An unusual isomerization to tetraazastiboles

Angewandte Chemie - International Edition

Volumn 50, Issue 22, 2011, Pages 5221-5224

  Lehmann, Mathias ^a   Schulz, Axel ^a   Villinger, Alexander ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

antimony; azides; main group elements; structure elucidation; tetraazastibole

Indexed keywords

ADDUCT FORMATION; AZIDES; LEWIS ACID; MAIN GROUP ELEMENTS; STRUCTURE ELUCIDATION; TETRAAZASTIBOLE;

ISOMERIZATION;

ISOMERS;

EID: 79956082385     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201100663     Document Type: Article

References (62)

1. K. Clusius, H. Hurzeler, Helv. Chim. Acta 1954, 37, 798-804.
2. R. Huisgen, I. Ugi, Chem. Ber. 1957, 90, 2914-2927
3. I. Ugi, H. Perlinger, L. Behringer, Chem. Ber. 1958, 91, 2324-2330
4. I. Ugi, R. Huisgen, Chem. Ber. 1958, 91, 531-537.
5. A. Schmidpeter, K. Karaghiosoff, Heterophospholes in Multiple Bonding and Low Corrdination in Phosphorus Chemistry (Eds.:, M. Regitz, O. J. Scherer,), Thieme, Stuttgart, 1990, pp. 258-286
6. J. D. Woolins, Non-Metal Rings, Cages and Clusters, Wiley, Chichester, 1988
7. T. Chivers, A Guide to Chalcogen-Nitrogen Chemistry, World Scientific, London, 2005.
8. P. Mayer, A. Schulz, A. Villinger, Chem. Commun. 2006, 1236-1238
9. P. Mayer, A. Schulz, A. Villinger, J. Organomet. Chem. 2007, 692, 2839-2842.
10. D. Michalik, A. Schulz, A. Villinger, N. Weding, Angew. Chem. 2008, 120, 6565-6568
11. Angew. Chem. Int. Ed. 2008, 47, 6465-6468.
12. A. Schulz, A. Villinger, Angew. Chem. 2008, 120, 614-617
13. Angew. Chem. Int. Ed. 2008, 47, 603-606.
14. H. Brand, A. Schulz, A. Villinger, Z. Anorg. Allg. Chem. 2007, 633, 22-35.
15. A. Schulz, A. Villinger, Struct. Chem. 2009, 20, 59-62.
16. S. Herler, A. Villinger, P. Mayer, A. Schulz, J. J. Weigand, Angew. Chem. 2005, 117, 7968-7971
17. Angew. Chem. Int. Ed. 2005, 44, 7790-7793.
18. M. Kowalewski, B. Krumm, P. Mayer, A. Schulz, A. Villinger, Eur. J. Inorg. Chem. 2007, 5319-5322.
19. A. Schulz, A. Villinger, Inorg. Chem. 2009, 48, 7359-7367
20. W. Baumann, A. Schulz, A. Villinger, Angew. Chem. 2008, 120, 9672-9675
21. Angew. Chem. Int. Ed. 2008, 47, 9530-9532
22. A. Villinger, A. Schulz, Angew. Chem. 2010, 122, 8190-8194
23. Angew. Chem. Int. Ed. 2010, 49, 8017-8020.
24. M. Lehmann, A. Schulz, A. Villinger, Struct. Chem. 2011, 22, 35-43.
25. M. Lehmann, A. Schulz, A. Villinger, Eur. J. Inorg. Chem. 2010, 5501-5508.
26. Similar exchange reactions have already been reported for arsenic, see for example D. Michalik, A. Schulz, A. Villinger, Inorg. Chem. 2008, 47, 11798-11806
27. A. Schulz, P. Mayer, A. Villinger, Inorg. Chem. 2007, 46, 8316-8322.
28. Details of the synthesis and full characterization, including X-ray structure elucidation of all of the species considered herein, can be found in the Supporting Information.
29. An analogous reaction is known for Mes*N=AsCl
30. P. B. Hitchcock, H. A. Jasim, M. F. Lappert, H. D. Williams, J. Chem. Soc. Chem. Commun. 1986, 1634-1636
