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Volumn 14, Issue 8, 2011, Pages 1306-1310

Synthesis, structure, and catalytic behavior of a PSiP pincer-type iridium(III) complex

Author keywords

Iridium; Pincer; Silyl; Transfer hydrogenation; Tridentate ligands

Indexed keywords


EID: 79958778222     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.05.018     Document Type: Article
Times cited : (38)

References (64)
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    • note
    • iPrOH, 0.1 mmol) under nitrogen. The resulting brown solution was stirred at room temperature for 10 min. The mixture was then heated at 80 °C. The mixture turned pale yellowish after the reaction was complete. The yields were determined by GC analysis with n-undecane as internal standard, and the identities of the hydrogenation products were confirmed by comparison to authentic samples.
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    • 2 = 0.0435 [I > 2σ(I)]. Structural data for was collected on a Bruker Smart Apex CCD with graphite-monochromated Mo-Kα radiation (λ = 0.71073 Å) at 153 K. The structure was solved by direct methods and refined with the full-matrix least-squares technique using the SHELXS-97 and SHELXL-97 programs.
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