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Volumn 30, Issue 6, 2011, Pages 1668-1676

Steric and electronic parameters characterizing bulky and electron-rich dialkylbiarylphosphines

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC PROPERTIES; FREQUENCY ESTIMATION; IRIDIUM COMPOUNDS; LIGANDS; PHOSPHORUS COMPOUNDS;

EID: 79952932753     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om101174x     Document Type: Article
Times cited : (42)

References (63)
  • 46
    • 2742566665 scopus 로고
    • 3Cl] can also be used as a starting material
    • 3Cl] can also be used as a starting material: Walter, H.; Frey, V. Chem. Ber. 1966, 99, 2607-2613
    • (1966) Chem. Ber. , vol.99 , pp. 2607-2613
    • Walter, H.1    Frey, V.2
  • 47
    • 79952908105 scopus 로고    scopus 로고
    • CCDC 744632 - 744635 (3a - d), 746738 (4a), 744636 (4b), 746738 (4c), 744637 (4d), and 802800 (4g) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
    • CCDC 744632 - 744635 (3a - d), 746738 (4a), 744636 (4b), 746738 (4c), 744637 (4d), and 802800 (4g) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
  • 50
    • 79952963045 scopus 로고    scopus 로고
    • The H atoms in the XRD structures are calculated on the basis of optimized geometries
    • The H atoms in the XRD structures are calculated on the basis of optimized geometries.
  • 51
    • 0000230035 scopus 로고    scopus 로고
    • Typical anagostic bonds range from 2.3 to 2.9 Å. For more informatin see
    • Typical anagostic bonds range from 2.3 to 2.9 Å. For more informatin see: Braga, D.; Grepioni, F.; Tedesco, E.; Biradha, K.; Desiraju, G. R. Organometallics 1997, 16, 1846-1856
    • (1997) Organometallics , vol.16 , pp. 1846-1856
    • Braga, D.1    Grepioni, F.2    Tedesco, E.3    Biradha, K.4    Desiraju, G.R.5
  • 53
    • 79952902915 scopus 로고    scopus 로고
    • This statement should hold true even despite the XRD data, which implied a possible Ir - -H anagostic interaction. This interaction may indeed increase the uncertainty in electron-donating abilities, but in solution, the steric pressure of the bulky ligands should be less
    • This statement should hold true even despite the XRD data, which implied a possible Ir - -H anagostic interaction. This interaction may indeed increase the uncertainty in electron-donating abilities, but in solution, the steric pressure of the bulky ligands should be less.
  • 58
    • 79952919904 scopus 로고    scopus 로고
    • bur of ligands 2 in complexes 3 and 4 using the experimentally determined Ir-P distances
    • bur of ligands 2 in complexes 3 and 4 using the experimentally determined Ir-P distances.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.