메뉴 건너뛰기




Volumn 283, Issue 5404, 1999, Pages 963-965

Ordered mesoporous polymers of tunable pore size from colloidal silica templates

Author keywords

[No Author keywords available]

Indexed keywords

COLLOIDS; NANOSTRUCTURED MATERIALS; ORGANIC COMPOUNDS; PARTICLE SIZE ANALYSIS; POROSITY; SILICA;

EID: 0033548120     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.283.5404.963     Document Type: Article
Times cited : (642)

References (42)
  • 5
    • 85046172804 scopus 로고    scopus 로고
    • O. D. Velev, T. A. Jede, R. F. Lobo, A. M. Lenhoff, Nature 389, 447 (1997); A. Imhof and D. J. Pine, ibid., p. 948; B. T. Holland, C. F. Blanford, A. Stein, Science 281, 538 (1998); J. E. G. J. Wijnhoven and W. L. Vos, ibid., p. 802.
    • (1997) Nature , vol.389 , pp. 447
    • Velev, O.D.1    Jede, T.A.2    Lobo, R.F.3    Lenhoff, A.M.4
  • 6
    • 0345090787 scopus 로고    scopus 로고
    • O. D. Velev, T. A. Jede, R. F. Lobo, A. M. Lenhoff, Nature 389, 447 (1997); A. Imhof and D. J. Pine, ibid., p. 948; B. T. Holland, C. F. Blanford, A. Stein, Science 281, 538 (1998); J. E. G. J. Wijnhoven and W. L. Vos, ibid., p. 802.
    • Nature , pp. 948
    • Imhof, A.1    Pine, D.J.2
  • 7
    • 0032563228 scopus 로고    scopus 로고
    • O. D. Velev, T. A. Jede, R. F. Lobo, A. M. Lenhoff, Nature 389, 447 (1997); A. Imhof and D. J. Pine, ibid., p. 948; B. T. Holland, C. F. Blanford, A. Stein, Science 281, 538 (1998); J. E. G. J. Wijnhoven and W. L. Vos, ibid., p. 802.
    • (1998) Science , vol.281 , pp. 538
    • Holland, B.T.1    Blanford, C.F.2    Stein, A.3
  • 8
    • 0032493893 scopus 로고    scopus 로고
    • O. D. Velev, T. A. Jede, R. F. Lobo, A. M. Lenhoff, Nature 389, 447 (1997); A. Imhof and D. J. Pine, ibid., p. 948; B. T. Holland, C. F. Blanford, A. Stein, Science 281, 538 (1998); J. E. G. J. Wijnhoven and W. L. Vos, ibid., p. 802.
    • Science , pp. 802
    • Wijnhoven, J.E.G.J.1    Vos, W.L.2
  • 10
    • 0032582488 scopus 로고    scopus 로고
    • A. A. Zakhidov, et al., Science 282, 897 (1998); A. van Blaaderen, ibid., p. 887.
    • (1998) Science , vol.282 , pp. 897
    • Zakhidov, A.A.1
  • 11
    • 0032582488 scopus 로고    scopus 로고
    • A. A. Zakhidov, et al., Science 282, 897 (1998); A. van Blaaderen, ibid., p. 887.
    • Science , pp. 887
    • Van Blaaderen, A.1
  • 17
    • 0028027769 scopus 로고
    • C.-G. Wu and T. Bein, ibid. 266, 1013 (1994); ibid. 264, 1757 (1994).
    • (1994) Science , vol.266 , pp. 1013
    • Wu, C.-G.1    Bein, T.2
  • 18
    • 0028457096 scopus 로고
    • C.-G. Wu and T. Bein, ibid. 266, 1013 (1994); ibid. 264, 1757 (1994).
    • (1994) Science , vol.264 , pp. 1757
  • 21
    • 0001098209 scopus 로고
    • T. Kyotani, N. Sonobe, A. Tomita, Nature 331, 331 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 4, 573 (1988); N. Sonobe, T. Kyotani, Y. Hishiyama, M. Shiraishi, A. Tomita, J. Phys. Chem. 92, 2, 7029 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 28, 483 (1990); ibid. 29, 9, 61 (1991); T. Kyotani, H. Yamada, N. Sonobe, A. Tomita, ibid. 32, 2, 627 (1994); T. Kyotani, T. Mori, A. Tomita, Chem. Mater. 6, 2138 (1994).
    • (1988) Nature , vol.331 , pp. 331
    • Kyotani, T.1    Sonobe, N.2    Tomita, A.3
  • 22
    • 0023862792 scopus 로고
