Tetrazarsoles - A new class of binary arsenic-nitrogen heterocycles

Angewandte Chemie - International Edition

Volumn 47, Issue 3, 2008, Pages 603-606

  Schulz, Axel ^a   Villinger, Alexander ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

Arsenic; Azarsoles; Cycloaddition; Nitrogen heterocycles; Structure elucidation

Indexed keywords

CYCLOADDITION; GALLIUM COMPOUNDS; NITROGEN; SYNTHESIS (CHEMICAL);

NITROGEN HETEROCYCLES; STRUCTURE ELUCIDATION;

ARSENIC COMPOUNDS;

EID: 40949162048     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200704367     Document Type: Article

References (33)

1. a) S. Herler, A. Villinger, J. Weigand, P. Mayer, A. Schulz, J. Schmedt auf der Günne, Angew. Chem. 2005, 117, 7968-7971;
2. Angew. Chem. Int. Ed. 2005, 44, 7790-7793;
3. b) P. Mayer, A. Schulz, A. Villinger, J. Organomet. Chem. 2007, 692, 2839-2842.
4. G. Fischer, S. Herler, P. Mayer, A. Schulz, A. Villinger, J. Weigand, Inorg. Chem. 2005, 44, 1740-1751.
5. P. Mayer, A. Schulz, A. Villinger, Chem. Commun. 2006, 1236-1238.
6. 3H: H. W. Roesky, G. Sidiropoulos, Z. Naturforsch. B 1978, 33, 756-758;
7. b) A. Schulz, P. Mayer, A. Villinger, Inorg. Chem. 2007, 46, 8316-8322.
8. N. Burford, T. S. Cameron, C. L. B. Macdonald, K. N. Robertson, R. Schurko, D. Walsh, Inorg. Chem. 2005, 44, 8058-8064.
9. 1H} NMR);
10. b) crystal data;
11. c) full description of the experimental data, technique, and details of 3 and 4, including improved syntheses of all starting materials;
12. d) computational details;
13. e) summary of the NBO analysis for 3: 1) partial charges, 2) hybridization effects, and 3) polarization.
14. a) R. Huisgen, I. Ugi, Chem. Ber. 1957, 90, 2914-2927;
15. b) I. Ugi, H. Perlinger, L. Behringer, Chem. Ber. 1958, 91, 2324-2330;
16. c) I. Ugi, R. Huisgen, Chem. Ber. 1958, 91, 531-537;
17. J. D. Wallis, J. D. Dunitz, J. Chem. Soc. Chem. Commun. 1983, 910-911.
18. A. F. Holleman, E. Wiberg, Lehrbuch der Anorganischen Chemie, 102nd ed., Walter de Gruyter, Berlin, 2007, Appendix IV.
19. T. Gans-Eichler, D. Gudat, M. Nieger, Heteroat. Chem. Heteroatom. Chem. 2005, 16, 327-338.
20. E. Niecke, D. Gudat, Angew. Chem. 1991, 103, 251-270;
21. Angew. Chem. Int. Ed. Engl. 1991, 30, 217-237.
22. See, for instance: a) C. Kruppa, M. Nieger, B. Ross, I. Väth, Eur. J. Inorg. Chem. 2000, 165-168;
23. b) K. Miqueu, J.-M. Sotiropoulos, G. Pfister-Guillouzo, V. D. Romanenko, New J. Chem. 2001, 25, 930-938;
24. c) J. T. Ahlmann, A. Kunzel, H. W. Roesky, M. Noltemeyer, L. Markovskii, H. G. Schmidt, Inorg. Chem. 1996, 35, 6644-6645;
25. d) S. K. Vasisht, T. P. Kaur, K. Usha, J. Kaushal, K. Bandhu, Phosphorus Sulfur Silicon Relat. Elem. 1995, 107, 189-195.
26. P. B. Hitchcock, M. F. Lappert, A. K. Rai, H. D. Williams, J. Chem. Soc. Chem. Commun. 1986, 1633-1634.
27. Single-point calculations were computed with a tight conversion criterion using the program package Gaussian 98. For computational details, see the Supporting Information; M. J. Frisch, et al. Gaussian 98, Revision All, Gaussian Inc., Pittsburgh PA, 1998.
28. a) E. D. Glendening, A. E. Reed, J. E. Carpenter, F. Weinhold, NBO Version 3.1;
29. b) J. E. Carpenter, F. Weinhold, J. Mol. Struct. (Theochem) 1988, 169, 41-62;
30. c) F. Weinhold, J. E. Carpenter, The Structure of Small Molecules and Ions, Plenum, Oxford, 1988, p. 227;
31. d) F. Weinhold, C. Landis, Valency and Bonding. A Natural Bond Orbital Donor-Acceptor Perspective, Cambridge University Press, 2005, and references therein.
32. S. P. Green, C. Jones, G. Jin, A. Stasch, Inorg. Chem. 2007, 46, 8-10.
33. A. J. Downs, N. I. Hunt, G. S. McGrady, D. W. H. Rankin, H. E. Robertson, J. Mol. Struct. 1991, 248, 393-406.