycondensation. J Am Chem Soc 131:16445-16453
21. Hemmerle J, Roucoules V, Fleith G, Nardin M, Ball V, Lavalle P, Marie P, Voegel JC, Schaaf P (2005) Mechanically responsive films of variable hydrophobicity made of polyelectrolyte multilayers. Langmuir 21:10328-10331 (Pubitemid 41692101)
22. Tamber H, Johansen P, Merkle HP, Gander B (2005) Formulation aspects of biodegradable polymeric microspheres for antigen delivery. Adv Drug Deliv Rev 57:357-376 (Pubitemid 39555502)
23. Hammer DA, Discher DE (2001) Synthetic cells - self-assembling polymer membranes and bioadhesive colloids. Annu Rev Mater Sci 31:387-404 (Pubitemid 33073855)
24. Tsukruk V, Luzinov I, Larson K, Li S, McGrath DV (2001) Intralayer reorganization of photochromic molecular films. J Mater Sci Lett 20:873-876 (Pubitemid 32690837)
25. Caruso F, Caruso RA, Mohwald H (1998) Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating. Science 282:1111-1114 (Pubitemid 28516238)
26. Donath E, Sukhorukov GB, Caruso F, Davis S (1998) Novel hollow polymer shells by colloid-templated assembly of polyelectrolytes. Angew Chem Int Ed 37:2202-2205 (Pubitemid 28450870)
27. Johnson SA, Ollivier PJ, Mallouk TE (1999) Ordered mesoporous polymers of tunable pore size from colloidal silica templates. Science 283:963-965 (Pubitemid 29100248)
28. Bronich TK, Ouyang M, Kabanov VA, Eisenberg A, Szoka FC, Kabanov AV (2002) Synthesis of vesicles on polymer template. J Am Chem Soc 124:11872-11873
29. Holmesfarley SR, Reamey RH, Nuzzo R, McCarthy TJ, Whitesides GM (1987) Reconstruction of the interphase of oxidatively functionalized polyethylene and derivatives on heating. Langmuir 3:799-815 (Pubitemid 18522640)
30. Dowding PJ, Atkin R, Vincent B, Bouillot P (2004) Oil core-polymer shell microcapsules prepared by internal phase separation from emulsion droplets: I. Characterization and release rates for microcapsules with polystyrene shells. Langmuir 20:11374-11379
31. Dinsmore AD, Hsu MG, Nikolaides MG, Marques M, Bausch AR, Weitz DA (2002) Colloidosomes: selectively permeable capsules composed of colloidal particles. Science 298:1006-1009 (Pubitemid 35247303)
32. Hotz J, Meier W (1998) Vesicle-templated polymer hollow spheres. Langmuir 14:1031-1036 (Pubitemid 128620501)
33. Qian J, Wu FP (2007) Synthesis of thermosensitive hollow spheres via a one-pot process. Chem Mater 19:5839-5841
34. Peyratout CS, Dahne L (2004) Tailor-made polyelectrolyte microcapsules: from multilayers to smart containers. Angew Chem Int Ed 43:3762-3783 (Pubitemid 39257491)
35. Velev OD, Furusawa K (1996) Assembly of latex particles by using emulsion droplets as templates: 1. Microstructured hollow spheres. Langmuir 12:2374-2384 (Pubitemid 126567786)
36. Zhao B, Brittain WJ (1999) Synthesis of tethered polystyrene-block- poly(methyl methacrylate) monolayer on a silicate substrate by sequential carbocationic polymerization and atom transfer radical polymerization. J Am Chem Soc 121:3557-3558 (Pubitemid 29190936)
37. Sidorenko A, Minko S, Schenk-Meuser K, Duschner H, Stamm M (1999) Switching of polymer brushes. Langmuir 15:8349-8355 (Pubitemid 30514733)
38. Tiarks F, Landfester K, Antonietti M (2001) Preparation of polymeric nanocapsules by miniemulsion polymerization. Langmuir 17:908-918 (Pubitemid 32873073)
39. Makal U, Wynne KJ (2005) Water induced hydrophobic surface. Langmuir 21:3742-3745 (Pubitemid 40654573)