    • T. Kyotani, N. Sonobe, A. Tomita, Nature 331, 331 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 4, 573 (1988); N. Sonobe, T. Kyotani, Y. Hishiyama, M. Shiraishi, A. Tomita, J. Phys. Chem. 92, 2, 7029 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 28, 483 (1990); ibid. 29, 9, 61 (1991); T. Kyotani, H. Yamada, N. Sonobe, A. Tomita, ibid. 32, 2, 627 (1994); T. Kyotani, T. Mori, A. Tomita, Chem. Mater. 6, 2138 (1994).
    • (1988) Carbon , vol.4 , pp. 573
    • Sonobe, N.1    Kyotani, T.2    Tomita, A.3
  • 23
    • 0024142578 scopus 로고
    • T. Kyotani, N. Sonobe, A. Tomita, Nature 331, 331 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 4, 573 (1988); N. Sonobe, T. Kyotani, Y. Hishiyama, M. Shiraishi, A. Tomita, J. Phys. Chem. 92, 2, 7029 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 28, 483 (1990); ibid. 29, 9, 61 (1991); T. Kyotani, H. Yamada, N. Sonobe, A. Tomita, ibid. 32, 2, 627 (1994); T. Kyotani, T. Mori, A. Tomita, Chem. Mater. 6, 2138 (1994).
    • (1988) J. Phys. Chem. , vol.92 , Issue.2 , pp. 7029
    • Sonobe, N.1    Kyotani, T.2    Hishiyama, Y.3    Shiraishi, M.4    Tomita, A.5
  • 24
    • 0025682547 scopus 로고
    • T. Kyotani, N. Sonobe, A. Tomita, Nature 331, 331 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 4, 573 (1988); N. Sonobe, T. Kyotani, Y. Hishiyama, M. Shiraishi, A. Tomita, J. Phys. Chem. 92, 2, 7029 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 28, 483 (1990); ibid. 29, 9, 61 (1991); T. Kyotani, H. Yamada, N. Sonobe, A. Tomita, ibid. 32, 2, 627 (1994); T. Kyotani, T. Mori, A. Tomita, Chem. Mater. 6, 2138 (1994).
    • (1990) Carbon , vol.28 , pp. 483
    • Sonobe, N.1    Kyotani, T.2    Tomita, A.3
  • 25
    • 0001098209 scopus 로고
    • T. Kyotani, N. Sonobe, A. Tomita, Nature 331, 331 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 4, 573 (1988); N. Sonobe, T. Kyotani, Y. Hishiyama, M. Shiraishi, A. Tomita, J. Phys. Chem. 92, 2, 7029 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 28, 483 (1990); ibid. 29, 9, 61 (1991); T. Kyotani, H. Yamada, N. Sonobe, A. Tomita, ibid. 32, 2, 627 (1994); T. Kyotani, T. Mori, A. Tomita, Chem. Mater. 6, 2138 (1994).
    • (1991) Carbon , vol.29 , Issue.9 , pp. 61
  • 26
    • 0028058313 scopus 로고
    • T. Kyotani, N. Sonobe, A. Tomita, Nature 331, 331 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 4, 573 (1988); N. Sonobe, T. Kyotani, Y. Hishiyama, M. Shiraishi, A. Tomita, J. Phys. Chem. 92, 2, 7029 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 28, 483 (1990); ibid. 29, 9, 61 (1991); T. Kyotani, H. Yamada, N. Sonobe, A. Tomita, ibid. 32, 2, 627 (1994); T. Kyotani, T. Mori, A. Tomita, Chem. Mater. 6, 2138 (1994).
    • (1994) Carbon , vol.32 , Issue.2 , pp. 627
    • Kyotani, T.1    Yamada, H.2    Sonobe, N.3    Tomita, A.4
  • 27
    • 0000109937 scopus 로고
    • T. Kyotani, N. Sonobe, A. Tomita, Nature 331, 331 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 4, 573 (1988); N. Sonobe, T. Kyotani, Y. Hishiyama, M. Shiraishi, A. Tomita, J. Phys. Chem. 92, 2, 7029 (1988); N. Sonobe, T. Kyotani, A. Tomita, Carbon 28, 483 (1990); ibid. 29, 9, 61 (1991); T. Kyotani, H. Yamada, N. Sonobe, A. Tomita, ibid. 32, 2, 627 (1994); T. Kyotani, T. Mori, A. Tomita, Chem. Mater. 6, 2138 (1994).
    • (1994) Chem. Mater. , vol.6 , pp. 2138
    • Kyotani, T.1    Mori, T.2    Tomita, A.3
  • 29
    • 0015134753 scopus 로고
    • J. N. Weber, E. W. White, J. Lebiedzik, Nature 233, 337 (1971); R. L. White, J. N. Weber, E. W. White, Science 176, 1922 (1972); D. M. Roy and S. K. Linnehan, Nature 247, 220 (1974).
    • (1971) Nature , vol.233 , pp. 337
