A rhenium-cyclohexane complex with preferential binding of axial C-H bonds: A probe into the relative ability of C-H, C-D, and C-C bonds as hyperconjugative electron donors?

Angewandte Chemie - International Edition

Volumn 45, Issue 27, 2006, Pages 4486-4490

  Lawes, Douglas J ^b   Darwish, Tamim A ^b   Clark, Timothy ^a   Harper, Jason B ^b   Ball, Graham E ^b  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b UNIVERSITY OF NEW SOUTH WALES   (Australia)

Author keywords

Ab initio calculations; Alkane ligands; C H activation; Hyperconjugation; NMR spectroscopy

Indexed keywords

ELECTRONS; NUCLEAR MAGNETIC RESONANCE; PARAFFINS; PROTONS; THERMAL EFFECTS;

AB INITIO CALCULATIONS; ALKANE LIGANDS; C-H ACTIVATION; HYPERCONJUGATION;

CHEMICAL BONDS;

EID: 33746272399     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200600313     Document Type: Article

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