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Examples of isolation of terminal vanadium(V) - alkylidenes: (a) Buijink, J.-K. F.; Teuben, J. H.; Kooijman, H.; Spek, A. L. Organometallics 1994, 13, 2922 No reaction between CpV(CHPh)(NAr)(PMe3) and norbomene or acetone was observed.
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Examples of isolation of terminal vanadium(V) - alkylidenes: (a) Buijink, J.-K. F.; Teuben, J. H.; Kooijman, H.; Spek, A. L. Organometallics 1994, 13, 2922 No reaction between CpV(CHPh)(NAr)(PMe3) and norbomene or acetone was observed.
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Examples of related complexes containing vanadium(V)-carbon double bonds:(a) Hessen, B.; Meetsma, A.; van Bolhuis, F.; Teuben, J. H. Organometallics 1990, 9, 1925.
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55249100649
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These results were partly presented at the XVIIth International symposium on olefin metathesis (ISOMXVII), July2007, Pasadena, CA.
-
These results were partly presented at the XVIIth International symposium on olefin metathesis (ISOMXVII), July2007, Pasadena, CA.
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Wang, W.1
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55249112170
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The NMR spectra for 1 and the spectra monitoring the reaction of 1 with RCN (and with styrene) are shown in the Supporting Information.
-
The NMR spectra for 1 and the spectra monitoring the reaction of 1 with RCN (and with styrene) are shown in the Supporting Information.
-
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47
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55249105094
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Two possibilities, i) partial dissociation of PMe3 (as observed in the alkylidene recently reported)12 and (ii) a mixture of isomers (syn/anti isomers, as seen in the molybdenum-alkylidene complexes),2,4b have to be considered for explanation for the two resonances in the 51V NMR spectra of 1. PMe3 in the aryloxo-alkylidene V(CHSiMe3)(N-2,6-Me2C6H 3, O-iPr2C6H3)(PMe 3) dissociated partially, confirmed by both the elemental analysis and the NMR spectra,12 and the 1H NMR spectrum of 1 (in C6D6) showed only one broad resonance ascribed to the alkylidene proton and only one broad resonance ascribed to the alkylidene was observed in the 13C NMR spectrum (and one broad resonance was seen in the 31P NMR spectrum, The latter possibility the presence of isomers, shown
-
3 are shown in the Supporting Information.
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48
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33947094577
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Selected examples for reaction with nitriles (Ta): (a) Schrock, R. R.; Fellmann, J. D. J. Am. Chem. Soc. 1978, 100, 3359-3370.
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Selected examples for reaction with nitriles (Ti): (a) Doxsee, K. M.; Farahi, J. B.; Hope, H. J. Am. Chem. Soc. 1991, 113, 8889.
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Selected examples for reaction with nitriles (Ti): (a) Doxsee, K. M.; Farahi, J. B.; Hope, H. J. Am. Chem. Soc. 1991, 113, 8889.
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55249083867
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Detailed analysis parameters including CIF files are shown in the Supporting Information
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Detailed analysis parameters including CIF files are shown in the Supporting Information.
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55
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Bimolecular decomposition of Cp2Ta(CH2)(CH 3) in the presence of PMe3 afforded Cp2Ta(V, CH2CH2)(CH3) and Cp2Ta(CH 3)(PMe3, a) Schrock, R. R J. Am. Chem. Soc. 1975, 97, 6577
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2442547607
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Formation of Mo(NAi′)(Biphen)(ethylene) complex from Mo(NAr′)(CHCMe2Ph)(Biphen) by reacting with 2 equiv of ethylene via β-H elimination: (a) Tsang, W. C. P, Jamieson, J. Y, Aeilts, S. L, Hultzsch, K. C, Schrock, R. R, Hoveyda, A. H. Organometallics 2004, 23, 1997. In our case, we would be able to eliminate this possibility [a route via formation of vanadium(III) and subsequent addition of styrène, because the observed reaction product by 51V NMR spectrum14 from the reaction of 1 with 1 equiv of styrene was 6 exclusively. The related reaction in CpTi(CHMe3)[PMe 2-CH2C(O)-CMe2-o-C6H 4CMe2, The titanium-alkylidene reacts with ethylene, initially forming a metallacycle, while subsequent reactions produce a stable ethylene complex
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2] (The titanium-alkylidene reacts with ethylene, initially forming a metallacycle, while subsequent reactions produce a stable ethylene complex).
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27544439033
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(a) Schrock, R. R.; Lopez, L. P. H.; Hafer, J.; Singh, R.; Sinha, A.; Müller, P. Organometallics 2005, 24, 5211.
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55249098295
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Negligible amount of polymer was collected when a toluene solution (5 mL) containing complex 6 (5 mg, 10 μmol) and norbornene 200 mg (2.1 mmol) was heated at 80 °C for 1 h.
-
Negligible amount of polymer was collected when a toluene solution (5 mL) containing complex 6 (5 mg, 10 μmol) and norbornene 200 mg (2.1 mmol) was heated at 80 °C for 1 h.
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66
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55249126723
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34047252798
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