Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp-rhodium complexes

Journal of the American Chemical Society

Volumn 132, Issue 9, 2010, Pages 3078-3091

  Wei, Carolyn S ^a   Jiménez Hoyos, Carlos A ^b,c   Videa, Marcelo F ^d   Hartwig, John F ^a   Hall, Michael B ^b  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

^b TEXAS A AND M UNIVERSITY   (United States)

^c RICE UNIVERSITY   (United States)

^d SCHOOL OF ENGINEERING AND SCIENCES   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

BOND FORMATION; BORANE REAGENTS; BORYLATION; C-H BOND; C-H BOND CLEAVAGE; CATALYTIC REACTIONS; COMPUTATIONAL ANALYSIS; COMPUTATIONAL STUDIES; CUMULATIVE EFFECTS; CYCLIC ALKANES; DENSITY FUNCTIONAL THEORY CALCULATIONS; ENERGY PATHWAY; EXPERIMENTAL STUDIES; FUNCTIONALIZATIONS; H/D EXCHANGE; HIGH SELECTIVITY; KINETIC EXPERIMENT; LINEAR ALKANES; N-OCTANES; RH COMPLEXES; RHODIUM COMPLEXES; STERIC EFFECT;

ALKYLATION; CATALYSIS; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; ISOMERS; PARAFFINS; PROPANE; REACTION INTERMEDIATES; RHODIUM;

RHODIUM COMPOUNDS;

ALKYL GROUP; OCTANE; PROPANE; RHODIUM COMPLEX;

ARTICLE; CATALYSIS; CHEMICAL BOND; DENSITY FUNCTIONAL THEORY; DISSOCIATION; ELECTRON; EXPERIMENTAL STUDY; HYDROGEN BOND; KINETICS;

ALKANES; BINDING SITES; BORANES; CATALYSIS; COMPUTER SIMULATION; MODELS, CHEMICAL; ORGANOMETALLIC COMPOUNDS; RHODIUM;

EID: 77949409053     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja909453g     Document Type: Article

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