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Volumn 30, Issue 10, 2011, Pages 2712-2720

1,2-C-H activation of benzene promoted by (Arylimido)vanadium(V)-alkylidene complexes: Isolation of the alkylidene, benzyne complexes

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLIDENE COMPLEXES; ALKYLIDENES; ARYLIMIDO; BENZYNE COMPLEXES; DIALKYL COMPLEXES; N-HEXANE;

EID: 79956099379     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om200086n     Document Type: Article
Times cited : (66)

References (79)
  • 6
    • 0037297597 scopus 로고    scopus 로고
    • Related reviews for olefin polymerization catalysts including vanadium complexes
    • Related reviews for olefin polymerization catalysts including vanadium complexes: Gambarotta, S. Coord. Chem. Rev. 2003, 237, 229
    • (2003) Coord. Chem. Rev. , vol.237 , pp. 229
    • Gambarotta, S.1
  • 10
    • 33845657716 scopus 로고    scopus 로고
    • Bevy, L. P., Ed.; Nova Science Publishers, Inc.: New York
    • Nomura, K. In New Developments in Catalysis Research; Bevy, L. P., Ed.; Nova Science Publishers, Inc.: New York, 2005; p 199.
    • (2005) New Developments in Catalysis Research , pp. 199
    • Nomura, K.1
  • 12
    • 0001422883 scopus 로고
    • For examples, see
    • For examples, see: Schrock, R. R. Acc. Chem. Res. 1990, 23, 158
    • (1990) Acc. Chem. Res. , vol.23 , pp. 158
    • Schrock, R.R.1
  • 14
    • 14644441385 scopus 로고    scopus 로고
    • Grubbs, R. H., Ed.; Wiley-VCH: Weinheim, Germany
    • Schrock, R. R. In Handbook of Metathesis; Grubbs, R. H., Ed.; Wiley-VCH: Weinheim, Germany, 2003; Vol. 1, p 8.
    • (2003) Handbook of Metathesis , vol.1 , pp. 8
    • Schrock, R.R.1
  • 15
    • 33845559693 scopus 로고
    • For examples, see
    • For examples, see: Schrock, R. R. Acc. Chem. Res. 1979, 12, 98
    • (1979) Acc. Chem. Res. , vol.12 , pp. 98
    • Schrock, R.R.1
  • 22
    • 1442360753 scopus 로고    scopus 로고
    • Wiley-VCH: Weinheim, Germany
    • Grubbs, R. H., Ed. Handbook of Metathesis; Wiley-VCH: Weinheim, Germany, 2003; Vols. 1-3.
    • (2003) Handbook of Metathesis , vol.13
    • Grubbs, R.H.1
  • 38
    • 79956061659 scopus 로고    scopus 로고
    • note
    • 5) confirmed by the crystallographic analysis] by C-H activation. The present article describes a detailed study concerning these observations.
  • 40
    • 0037395422 scopus 로고    scopus 로고
    • For example (1,2-C-H bond activation of benzene using Mo, W), see
    • For example (1,2-C-H bond activation of benzene using Mo, W), see: Pamplin, C. B.; Legzdins, P. Acc. Chem. Res. 2003, 36, 223
    • (2003) Acc. Chem. Res. , vol.36 , pp. 223
    • Pamplin, C.B.1    Legzdins, P.2
  • 49
    • 0001046250 scopus 로고
    • For example (1,2-C-H bond activation of benzene using Ti), see
    • For example (1,2-C-H bond activation of benzene using Ti), see: McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629
    • (1982) Organometallics , vol.1 , pp. 1629
    • McDade, C.1    Green, J.C.2    Bercaw, J.E.3
  • 56
    • 33845374750 scopus 로고
    • For example (1,2-C-H bond activation of benzene using Ta), see
    • For example (1,2-C-H bond activation of benzene using Ta), see: Chamberlain, L. R.; Rothwell, I. P.; Huffman, J. C. J. Am. Chem. Soc. 1986, 108, 1502
    • (1986) J. Am. Chem. Soc. , vol.108 , pp. 1502
    • Chamberlain, L.R.1    Rothwell, I.P.2    Huffman, J.C.3
  • 73
    • 79956085857 scopus 로고    scopus 로고
    • note
    • 6, 4, 6) are shown in the Supporting Information.
  • 74
    • 79956088462 scopus 로고    scopus 로고
    • note
    • 1H NMR spectrum. Since the crystallographic analysis result for 6 reveals that 6 has a rather distorted tetrahedral geometry around vanadium and because the bond angles of N(1)-V(1)-C(100) [112.89(5)°] and N(2)-V(1)-C(100) [125.14(4)°] are larger than those of N(1)-V(1)-C(101) [106.04(5)°] and N(2)-V(1)-C(101) [108.71(4)°], it seems likely that there are two isomers in the solution.
  • 78
    • 53649109699 scopus 로고    scopus 로고
    • Crystal Structure Analysis Package; Rigaku and Rigaku Americas: The Woodlands, TX, USA
    • CrystalStructure 3.8, Crystal Structure Analysis Package; Rigaku and Rigaku Americas: The Woodlands, TX, USA, 2000-2007.
    • (2000) CrystalStructure 3.8
  • 79
    • 0004150157 scopus 로고    scopus 로고
    • University of Göttingen: Germany
    • Sheldrick, G. M. SHELX97; University of Göttingen: Germany, 1997.
    • (1997) SHELX97
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.