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4243182579
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note
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A C-H reductive elimination mechanism for labeling of the ipso C-H may also be operative, although we could not distinguish the ipso C-H signal from the other side chain protons.
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18
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4243125265
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note
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Complex 2 and the products of its reactions with various gases are extremely air-sensitive. Therefore, no elemental analyses based on combustion methods were performed.
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21
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1H NMR is usually substantially lower than those for classic hydrides. For review see: Kubas, G. Acc. Chem. Res. 1988, 21, 120-128.
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The solubilities of gases in liquids increase lineary under moderate pressure (1-3 atm in our case), and therefore they could be calculated from the literature data: (a) Dymond, J. H. J. Phys. Chem. 1967, 6, 1829-1831. (b) Wilhelm, E.; Battino, R. Chem. Rev. 1973, 73, 1-9 and references cited therein. (c) Hayduk, W., Ed. Solubility Data Series; Pergamon: New York, 1994; Vol. 57.
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9344263550
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The solubilities of gases in liquids increase lineary under moderate pressure (1-3 atm in our case), and therefore they could be calculated from the literature data: (a) Dymond, J. H. J. Phys. Chem. 1967, 6, 1829-1831. (b) Wilhelm, E.; Battino, R. Chem. Rev. 1973, 73, 1-9 and references cited therein. (c) Hayduk, W., Ed. Solubility Data Series; Pergamon: New York, 1994; Vol. 57.
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The solubilities of gases in liquids increase lineary under moderate pressure (1-3 atm in our case), and therefore they could be calculated from the literature data: (a) Dymond, J. H. J. Phys. Chem. 1967, 6, 1829-1831. (b) Wilhelm, E.; Battino, R. Chem. Rev. 1973, 73, 1-9 and references cited therein. (c) Hayduk, W., Ed. Solubility Data Series; Pergamon: New York, 1994; Vol. 57.
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