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Volumn 44, Issue 47, 2005, Pages 7790-7793

A triazadiphosphole

Author keywords

Bonding analysis; Lewis acid base adducts; P,N heterocycles; Structure determination; Triazadiphospholes

Indexed keywords

CHARACTERIZATION; CHEMICAL BONDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROBABILITY DENSITY FUNCTION; REACTION KINETICS; STRUCTURE (COMPOSITION); THERMAL EFFECTS;

EID: 28744451070     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200502475     Document Type: Article
Times cited : (50)

References (66)
  • 15
  • 26
    • 0001867777 scopus 로고
    • and references therein
    • b) A. Schmidpeter, Phosphorus Sulfur 1986, 28, 71-89, and references therein.
    • (1986) Phosphorus Sulfur , vol.28 , pp. 71-89
    • Schmidpeter, A.1
  • 30
    • 28744434182 scopus 로고    scopus 로고
    • note
    • 3 is used, the reaction is not complete, i.e. both compounds 2 and 1 are observed.
  • 31
    • 28744432222 scopus 로고    scopus 로고
    • note
    • 31P)) and coupling constants; b) crystal data; c) computational details, calculated structural and vibrational data of all described species (B3LYP), approximate assignment and trends; d) full description of the experimental data, technique and details; e) summary of the NBO analysis for 2 and 3: 1) partial charges, 2) hybridization effects, 3) polarization, and 4) Wiberg bond indices.
  • 35
    • 28744455455 scopus 로고    scopus 로고
    • note
    • The structural parameters of second independent molecule are almost identical to those of the first; hence, we have only discussed the data of the first molecule.
  • 42
    • 28744432404 scopus 로고    scopus 로고
    • note
    • b) see Figure S3 and S4 in the Supporting Information.
  • 43
    • 0035133946 scopus 로고    scopus 로고
    • and references therein
    • It is known that for adducts in the solid state and gas phase, structural data and donor-acceptor energies can be quite different. Leopold et al. have indicated that the donor-acceptor bond is much shorter in the solid state than in the gas phase, and this change has been associated with the substantial dipole moment of the adduct. D. L. Fiacco, Y. Mo, S. W. Hunt, M. E. Ott, A. Roberts, K. R. Leopold, J. Phys. Chem. A 2001, 105, 484-493, and references therein.
    • (2001) J. Phys. Chem. A , vol.105 , pp. 484-493
    • Fiacco, D.L.1    Mo, Y.2    Hunt, S.W.3    Ott, M.E.4    Roberts, A.5    Leopold, K.R.6
  • 59
    • 0037119339 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 3051-3054;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 3051-3054


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.