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Volumn 83, Issue 4, 2011, Pages 1232-1242

Fluorescence quantum yields of a series of red and near-infrared dyes emitting at 600-1000 nm

Author keywords

[No Author keywords available]

Indexed keywords

AS-LINKS; COUMARIN 153; CRESYL VIOLET; CYANINE DYES; DIRECT MEASUREMENT; EFFECTS OF TEMPERATURE; EMISSION RANGE; ETHANOL SOLUTIONS; FLUORESCENCE QUANTUM YIELD; FLUORESCENT DYES; NATIONAL INSTITUTE OF STANDARDS; NEAR-INFRARED DYES; QUININE SULFATE; RHODAMINE 101; SPECTROSCOPIC FEATURES; STANDARD REFERENCE MATERIAL; TRANSFER STANDARD;

EID: 79951703915     PISSN: 00032700     EISSN: None     Source Type: Journal    
DOI: 10.1021/ac101329h     Document Type: Article
Times cited : (556)

References (86)
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    • Certificate of Analysis, Standard Reference Material SRM 936a, Quinine Sulfate Dihydrate. National Institute of Standards and Technology: Gaithersburg, MD,. (accessed Dec 1, 2010). Note that, according to NISTs website, this SRM is currently out of stock.
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    • Updated, see: BAM-F001, -F002a, -F003-F005, Calibration Kit, Spectral Fluorescence Standards; BAM Federal Institute for Materials Research and Testing: Berlin, 2009. http://www.comar.bam.de/home/search-crm.php (accessed Dec 1, 2010).
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  • 43
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    • note
    • Rh-101, 8-(2-carboxyphenyl)-2,3,5,6,11,12,14,15-octahydro-1 H,4 H,10 H,13 H -diquinolizino[9,9 a,1- bc:9′,9 a ′,1- hi ]xanthylium perchlorate; CV, 5,9-diaminobenzo[ a ]phenoxazonium perchlorate; Ox-170, 9-ethylamino-5-ethylimino-10-methyl-5 H -benzo[ a ]phenoxazonium perchlorate; Ox-1, 3-diethylamino-7-diethyliminophenoxazonium perchlorate; Cc, 1,1′-diethyl-4,4′-carbocyanine iodide; HITCI, 1,1′,3,3, 3′,3′-hexamethylindotricarbocyanine iodide; IR-140, 3,3′-diethyl-5,5-dichloro-3,5-ethylene-4-(diphenylamino)-2, 2′-indotricarbocyanine perchlorate; IR-125, 1,1′- di(butylenesulfonate)-3,3,3′,3′-tetramethyl-4,4′,5, 5′-dibenzo-2,2′-indotricarbocyanine sodium; C-102, 2,3,5,6,-1 H,4 H -tetrahydro-8-methylquinolizino-(9,9 a,1- gh)coumarin; C-153, 2,3,5,6,-1 H,4 H -tetrahydro-8-trifluormethylquinolizino-(9,9 a,1- gh)coumarin; DCM, 4-dicyanomethylene-2-methyl-6-(p -dimethylaminostyryl)-4 H -pyran.
  • 44
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    • note
    • HEDITCP, 1,1′,3,3,3′,3′-hexamethyl-3,5-ethylene-4- (dimethylamino)-2,2′-indotricarbocyanine perchlorate; HPDITCP, 1,1′,3,3,3′,3′-hexamethyl-3,5-propylene-4-(dimethylamino)-2, 2′-indotricarbocyanine perchlorate.
  • 46
    • 79951683749 scopus 로고    scopus 로고
    • note
    • ONITCP, 1,1′,3,3,3′,3′(3,3′)-octamethyl-3,5- neopentylene-2,2′-indotetracarbocyanine perchlorate; ODNITCP, 1,1′,3,3,3′,3′(3,3′)-octamethyl-4,4′,5, 5′-dibenzo-3,5-neopentylene-2,2′-indotetracarbocyanine perchlorate.
  • 50
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    • note
    • ex was verified for these dyes across the wavelength range of their first absorption bands.
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    • note
    • With regard to the method of degassing, the performance of Ar deoxygenation proved to be similarly effective to the frequently employed freeze-pump-thaw technique while offering more straightforward handling.
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    • note
    • For dependences, see the respective entries for ethanol in ref 48.
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    • note
    • When lowering the temperature and especially when freezing the solvent, significant changes in viscosity occur and give rise to polarization effects, rendering the use of defined polarization conditions in excitation and emission mandatory. Furthermore, it is important to use optically dilute solutions because the absorption and emission bands are not only narrowed upon reduction of the temperature, but the Stokes shift is commonly also decreased, rendering reabsorption errors more significant at low temperatures.
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    • note
    • The weaker the fluorescence of a compound, the higher is usually the relative uncertainty introduced by the experimental standard deviation; see section II.2.3e, Supporting Information.
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    • note
    • Due to its considerably low fluorescence quantum yield and high anisotropy, Cc is not included here.
  • 84
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    • note
    • The fluorescence emission of C-102, C-153, DCM, Rh-101, CV, Ox-170, Ox-1, and HEDITCP does not depend on the excitation wavelength within the specified excitation range. For HITCI, IR-125, IR-140, ONITCP, and ODNITCP, the match of absorption and fluorescence excitation spectra could not be verified because of the spectral limitations of the excitation channel of the instrument employed. As reported in ref 43, absorption and fluorescence excitation spectra show a slight mismatch above ca. 680 nm for HPDITCP. Below 670 nm, the fluorescence quantum yield is independent of excitation wavelength in the specified range.
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    • 2940-2943, Relative Intensity Correction Standards for Fluorescence Spectroscopy (Orange, Green, Ultraviolet, Blue Emission). National Institute of Standards and Technology: Gaithersburg, MD,. (accessed Dec 1, 2010).
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.