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0011044777
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note
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3-CN).
-
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13
-
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0010968659
-
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note
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-1.
-
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14
-
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0011051218
-
-
note
-
+ (n = 1, 3, 4).
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15
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0000235959
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0003151228
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17
-
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0010997002
-
-
note
-
-1 (BP86/DZP, effective core potential of Si: Stuttgart RLC ECP, ref 14). This suggests that the corresponding absorption bands are not resolved in the IR spectra of 1.
-
-
-
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18
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84944675147
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Bergner, A.; Dolg, M.; Kuechle, W.; Stoll, H.; Preuss, H. Mol. Phys. 1993, 80, 1431.
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19
-
-
0011004349
-
-
note
-
3) modes, respectively. These bands were not observed in the IR spectra of 1.
-
-
-
-
20
-
-
0010963371
-
-
note
-
2.
-
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-
-
22
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0002255967
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23
-
-
0011005315
-
-
note
-
The Nβ signal of 1 = -133 ppm) is hidden under the solvent signal (δ = -135.5 ppm).
-
-
-
-
24
-
-
4243539377
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All calculations were carried out with the program system Turbomole, V5.3; Ahlrichs, R.; Bär, M.; Häser, M.; Horn, H.; Kölmel, C. Chem. Phys. Lett. 1989, 162, 165.
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31
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0010963372
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note
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β atoms.
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33
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0001748025
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