    • Weber, J.N.1    White, E.W.2    Lebiedzik, J.3
  • 30
    • 0015134753 scopus 로고
    • J. N. Weber, E. W. White, J. Lebiedzik, Nature 233, 337 (1971); R. L. White, J. N. Weber, E. W. White, Science 176, 1922 (1972); D. M. Roy and S. K. Linnehan, Nature 247, 220 (1974).
    • (1972) Science , vol.176 , pp. 1922
    • White, R.L.1    Weber, J.N.2    White, E.W.3
  • 31
    • 0016401478 scopus 로고
    • J. N. Weber, E. W. White, J. Lebiedzik, Nature 233, 337 (1971); R. L. White, J. N. Weber, E. W. White, Science 176, 1922 (1972); D. M. Roy and S. K. Linnehan, Nature 247, 220 (1974).
    • (1974) Nature , vol.247 , pp. 220
    • Roy, D.M.1    Linnehan, S.K.2
  • 32
    • 0028594017 scopus 로고
    • C. R. Martin, Science 266, 1961 (1994); Acc. Chem. Res. 28, 8, 61 (1995); Chem. Mater. 8, 1739 (1996); B. B. Lakshmi, P. K. Korhout, C. R. Martin, ibid. 9, 857 (1997).
    • (1994) Science , vol.266 , pp. 1961
    • Martin, C.R.1
  • 33
    • 0028594017 scopus 로고
    • C. R. Martin, Science 266, 1961 (1994); Acc. Chem. Res. 28, 8, 61 (1995); Chem. Mater. 8, 1739 (1996); B. B. Lakshmi, P. K. Korhout, C. R. Martin, ibid. 9, 857 (1997).
    • (1995) Acc. Chem. Res. , vol.28 , Issue.8 , pp. 61
  • 34
    • 0000279453 scopus 로고    scopus 로고
    • C. R. Martin, Science 266, 1961 (1994); Acc. Chem. Res. 28, 8, 61 (1995); Chem. Mater. 8, 1739 (1996); B. B. Lakshmi, P. K. Korhout, C. R. Martin, ibid. 9, 857 (1997).
    • (1996) Chem. Mater. , vol.8 , pp. 1739
  • 35
    • 0000907697 scopus 로고    scopus 로고
    • C. R. Martin, Science 266, 1961 (1994); Acc. Chem. Res. 28, 8, 61 (1995); Chem. Mater. 8, 1739 (1996); B. B. Lakshmi, P. K. Korhout, C. R. Martin, ibid. 9, 857 (1997).
    • (1997) Chem. Mater. , vol.9 , pp. 857
    • Lakshmi, B.B.1    Korhout, P.K.2    Martin, C.R.3
  • 39
    • 0025522035 scopus 로고
    • Silica colloids were made by a slight modification of the technique described by K. Osseo-Asare and F. J. Arriagada [Colloids Surf. 50, 321 (1990)]. A micro-emulsion was prepared by rapidly stirring 150 ml of cyclohexane, 6 ml of n-hexanol, 19 ml of Triton N-101, 7 ml of water, and 1.7 ml of 28% aqueous ammonia. To this was added 10 ml of tetraethyl orthosilicate, and the mixture was stirred at ambient temperature for 2 days. Most of the solvent was removed by rotary evaporation, and 100 ml of ethanol was added. The mixture was stirred for 1 hour, then centrifuged. The product solid was resuspended in ethanol and centrifuged three times, then dried at 80°C TEM images showed that the particle diameter was 35 ± 2 nm. Tablular pellets (0.7 cm in diameter; thickness. 0.3 cm) were made from the dry powder by means of a pellet press.
    • (1990) Colloids Surf. , vol.50 , pp. 321
    • Osseo-Asare, K.1    Arriagada, F.J.2
  • 40
    • 0345090781 scopus 로고    scopus 로고
    • note
    • The pore size plots in Fig. 4B were calculated from adsorption isotherms with a model that is optimized for much smaller slit-shaped pores (24). The maxima are systematically shifted to pore diameters larger than are found by TEM (Figs. 1 through 3).
  • 42
    • 0344228673 scopus 로고    scopus 로고
    • note
    • This work was supported by grant GM-43844 from NIH. We thank R. Walsh and the Electron Microscope Facility for the Life Sciences in the Biotechnology Institute at Pennsylvania State University for the use of the TEM and S. Kumar, P. Sokol, and J. Patel for helpful discussions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.