Four-coordinate, trigonal pyramidal Pt(II) and Pd(II) complexes

Journal of the American Chemical Society

Volumn 132, Issue 40, 2010, Pages 13975-13977

  Tsay, Charlene ^b   Mankad, Neal P ^b   Peters, Jonas C ^a  

^a California Institute of Technology   (United States)

^b NONE

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATED LIGANDS; ISOSTRUCTURAL; PALLADIUM COMPLEXES;

DYES; INTERNET PROTOCOLS; LIGANDS; PALLADIUM; PALLADIUM COMPOUNDS; PLATINUM; POSITIVE IONS; TOLUENE;

PLATINUM COMPOUNDS;

PALLADIUM COMPLEX; PLATINUM COMPLEX;

ARTICLE; COMPLEX FORMATION; GEOMETRY; LOW TEMPERATURE; MOLECULAR INTERACTION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE; X RAY DIFFRACTION;

EID: 77957696819     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105284p     Document Type: Article

References (33)

1. Lersch, M. and Tilset, M. Chem. Rev. 2005, 105, 2471-2526
2. Stahl, S. S., Labinger, J. A., and Bercaw, J. E. Angew. Chem., Int. Ed. 1998, 37, 2181-2192
3. Periana, R. A., Taube, D. J., Gamble, S., Taube, H., Satoh, T., and Fujii, H. Science 1998, 280, 560-564
4. Sen, A. Acc. Chem. Res. 1998, 31, 550-557
5. Peters, J. C., Thomas, J. C., Thomas, C. M., and Betley, T. A. In Activation and Functionalization of C-H Bonds; Goldberg, K. and Goldman, A., Eds. 2004; Vol. 885.
6. Shilov, A. E. Activation of Saturated Hydrocarbons by Transition Metal Complexes; D. Reidel: Dordrecht, The Netherlands, 1984.
7. Mankad, N. P., Whited, M. T., and Peters, J. C. Angew. Chem., Int. Ed. 2007, 46, 5768-5771
8. Ostendorf, D., Landis, C., and Grützmacher, H. Angew. Chem., Int. Ed. 2006, 45, 5169-5173
9. 3: Goodman, J., Grushin, V. V., Larichev, R. B., Macgregor, S. A., Marshall, W. J., and Roe, D. C. J. Am. Chem. Soc. 2009, 131, 4236-4238
10. Addison, A. W., Rao, T. N., Reedijk, J., van Rijn, J., and Verschoor, G. C. J. Chem. Soc., Dalton Trans. 1984, 1349-1356
11. Stahl, S. S., Labinger, J. A., and Bercaw, J. E. J. Am. Chem. Soc. 1996, 118, 5961-5976
12. Heiberg, H., Swang, O., Ryan, O. B., and Gropen, O. J. Phys. Chem. A 1999, 103, 10004-10008
13. Wick, D. D. and Goldberg, K. I. J. Am. Chem. Soc. 1997, 119, 10235-10236
14. Wick, D. D., Reynolds, K. A., and Jones, W. D. J. Am. Chem. Soc. 1999, 121, 3974-3983
15. Thomas, J. C. and Peters, J. C. J. Am. Chem. Soc. 2003, 125, 8870-8888
16. Schneider, J. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 1068-1075
17. Bengali, A. A., Schultz, R. H., Moore, C. B., and Bergman, R. G. J. Am. Chem. Soc. 1994, 116, 9585-9589
18. Lian, T., Bromberg, S. E., Yang, H., Proulx, G., Bergman, R. G., and Harris, C. B. J. Am. Chem. Soc. 1996, 118, 3769-3770
19. Geftakis, S. and Ball, G. E. J. Am. Chem. Soc. 1998, 120, 9953-9954
20. Bernskoetter, W. H., Schauer, C. K., Goldberg, K. I., and Brookhart, M. Science 2009, 326, 553-556
21. Three residual electron density peaks are generated near the fourth, meta carbon (distances to the carbon atom range from 0.88 Å to 1.49 Å), making its C-H distance ambiguous.
22. Brookhart, M., Green, M. L. H., and Parkin, G. Proc. Natl. Acad. Sci. U.S.A. 2007, 104, 6908-6914
23. Evans, D. R., Drovetskaya, T., Bau, R., Reed, C. A., and Boyd, P. D. W. J. Am. Chem. Soc. 1997, 119, 3633-334
24. Castro-Rodriguez, I., Nakai, H., Gantzel, P., Zakharov, L. N., Rheingold, A. L., and Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734-15735
25. Yang, L., Powell, D. R., and Houser, R. P. Dalton Trans. 2007, 955-964
26. Stahl, S. S., Labinger, J. A., and Bercaw, J. E. Inorg. Chem. 1998, 37, 2422-2431
27. Bontemps, S., Bouhadir, G., Gu, W., Mercy, M., Chen, C.-H., Foxman, B. M., Maron, L., Ozerov, O. V., and Bourissou, D. Angew. Chem., Int. Ed. 2008, 47, 1481-1484
28. Sircoglou, M., Bontemps, S., Bouhadir, G., Saffon, N., Miqueu, K., Gu, W., Mercy, M., Chen, C.-H., Foxman, B. M., Laurent, M., Ozerov, O. V., and Bourissou, D. J. Am. Chem. Soc. 2008, 130, 16729-16738
29. Parkin, G. In Comprehensive Organometallic Chemistry; 2007; Vol. 1, pp 1 - 57.
30. 8 Pd butterfly structure type has been reported: Frech, C. M., Shimon, L. J. W., and Milstein, D. Angew. Chem., Int. Ed. 2005, 44, 1709-1711
31. For representative Pd(II) structures significantly distorted from planarity, see
32. Bröring, M. and Brandt, C. D. J. Chem. Soc., Dalton Trans. 2002, 1391-1395
33. Yeo, J. S. L., Vittal, J. J., and Hor, T. S. A. Chem. Commun. 1999, 1477-1478