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0030883527
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2 is followed by transfer-hydrogenation of the ketone group. Complexes 2 and 3 were inactive under these conditions. See also K. Matsumura, S. Hashiguchi, T. Ikariya, R. Noyori, J. Am. Chem. Soc. 1997, 119, 8738-8739, and references therein.
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23
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33747532097
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note
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Analysis of these aldol products (GC-MS) in the reaction with cyclohexanone revealed that they were mainly the result of reaction of acetone with the substrate.
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24
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