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Volumn 47, Issue 34, 2008, Pages 6465-6468

A cationic cyclic phosphorus(III) azide

Author keywords

Azides; Diphosphadiazane; Heterocycles; P N cations; X ray diffraction

Indexed keywords

CHEMICAL REACTIONS;

EID: 53349118804     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200801674     Document Type: Article
Times cited : (54)

References (37)
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    • Angew. Chem. Int. Ed. 2005, 44, 7790-7793.
    • (2005) Angew. Chem. Int. Ed , vol.44 , pp. 7790-7793
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    • Angew. Chem. Int. Ed. 2008, 47, 603-606.
    • (2008) Angew. Chem. Int. Ed , vol.47 , pp. 603-606
  • 8
    • 53349158317 scopus 로고    scopus 로고
    • 3SiCl at ambient temperatures, resulting in the formation of Mes*N=PCl.
    • 3SiCl at ambient temperatures, resulting in the formation of Mes*N=PCl.
  • 19
    • 53349136376 scopus 로고    scopus 로고
    • See the Supporting Information: a chemical shifts (1H, 13C{1H, 31P{1H, b) crystal data; c) full description of the experimental data, technique, and details; d) Natural bond orbital (NBO) partial charge calculations of a series of R-N=P+ species; e) Although 5 and 6 are stable up to 210 and 140°C, respectively, they slowly decompose when stored at RT
    • + species; e) Although 5 and 6 are stable up to 210 and 140°C, respectively, they slowly decompose when stored at RT.
  • 24
    • 53349105042 scopus 로고    scopus 로고
    • The synthesis of cationic azidophosphenium ions bearing an azido substituent directly on the dicoordinate phosphorus atom has been claimed before, but without any experimental proof: M. R. Mazieres, M. Sanchez, J. Bellan, R. Wolf, Phosphorus Sulfur Relat. Elem. 1986, 26, 97-99
    • The synthesis of cationic azidophosphenium ions bearing an azido substituent directly on the dicoordinate phosphorus atom has been claimed before, but without any experimental proof: M. R. Mazieres, M. Sanchez, J. Bellan, R. Wolf, Phosphorus Sulfur Relat. Elem. 1986, 26, 97-99.
  • 25
    • 53349083704 scopus 로고    scopus 로고
    • Sum of covalent radii: r(P) = 1.1 and r(N) = 0.7; N. Wiberg, E. Wiberg, A. F. Holleman, Lehrbuch der Anorganischen Chemie, 102. Aufl., Walter de Gruyter, Berlin, 2007, Anhang IV.
    • a) Sum of covalent radii: r(P) = 1.1 and r(N) = 0.7; N. Wiberg, E. Wiberg, A. F. Holleman, Lehrbuch der Anorganischen Chemie, 102. Aufl., Walter de Gruyter, Berlin, 2007, Anhang IV.
  • 27
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    • T. M. Klapötke, A. Schulz, Ab initio Methods in Main Group Chemistry, Wiley, New York, 1998, with a chapter by R. D. Harcourt about valence bond (VB) Theory;
    • b) T. M. Klapötke, A. Schulz, Ab initio Methods in Main Group Chemistry, Wiley, New York, 1998, with a chapter by R. D. Harcourt about valence bond (VB) Theory;
  • 29
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    • a) U. Müller, Chem. Ber. 1977, 110, 788-791;
    • (1977) Chem. Ber , vol.110 , pp. 788-791
    • Müller, U.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.