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Volumn 596, Issue 1-2, 2000, Pages 22-26

The synthesis and structural characterization of phenyl tris(3-t-butylpyrazolyl)borato alkyl complexes of magnesium and zinc, [PhTpBut]MgR (R = Me, Et) and [PhTpBut]ZnMe

Author keywords

Alkyl; Magnesium; Tris(pyrazolyl)borate; Zinc

Indexed keywords


EID: 0002478415     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(99)00534-3     Document Type: Article
Times cited : (30)

References (40)
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    • note
    • The abbreviations adopted here for tris(pyrazolyl)hydroborato ligands are based on those described by Trofimenko (Ref. [1a]). Thus, the tris(pyrazolyl)hydroborato ligands are represented by the abbreviation Tp, with the 3- and 5-alkyl substituents listed, respectively as superscripts. If the fourth substituent on boron is anything other than hydrogen, the substituent is listed as a prefix, e.g. [pzTp] and [RTp].
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    • But]FeMe is 2.079(3) Å, intermediate between the corresponding values for Mg-C and Zn-C. See Ref. [10].
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    • See for example: (a) Y. Sohrin, H. Kokusen, M. Matsui, Inorg. Chem. 34 (1995) 3928-3934. (b) D.L. Reger, M.F. Huff, A.L. Rheingold, B.S. Haggerty, Inorg. Chem. 114 (1992) 579-584. (c) F.A. Cotton, B.A., Frenz, C.A. Murillo, J. Am. Chem. Soc. 97 (1975) 2118-2122.
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    • See for example: (a) Y. Sohrin, H. Kokusen, M. Matsui, Inorg. Chem. 34 (1995) 3928-3934. (b) D.L. Reger, M.F. Huff, A.L. Rheingold, B.S. Haggerty, Inorg. Chem. 114 (1992) 579-584. (c) F.A. Cotton, B.A., Frenz, C.A. Murillo, J. Am. Chem. Soc. 97 (1975) 2118-2122.
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