31. N. Burford, T. S. Cameron, C. L. B. Macdonald, K. N. Robertson, R. Schurko, D. Walsh, Inorg. Chem. 2005, 44, 8058-8064.
32. 2SbCl] (1 -Cl). For details, see the Supporting Information.
33. Holleman-Wiberg, Lehrbuch der Anorganischen Chemie, 102 nd ed., Walter de Gruyter, Berlin, 2007, Appendix IV.
34. M. S. Balakrishna, D. J. Eisler, T. Chivers, Chem. Soc. Rev. 2007, 36, 650-664
35. L. Stahl, Coord. Chem. Rev. 2000, 210, 203-250.
36. D. C. Haagenson, L. Stahl, Inorg. Chem. 2001, 40, 4491-4493.
37. I. C. Tornieporth-Oetting, T. M. Klapötke, Angew. Chem. 1995, 107, 559-568
38. Angew. Chem. Int. Ed. Engl. 1995, 34, 511-520.
39. For example T. M. Klapötke, A. Schulz, Main Group Met. Chem. 1997, 20, 325-339
40. D. F. Moser, I. Schranz, M. C. Gerrety, L. Stahl, R. J. Staples, J. Chem. Soc. Dalton Trans. 1999, 751-757
41. I. Schranz, L. P. Grocholl, L. Stahl, R. J. Staples, A. Johnson, Inorg. Chem. 2000, 39, 3037-3041
42. K. Karaghiosoff, T. M. Klapötke, B. Krumm, H. Nöth, T. Schütt, M. Suter, Inorg. Chem. 2002, 41, 170-179
43. A. C. Filippou, P. Portius, G. Schnakenburg, J. Am. Chem. Soc. 2002, 124, 12396-12397
44. R. Haiges, J. A. Boatz, R. Bau, S. Schneider, T. Schroer, M. Yousufuddin, K. O. Christe, Angew. Chem. 2005, 117, 1894-1899
45. Angew. Chem. Int. Ed. 2005, 44, 1860-1865
46. R. Haiges, J. A. Boatz, T. Schroer, M. Yousufuddin, K. O. Christe, Angew. Chem. 2006, 118, 4948-4953
47. Angew. Chem. Int. Ed. 2006, 45, 4830-4835.
48. J. D. Wallis, J. D. Dunitz, J. Chem. Soc. Chem. Commun. 1983, 910-911
49. F. Biesemeier, U. Müller, W. Massa, Z. Anorg. Allg. Chem. 2002, 628, 1933- 1934.
50. S. Pelzer, K. Wichmann, R. Wesendrup, P. Schwerdtfeger, J. Phys. Chem. A 2002, 106, 6387-6394
51. A. Alparone, H. Reis, M. G. Papadopoulos, J. Phys. Chem. A 2006, 110, 5909-5918.
52. D. Gudat, T. Gans-Eichler, M. Nieger, Chem. Commun. 2004, 2434-2435.
53. M. Veith, B. Bertschid, V. Huch, Z. Anorg. Allg. Chem. 1988, 559, 73-88
54. S. Burck, M. Nieger, D. Gudat, Z. Anorg. Allg. Chem. 2010, 636, 1263-1267.
55. H. A. Spinney, I. Korobkov, G. A. DiLabio, G. P. A. Yap, D. S. Richeson, Organometallics 2007, 26, 4972-4982.
56. A. Bernsdorf, H. Brand, R. Hellmann, M. Köckerling, A. Schulz, A. Villinger, K. Voss, J. Am. Chem. Soc. 2009, 131, 8958-8970.
57. H. Jacobsen, H. Berke, S. Doering, G. Kehr, G. Erker, R. Froehlich, O. Meyer, Organometallics 1999, 18, 1724-1735.
58. Computations were carried out at the B3LYP level of theory. For H, C, N, B, and F, a standard 6-31+G(d) basis set was used; for Sb, a quasi-relativistic pseudopotential ECP46MWB-VTZ with a triple zeta basis set was used.
59. E. D. Glendening, A. E. Reed, J. E. Carpenter, F. Weinhold NBO Version 3.1
60. J. E. Carpenter, F. Weinhold, J. Mol. Struct. (Theochem) 1988, 169, 41-62
61. F. Weinhold, J. E. Carpenter, The Structure of Small Molecules and Ions, Plenum, New York, 1988, 227
62. F. Weinhold, C. Landis, Valency and Bonding. A Natural Bond Orbital Donor-Acceptor Perspective, Cambridge University Press, Cambridge, 2005, and references therein.