40. Makal U, Uslu N, Wynne KJ (2007) Water makes it hydrophobic: contraphilic wetting for polyurethanes with soft blocks having semifluorinated and 5, 5-dimethylhydantoin side chains. Langmuir 23:209-216 (Pubitemid 46129726)
41. Cassie ABD (1948) Contact angles. Discuss Faraday Soc 3:11-16
42. Wenzel RN (1936) Resistance of solid surfaces to wetting by water. Ind Eng Chem 28:988-994
43. Lamb DJ, Anstey JF, Fellows CM, Monteiro MJ, Gilbert RJ (2001) Modification of natural and artificial polymer colloids by "topology- controlled" emulsion polymerization. Biomacromolecules 2:518-525
44. Horcas I, Fernandez R, Gomez-Rodriguez JM, Colchero J, Gomez-Herrero J, Baro AM (2007) WSXM: a software for scanning probe microscopy and a tool for nanotechnology. Rev Sci Instrum 78:013705
45. Hutter JL, Bechhoefer J (1993) Calibration of atomic-force microscope tips. Rev Sci Instrum 64:1868-1873
46. Ionov L, Houbenov N, Sidorenko A, Stamm M (2004) Inverse and reversible switching gradient surfaces from mixed polyelectrolyte brushes. Langmuir 20:9916-9919
47. Xu FJ, Neoh KG, Kang ET (2009) Bioactive surfaces and biomaterials via atom transfer radical polymerization. Prog Polym Sci 34:719-761
48. Pelton RH, Chibante P (1986) Preparation of aqueous lattices with N-isopropylacrylamide. Colloids Surf 20:247-256
49. Tanaka H (1979) Hofmann reaction of polyacrylamide - relationship between reaction condition and degree of polymerization of polyvinylamine. J Polym Sci A Polym Chem 17:1239-1245
50. Yamamoto Y, Sefton MV (1996) Hofmann degradation of acrylamide copolymer: synthesis of amine functionalized thermoplastic hydrogel. J Appl Polym Sci 61:351-358 (Pubitemid 126535242)
51. Zhang LH, Kauffman GS, Pesti JA, Yin JG (1997) Rearrangement of N-alpha-protected L-asparagines with iodosobenzene diacetate. A practical route to beta-amino-l-alanine derivatives. J Org Chem 62:6918-6920 (Pubitemid 127494628)
52. Brazel CS, Peppas NA (1995) Synthesis and characterization of thermomechanically and chemomechanically responsive poly(N-isopropylacrylamide- co-methacrylic acid) hydrogels. Macromolecules 28:8016-8020
53. Zhou S, Chu B (1998) Synthesis and volume phase transition of poly (methacrylic acid-co-N-isopropylacrylamide) microgel particles in water. J Phys Chem B 102:1364-1371 (Pubitemid 128600631)
54. Nerapusri V, Keddie JL, Vincent B, Bushnak IA (2006) Swelling and deswelling of adsorbed microgel monolayers triggered by changes in temperature, pH, and electrolyte concentration. Langmuir 22:5036-5041 (Pubitemid 44012068)
55. Lopez-Leon T, Ortega-Vinuesa JL, Bastos-Gonzalez B, Elaissari A (2006) Cationic and anionic poly(N-isopropylacrylamide) based submicron gel particles: electrokinetic properties and colloidal stability. J Phys Chem B 110:4629-4636
56. Tsuji S, Kawaguchi H (2005) Self-assembly of poly(N-isopropylacrylamide)- carrying microspheres into two-dimensional colloidal arrays. Langmuir 21:2434-2437 (Pubitemid 40421892)
57. Serpe MJ, Jones CD, Lyon LA (2003) Layer-by-layer deposition of thermoresponsive microgel thin films. Langmuir 19:8759-8764
58. Khanduyeva N, Senkovskyy V, Beryozkina T, Horecha M, Stamm M, Uhrich C, Riede M, Leo K, Kiriy A (2009) Surface engineering using kumada catalyst-transfer polycondensation (KCTP): preparation and structuring of poly(3-hexylthiophene)-based graft copolymer brushes. J Am Chem Soc 331:153-161
