Experimental evidence for linear metal-azido coordination: The binary group 5 azides [Nb(N3)5], [Ta(N3)5], [Nb(N3)6]-, and [Ta(N3) 6]-, and 1:1 acetonitrile adducts [Nb(N3) 5(CH3CN)] and [Ta(N3)5(CH 3CN)]

Angewandte Chemie - International Edition

Volumn 45, Issue 29, 2006, Pages 4830-4835

  Haiges, Ralf ^a   Boatz, Jerry A ^b   Schroer, Thorsten ^a   Yousufuddin, Muhammed ^a   Christe, Karl O ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

^b AIR FORCE RESEARCH LABORATORY   (United States)

Author keywords

Azides; Density functional calculations; Niobium; Tantalum; Vibrational spectroscopy

Indexed keywords

ACETONITRILE; MOLECULAR VIBRATIONS; NIOBIUM; NITROGEN COMPOUNDS; REACTION KINETICS; TANTALUM;

AZIDES; DENSITY FUNCTIONAL CALCULATIONS; VIBRATIONAL SPECTROSCOPY;

NIOBIUM COMPOUNDS;

EID: 33746795000     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200601060     Document Type: Article

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