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31
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85034549643
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note
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12 and an unidentified red crystalline byproduct from crude 2 by flash chromatography and recrystallization without losing a large amount of 2.
-
-
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-
32
-
-
85034558858
-
-
note
-
w = 0.065. The structure was solved by the direct method (SIR92) and refined by full-matrix least-squares using the crystal structure analysis package teXsan on a Silicon Graphics Indy computer. Positions of non-hydrogen atoms were refined anisotropically.
-
-
-
-
33
-
-
3843147727
-
-
2 is known to undergo cis-trans isomerization at 80°C (trans:cis = 65:36 at 84.6°C in Decalin), and the cis form is suggested to react with benzene: Pomeroy, R. K.; Graham, W. A. G. Con. J. Chem. 1978, 53, 2985.
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84986397941
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Complex 4 was prepared by applying Fink's procedure described in the following paper: Fink, W. Helv. Chim. Acta 1976, 59, 606.
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85034531542
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note
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6-toluene ligand in 3 for p-xylene, mesitylene, anisole, and 4,4′-bitolyl ligands.
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37
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