59. Beryozkina T, Boyko K, Khanduyeva N, Senkovskyy V, Horecha M, Oertel U, Simon F, Komber H, Stamm M, Kiriy A (2009) Grafting of polyfluorene by surface-initiated suzuki polycondensation. Angew Chem 48:2695-2698
60. Flory PJ, Rabjohn N, Shaffer MC (1949) Dependence of elastic properties of vulcanized rubber on the degree of cross linking. J Polym Sci 4:225-245
61. Moulton A, Grosjean J, Owen G (2005) In: The Moulton formulae and methods - directly usable for calculations in mechanical engineering. Professional Engineering Publishing, London, UK
62. NashWA (1992) In: Schaum's outline series theory and problems of statics and mechanics ofmaterials, chap 10.McGraw Hill, New York
63. Hicks TG (2003) In: Pocket guide mechanical engineering formulas, sect 3. McGraw Hill, New York
64. Meunier F, Elaissari A, Pichot C (1995) Preparation and characterization of cationic poly(N-Isopropylacrylamide) copolymer latex. Polym Adv Technol 6:489-496
65. Pelton RH, Pelton HM, Morphesis A, Rowell RL (1989) Particle sizes and electrophoretic mobilities of poly(N-isopropylacrylamide) latex. Langmuir 5:816-818
66. Wu X, Pelton RH, Hamielec AE, Woods DR, McPhee W (1994) The kinetics of poly(N-isopropylacrylamide) microgel latex formation. Colloid Polym Sci 272:467-477
67. Saunders BR (2004) On the structure of poly(N-isopropylacrylamide) microgel particles. Langmuir 2:3925-3932
68. Mason TG, Lin MY (2005) Density profiles of temperaturesensitive microgel particles. Phys Rev E 71:040801
69. Stieger M, Pedersen JS, Lindner P, Richtering W (2004) Are thermoresponsive microgels model systems for concentrated colloidal suspensions? A rheology and small-angle neutron scattering study. Langmuir 20:7283-7292
70. Fernandez-Barbero A, Fernandez-Nieves I, Grillo E, Lopez-Cabarco (2002) Structural modifications in the swelling of inhomogeneous microgels by light and neutron scattering. Phys Rev E 66:051803
71. Saunders BR, Laajam N, Daly E, Teow S, Hu X, Stepto R (2009) Microgels: from responsive polymer colloids to biomaterials. Adv Colloid Interface Sci 147-148:251-262
72. Christensen ML, Keiding K (2005) Study of the compositional heterogeneity in poly (N-isopropylacrylamide-acrylic acid) microgels by potentiometric titration experiments. Colloids Surf A Physicochem Eng Asp 252:61-69, It is believed that during the formation of PNIPAM microgels, MBA cross-linker was consumed faster and therefore preferentially incorporated into the microgels. As a result of the progressive depletion of the polymerization mixture by the cross-linker, cross-linking density for the PNIPAM microgels will decrease from the centre to the periphery. It can be assumed that at certain conditions "hairy" microgels will be formed, where the highly crosslinked core is decorated by branched or even linear dangling polymer chains
73. Horecha M, Senkovskyy V, Synytska A, Stamm M, Chervanyov A, Kiriy A (2010) Ordered surface structures from PNIPAM-based loosely packed microgel particles. Soft Matter published in web 21.09.2010. doi:10.1039/C0SM00634C
74. Hofl S, Zitzler L, Hellweg T, Herminghaus S, Mugele F (2007) Volume phase transition of "smart" microgels in bulk solution and adsorbed at an interface: a combined AFM, dynamic light, and small angle neutron scattering study. Polymer 48:245-254