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note
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The observation of products is restricted by precipitation that occurs under the extremely low-temperature conditions, especially for the dinuclear products.
-
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64
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79951845182
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note
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-1[alkane], and the rate is also first order in [L].
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65
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79951819027
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note
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The isomers are formed in a 3:1 ratio of integrations. Because the resonances correspond to 3 and 2 protons, respectively, assuming no chain walking (see above), this works out as a 2:1 molar ratio. However, the use of solvent suppression makes these calculations error prone.
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66
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72949102458
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2)] (δ(Mn-H) =-8.88; δ(Re-H) =-6.09).
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2H] (δ(Mn-H) = -12.15; δ(Re-H) = -12.35).
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